Hydroxyl Group-Assisted Palladium-Catalyzed Lactonization of Homoallylic Alcohols

ChemCatChem ◽  
2014 ◽  
Vol 6 (2) ◽  
pp. 561-566 ◽  
Author(s):  
Liangbin Huang ◽  
Qian Wang ◽  
Wanqing Wu ◽  
Huanfeng Jiang
Keyword(s):  
Hydroxyl Group ◽  
Homoallylic Alcohols ◽  
Palladium Catalyzed

ChemInform Abstract: Hydroxyl Group-Assisted Palladium-Catalyzed Lactonization of Homoallylic Alcohols.

ChemInform ◽  
2014 ◽  
Vol 45 (31) ◽  
pp. no-no
Author(s):  
Liangbin Huang ◽  
Qian Wang ◽  
Wanqing Wu ◽  
Huanfeng Jiang
Keyword(s):  
Hydroxyl Group ◽  
Homoallylic Alcohols ◽  
Palladium Catalyzed

Synthesis of (Z)-Alkene-Containing Linear Conjugated Dienyl Homoallylic Alcohols by a Palladium-Catalyzed Three-Component Reaction

Synlett ◽  
2020 ◽  
Vol 31 (13) ◽  
pp. 1323-1327
Author(s):  
Yoshikazu Horino ◽  
Juri Sakamoto ◽  
Miki Murakami ◽  
Miki Sugata
Keyword(s):  
Present Method ◽  
Functional Group ◽  
Homoallylic Alcohols ◽  
Three Component Reaction ◽  
Palladium Catalyzed

A synthesis of (Z)-alkene-containing linear conjugated dienyl homoallylic alcohols by using a palladium-catalyzed three-component reaction has been developed. This method shows good functional-group compatibility and generality, with high diastereoselectivity. Additionally, in many cases, the present method controls the alkene stereochemistry of the newly formed C–C bond and overcomes the inherent preference for (E)-alkene formation, giving (Z,E)- and (Z,Z)-products.

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