Improving the Visible Light Photocatalytic Aerobic Oxidation of Sulfides into Sulfoxides on Dye-Sensitized TiO2

ChemCatChem ◽  
2018 ◽  
Vol 10 (20) ◽  
pp. 4545-4554 ◽  
Author(s):  
Huimin Hao ◽  
Zhan Wang ◽  
Ji-Long Shi ◽  
Xia Li ◽  
Xianjun Lang
2019 ◽  
Vol 17 (30) ◽  
pp. 7144-7149 ◽  
Author(s):  
Yueying Gao ◽  
Huan Xu ◽  
Shiwei Zhang ◽  
Yan Zhang ◽  
Chunlei Tang ◽  
...  

Under visible light, a metal-free aerobic selective sulfoxidation photosensitized by a perylene diimide photocatalyst has been developed.


2017 ◽  
Vol 7 (21) ◽  
pp. 4955-4963 ◽  
Author(s):  
Yichi Zhang ◽  
Zhan Wang ◽  
Xianjun Lang

Efficient visible-light-induced selective aerobic oxidation of alcohols was accomplished by merging the photocatalysis of dye-sensitized TiO2 with TEMPO catalysis.


RSC Advances ◽  
2016 ◽  
Vol 6 (82) ◽  
pp. 79085-79089 ◽  
Author(s):  
Maasoumeh Jafarpour ◽  
Hossein Kargar ◽  
Abdolreza Rezaeifard

A cobalt Schiff base complex and TiO2 nanoparticles exhibited a synergistic effect on the visible-light photocatalytic activity in the aerobic oxidation of various olefins in the absence of reducing agent.


2015 ◽  
Vol 6 (8) ◽  
pp. 5000-5005 ◽  
Author(s):  
Xianjun Lang ◽  
Wei Hao ◽  
Wan Ru Leow ◽  
Shuzhou Li ◽  
Jincai Zhao ◽  
...  

The selective aerobic oxidation of sulfides into sulfoxides on TiO2 under visible-light irradiation was accomplished through synergistic catalysis with triethylamine.


2018 ◽  
Vol 6 (31) ◽  
pp. 15154-15161 ◽  
Author(s):  
Jian Luo ◽  
Jingzhi Lu ◽  
Jian Zhang

Carbazole–triazine based donor–acceptor porous organic frameworks are efficient photocatalysts for aerobic oxidation reactions.


2015 ◽  
Vol 814 ◽  
pp. 31-38
Author(s):  
Xiao Yu Xu ◽  
Meng Wang ◽  
Lin Lin ◽  
Dan Nong He

Sensitized TiO2 nanospheres with uniform diameter of ca. 100 nm were successfully synthesized by a hydrothermal method using urea as templates and subsequently employed as robust visible-light photocatalysts. The photocatalytic activities of the sensitized TiO2 nanospheres evaluated by photodegrading methyl orange (MO) were recorded, giving the best photocatalytic performance for the sample synthesized at 110°C for 36 h. The photocatalytic mechanisms of the sensitized TiO2 nanospheres were attributed to the reduction of bandgap energies and the sensitizing effect of melon. The resultant melon acted as a sensitizer to absorb visible light and induced electrons which participated in the photodegradation of MO molecules. The new concept was helpful to guide the synthesis of robust photocatalysts, dye-sensitized solar cells, or hybrid solar cells, and the results suggested that the sensitized TiO2 nanospheres were very promising for enhancing the visible-light photocatalytic activity of TiO2 photocatalysts.


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