Mechanistic Insight into Catalytic Oxidation of Ammonia on Clean, O- and OH-Assisted Ir(1 1 1) Surfaces

ChemCatChem ◽  
2013 ◽  
Vol 5 (7) ◽  
pp. 1832-1841 ◽  
Author(s):  
Xiaoqing Lu ◽  
Zhigang Deng ◽  
Ka-Shing Chau ◽  
Longfei Li ◽  
Zengqiang Wen ◽  
...  
Keyword(s):  
Catalytic Oxidation ◽  
Mechanistic Insight ◽  
Insight Into ◽  
Oxidation Of Ammonia

scholarly journals Chemical and Electrocatalytic Ammonia Oxidation by Ferrocene

2019 ◽  
Author(s):  
Mahdi Raghibi Boroujeni ◽  
Christine Greene ◽  
Jeffery A. Bertke ◽  
Timothy H. Warren
Keyword(s):  
Liquid Ammonia ◽  
Computational Analysis ◽  
Ammonia Oxidation ◽  
Nitrogen Gas ◽  
Simple Modification ◽  
Mechanistic Insight ◽  
Earth Abundant ◽  
Insight Into ◽  
Oxidation Of Ammonia

Recognizing the potential of ammonia to serve as a carbon-free fuel, we describe an electrocatalytic system for the oxidation of ammonia based on ferrocene (Cp<sub>2</sub>Fe), an inexpensive, robust catalyst utilizing Earth-abundant iron. Ferrocenium (Cp<sub>2</sub>Fe<sup>+</sup>), the 1-electron oxidized form of ferrocene, cleanly oxidizes ammonia to generate nitrogen gas (N<sub>2</sub>) and protons captured by excess ammonia as NH<sub>4</sub><sup>+ </sup>with electrons reducing ferrocenium to ferrocene. This process occurs under electrocatalytic conditions to generate N<sub>2 </sub>with sustained current. Simple modification of ferrocene through sulfonation allows for solubility in liquid ammonia to enable electrocatalysis in highly concentrated, energy dense solutions of ammonia. Kinetic and computational analysis provides mechanistic insight into the oxidation of ammonia by ferrocenium.

Mechanistic Insight into the Catalytic Oxidation of Cyclohexane over Carbon Nanotubes: Kinetic and In Situ Spectroscopic Evidence

2013 ◽  
Vol 19 (30) ◽  
pp. 9818-9824 ◽  
Author(s):  
Xixian Yang ◽  
Hongjuan Wang ◽  
Jing Li ◽  
Wenxu Zheng ◽  
Rong Xiang ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Catalytic Oxidation ◽  
Spectroscopic Evidence ◽  
Mechanistic Insight ◽  
Insight Into

Mechanistic insight into the selective catalytic oxidation for NO and CO on co-doping graphene sheet: A theoretical study

Fuel ◽  
2019 ◽  
Vol 253 ◽  
pp. 1531-1544 ◽  
Author(s):  
Yanan Tang ◽  
Weiguang Chen ◽  
Jincheng Zhou ◽  
Huadou Chai ◽  
Yi Li ◽  
...  
Keyword(s):  
Catalytic Oxidation ◽  
Graphene Sheet ◽  
Theoretical Study ◽  
Co Doping ◽  
Mechanistic Insight ◽  
Selective Catalytic Oxidation ◽  
Insight Into

scholarly journals Chemical and Electrocatalytic Ammonia Oxidation by Ferrocene

2019 ◽  
Author(s):  
Mahdi Raghibi Boroujeni ◽  
Christine Greene ◽  
Jeffery A. Bertke ◽  
Timothy H. Warren
Keyword(s):  
Liquid Ammonia ◽  
Computational Analysis ◽  
Ammonia Oxidation ◽  
Nitrogen Gas ◽  
Simple Modification ◽  
Mechanistic Insight ◽  
Earth Abundant ◽  
Insight Into ◽  
Oxidation Of Ammonia

Recognizing the potential of ammonia to serve as a carbon-free fuel, we describe an electrocatalytic system for the oxidation of ammonia based on ferrocene (Cp<sub>2</sub>Fe), an inexpensive, robust catalyst utilizing Earth-abundant iron. Ferrocenium (Cp<sub>2</sub>Fe<sup>+</sup>), the 1-electron oxidized form of ferrocene, cleanly oxidizes ammonia to generate nitrogen gas (N<sub>2</sub>) and protons captured by excess ammonia as NH<sub>4</sub><sup>+ </sup>with electrons reducing ferrocenium to ferrocene. This process occurs under electrocatalytic conditions to generate N<sub>2 </sub>with sustained current. Simple modification of ferrocene through sulfonation allows for solubility in liquid ammonia to enable electrocatalysis in highly concentrated, energy dense solutions of ammonia. Kinetic and computational analysis provides mechanistic insight into the oxidation of ammonia by ferrocenium.

scholarly journals Mechanistic insight into B(C6F5)3 catalyzed imine reduction with PhSiH3 under stoichiometric water conditions

RSC Advances ◽  
2021 ◽  
Vol 11 (34) ◽  
pp. 20961-20969
Author(s):  
Yunqing He ◽  
Wanli Nie ◽  
Ying Xue ◽  
Qishan Hu
Keyword(s):  
Mechanistic Insight ◽  
Excess Water ◽  
Water Conditions ◽  
Imine Reduction ◽  
Water Amount ◽  
Insight Into

Hydrosilylation or amination products? It depends on water amount and nucleophiles like excess water or produced/added amines.

scholarly journals Mechanistic insight into the fluorescence activity of forensic fingerprinting reagents

2021 ◽  
Vol 154 (12) ◽  
pp. 124313
Author(s):  
L. M. Hunnisett ◽  
P. F. Kelly ◽  
S. Bleay ◽  
F. Plasser ◽  
R. King ◽  
...  
Keyword(s):  
Mechanistic Insight ◽  
Insight Into
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