scholarly journals Mesoporous High-Surface-Area Copper-Tin Mixed-Oxide Nanorods: Remarkable for Carbon Monoxide Oxidation

ChemCatChem ◽  
2016 ◽  
Vol 8 (14) ◽  
pp. 2329-2334 ◽  
Author(s):  
Honggen Peng ◽  
Yang Liu ◽  
Yarong Li ◽  
Xianhua Zhang ◽  
Xianglan Tang ◽  
...  
Author(s):  
Flavio Colmati Jr. ◽  
William H. Lizcano-Valbuena ◽  
Giuseppe A. Camara ◽  
Edson A. Ticianelli ◽  
Ernesto R. Gonzalez

2018 ◽  
Vol 105 ◽  
pp. 26-30 ◽  
Author(s):  
Baohuai Zhao ◽  
Rui Ran ◽  
Li Sun ◽  
Zesheng Yang ◽  
Xiaodong Wu ◽  
...  

2004 ◽  
Vol 93-95 ◽  
pp. 671-674 ◽  
Author(s):  
Min Chen ◽  
Peizhuang Zhang ◽  
Xiaoming Zheng

2019 ◽  
Vol 17 (12) ◽  
pp. 924-937
Author(s):  
K. Kasirajan ◽  
M. Karunakaran

Green synthesis of nanomaterials is an emphasis of recent developments. Herein, a facile and eco-friendly method for the synthesis of SrO–CeO2 mixed oxide NPs using ionic liquid (IL) assisted an ethanolic solution of Pedalium murex (PM) plant extract. NPs synthesized at room temperature using an ionic liquid (IL) as a mediator for the nucleation and growth process. SrO–CeO2 mixed oxide NPs system displaying nano rod like structure with 10–15 nm and high surface area that are confirmed by XRD, and SEM studies. GC-MS spectroscopy confirms the presence of N-Hexadecanoic acid (29%), 6-Octadecenoic acid, (Z) present in the plant extract that are capable to convert the corresponding metal ion precursor to SrO–CeO2 mixed oxide NPs. In FTIR the Ce–O and SrCO3 stretching bands were observed at 451 and 856 cm–1 respectively. Raman spectroscopy give stretching frequency at 457 and 159 cm–1 that proofs the presence of CeO2 and SrO present in the mixed oxide. The band gap energy of the SrO–CeO2 mixed oxide NPs was estimated as 3.17 eV from the UV-DRS spectroscopy. The anti-bacterial studies performed against a set of bacterial strains the result showed that SrO–CeO2 mixed oxide NPs more susceptible for gram negative (G–) bacteria then gram positive (G+) bacteria. A unique feature of the antioxidant behavior of NPs reduces the concentration of DPPH radical up to 89%. The toxicology behavior of SrO–CeO2 mixed oxide NPs found due to the high oxygen site vacancies, ROS formation, smallest particle size and higher surface area.


2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Sangeeta Adhikari ◽  
Debasish Sarkar

Attempts were made to compare the photocatalytic efficacy in between quasi-fiber and near spherical commercial grade ZnO through the addition of monoclinic WO3nanocuboid. Mixed oxide semiconductors were assessed for their dye degradation performance under irradiation of visible light energy. Surface area and the particle morphology pattern have an influence on the resultant photocatalytic features of these mixed oxide composites. The high porous quasi-fibrous ZnO was successfully fabricated by a simple solution combustion method. It is deliberately made of clusters of primary near spherical particles that supports WO3nanocuboid embedment and shows interactive characteristics in comparison to the counterpart commercial near spherical ZnO combined with WO3. The photocatalytic activity significantly increases up to 95% under visible radiation for 90 min due to high surface area imparted by unique quasi-fiber morphology. The photogenerated electron-hole pair interaction mechanism has been proposed to support the photocatalytic behavior.


2015 ◽  
Vol 39 (1) ◽  
pp. 172-178 ◽  
Author(s):  
Dipshikha Bharali ◽  
Rasna Devi ◽  
Pankaj Bharali ◽  
Ramesh C. Deka

NiMgAl mixed oxide catalyzes nitro-aldol condensation reaction at room temperature under solvent free conditions exhibiting 99% conversion.


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