Cinchona Alkaloid Catalyzed Asymmetric Desymmetrization ofmeso-Cyclic Anhydrides: The Origins of Stereoselectivity

ChemCatChem ◽  
2015 ◽  
Vol 7 (24) ◽  
pp. 4173-4179 ◽  
Author(s):  
Burcu Dedeoglu ◽  
Saron Catak ◽  
Asli Yildirim ◽  
Carsten Bolm ◽  
Viktorya Aviyente
RSC Advances ◽  
2016 ◽  
Vol 6 (76) ◽  
pp. 72300-72305 ◽  
Author(s):  
Shohei Takata ◽  
Yuta Endo ◽  
Mohammad Shahid Ullah ◽  
Shinichi Itsuno

Mizoroki–Heck polymerization of cinchona sulfonamide gave chiral polymers, which are active catalysts for enantioselective desymmetrization of cyclic anhydrides to give chiral hemiesters in high yield with high enantioselectivities.


2022 ◽  
Author(s):  
Hemant P. Soni ◽  
Sanjiv O. Tomer

In the present work, the molecular framework of the quinidine was modified at the methoxy functional of C6’ carbon of quinoline moiety with a long-chain carboxylic acid group (-COOH) and...


2021 ◽  
Author(s):  
Franck Le Bideau ◽  
Samuel Dagorne ◽  
Samir Messaoudi ◽  
Françoise Dumas ◽  
Gaël Printz ◽  
...  

Polyesters are omnipresent in our everyday lives and their synthesis via eco-friendly methods is becoming a major challenge today. The co-polymerization of cyclic anhydrides and epoxides was first reported by...


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