Effect of Particle Size upon Pt/SiO2Catalytic Cracking ofn-Dodecane under Supercritical Conditions: In situ SAXS and XANES Studies

ChemCatChem ◽  
2016 ◽  
Vol 9 (1) ◽  
pp. 99-102 ◽  
Author(s):  
Sungwon Lee ◽  
Sungsik Lee ◽  
Mrunmayi D. Kumbhalkar ◽  
Kamila M. Wiaderek ◽  
James Dumesic ◽  
...  
Fuel ◽  
2021 ◽  
Vol 291 ◽  
pp. 120270
Author(s):  
Seo Yeong Kang ◽  
Su Been Seo ◽  
Eun Sol Go ◽  
Hyung Woo Kim ◽  
Sang In Keel ◽  
...  

2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
Carola Contreras ◽  
Fernanda Isquierdo ◽  
Pedro Pereira-Almao ◽  
Carlos E. Scott

More than half of the total world oil reserves are heavy oil, extra heavy oil, and bitumen; however their catalytic conversion to more valuable products is challenging. The use of submicronic particles or nanoparticles of catalysts suspended in the feedstock may be a viable alternative to the conversion of heavy oils at refinery level or downhole (in situ upgrading). In the present work, molybdenum sulfide (MoS2) particles with varying diameters (10000–10 nm) were prepared using polyvinylpyrrolidone as capping agent. The prepared particles were characterized by DLS, TEM, XRD, and XPS and tested in the hydrodesulfurization (HDS) of a vacuum gas oil (VGO). A correlation between particle size and activity is presented. It was found that particles with diameters around 13 nm show double the HDS activity compared with the material with micrometric particle sizes (diameter ≈ 10,000 nm).


2015 ◽  
Vol 270 ◽  
pp. 337-347 ◽  
Author(s):  
J. Paul ◽  
S. Romeis ◽  
M. Mačković ◽  
V.R.R. Marthala ◽  
P. Herre ◽  
...  

2000 ◽  
Vol 80 (1) ◽  
pp. 203-206 ◽  
Author(s):  
C. Bayourthe ◽  
R. Moncoulon ◽  
F. Enjalbert

Ruminal disappearance characteristics of OM, CP and starch relative to particle size of dehulled pea seeds were determined using the in sacco method. Fine grinding (≤502 µm) highly increased the rapidly CP and starch degradable fractions and the rate of degradation of these nutrients. Key words: Pea flour, particle size, rumen degradation, crude protein, starch


ACS Catalysis ◽  
2012 ◽  
Vol 2 (3) ◽  
pp. 450-455 ◽  
Author(s):  
Takako Sato ◽  
Kazuki Okaya ◽  
Keiji Kunimatsu ◽  
Hiroshi Yano ◽  
Masahiro Watanabe ◽  
...  

2013 ◽  
Vol 45 (2) ◽  
pp. 165-172 ◽  
Author(s):  
W. Yan ◽  
N. Li ◽  
J. Tong ◽  
G. Liu ◽  
J. Xu

The porous cordierite-mullite ceramics were prepared by the pore-forming in-situ technique. The characterizations of porous cordierite-mullite ceramics were determined by an X-ray diffractometer (XRD), a scanning electron microscopy (SEM), and a microscopy measured method, etc., and the effect of particle size on phase composition, pore characterization and strength were investigated. It?s found that particle size affects strongly the formations of cordierite and mullite, and then changes the pore characterization and strength. With the decrease of the particle size, the sintering temperature at which the formations of cordierite and mullite take place extremely fast decreases, the pore size distribution becomes from bi-peak mode to mono-peak mode, the porosity and the median pore size decrease but strength increases. The most opposite mode is the specimen sintered at 1400 ?C from the grinded powder with an average particle size of 10.2 ?m, which consists of cordierite, mullite and minor spinel, and has a high apparent porosity (40 %), a high compressive strength (58.4 MPa), a small median pore size (6.3 ?m) and well-developed necks between particles.


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