Effect of Ion Exchange Resin Functionality on Catalytic Activity and Leaching of Palladium Nanoparticles in Suzuki Cross-Coupling Reactions

ChemCatChem ◽  
2016 ◽  
Vol 9 (3) ◽  
pp. 451-457 ◽  
Author(s):  
Beau Van Vaerenbergh ◽  
Jeroen Lauwaert ◽  
Wim Bert ◽  
Joris W. Thybaut ◽  
Jeriffa De Clercq ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Ion Exchange ◽  
Palladium Nanoparticles ◽  
Exchange Resin ◽  
Cross Coupling ◽  
Ion Exchange Resin ◽  
Coupling Reactions ◽  
Cross Coupling Reactions

Palladium stabilized on poly and mono sulfonamide ligands as novel, simple, effective, and recyclable nano catalysts for C–C cross-coupling reactions

2017 ◽  
Vol 95 (10) ◽  
pp. 1073-1080 ◽  
Author(s):  
Ramin Ghorbani-Vaghei ◽  
Narges Sarmast
Keyword(s):  
Catalytic Activity ◽  
Palladium Nanoparticles ◽  
Cross Coupling ◽  
Significant Loss ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Nano Catalysts ◽  
Reaction Cycles ◽  
Analytical Tools

Poly and mono sulfonamide ligands were successfully used for the stabilization of palladium nanoparticles. The prepared nano catalysts that appeared to be heterogeneous and novel were characterized with various analytical tools. To establish the catalytic activity of the prepared catalysts, they were used in the Suzuki–Miyaura and Sonogashira–Hagihara coupling reactions of aryl halides under low palladium loading conditions. The catalysts showed good stability and could be recovered and reused for seven reaction cycles without significant loss of catalytic activity.

scholarly journals Effect of Substrates on Catalytic Activity of Biogenic Palladium Nanoparticles in C–C Cross-Coupling Reactions

ACS Omega ◽  
2019 ◽  
Vol 4 (2) ◽  
pp. 3329-3340 ◽  
Author(s):  
Manashi Sarmah ◽  
Arindom B. Neog ◽  
Purna K. Boruah ◽  
Manash R. Das ◽  
Pankaj Bharali ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Palladium Nanoparticles ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions

Lewis Acid-Promoted Suzuki Reaction using Palladium Chloride Anchored on a Polymer as a Catalyst

2008 ◽  
Vol 61 (8) ◽  
pp. 610 ◽  
Author(s):  
Guozhi Fan ◽  
Hanjun Zhang ◽  
Siqing Cheng ◽  
Zhandong Ren ◽  
Zhijun Hu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Lewis Acid ◽  
Lewis Acids ◽  
Heterogeneous Catalysts ◽  
Suzuki Reaction ◽  
Cross Coupling ◽  
Palladium Chloride ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Recoverable Catalyst

Palladium chloride anchored on polystyrene modified by 5-amino-1,10-phenanthroline was prepared and used as an efficient recoverable catalyst for Suzuki cross-coupling reactions. The heterogeneous catalysts can be easily separated from the reaction mixture and reused for five cycles without significant Pd leaching and loss of catalytic activity. Rate enhancement in the Suzuki reaction by Lewis acids was also studied.

A cyano-bridged copper(ii)–copper(i) mixed-valence coordination polymer as a source of copper oxide nanoparticles with catalytic activity in C–N, C–O and C–S cross-coupling reactions

2014 ◽  
Vol 38 (9) ◽  
pp. 4267-4274 ◽  
Author(s):  
Manoj Trivedi ◽  
Sanjeev kumar Ujjain ◽  
Raj Kishore Sharma ◽  
Gurmeet Singh ◽  
Abhinav Kumar ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Coordination Polymer ◽  
Copper Oxide ◽  
Mixed Valence ◽  
Cross Coupling ◽  
Copper Oxide Nanoparticles ◽  
Cuo Nanoparticles ◽  
Oxide Nanoparticles ◽  
Coupling Reactions ◽  
Cross Coupling Reactions

A cyano-bridged Cu(ii)–Cu(i) complex was synthesized and transformed into CuO nanoparticles. Their catalytic activity in C–N, C–O, and C–S cross-coupling reactions was explored.

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