Low Temperature-High Selectivity Process over Supported Pd Nanoparticles in Partial Oxidation of Methanol

ChemCatChem ◽  
2011 ◽  
Vol 4 (1) ◽  
pp. 72-75 ◽  
Author(s):  
Robert Wojcieszak ◽  
Eric M. Gaigneaux ◽  
Patricio Ruiz
Keyword(s):  
Low Temperature ◽  
Partial Oxidation ◽  
High Selectivity ◽  
Pd Nanoparticles ◽  
Oxidation Of Methanol ◽  
Partial Oxidation Of Methanol ◽  
Supported Pd

Oxidation of methanol to methyl formate over supported Pd nanoparticles: insights into the reaction mechanism at low temperature

2014 ◽  
Vol 4 (9) ◽  
pp. 3298-3305 ◽  
Author(s):  
R. Wojcieszak ◽  
A. Karelovic ◽  
E. M. Gaigneaux ◽  
P. Ruiz
Keyword(s):  
Reaction Mechanism ◽  
Low Temperature ◽  
Methyl Formate ◽  
Pd Nanoparticles ◽  
Dissociative Adsorption ◽  
Reaction Step ◽  
Oxidation Of Methanol ◽  
Methoxy Groups ◽  
Supported Pd

The mechanism of methyl formate formation at low temperature was studied using DRIFT-operando. The first reaction step would be the formation of methoxy groups by dissociative adsorption of methanol and then transformation into formaldehyde. The final step would be the condensation of the formaldehyde species with gaseous methanol.

Modulation of the selectivity in partial oxidation of methanol over CuZnAl catalysts by adding CO 2 and/or H 2 into the reaction feed

2015 ◽  
Vol 168-169 ◽  
pp. 14-24 ◽  
Author(s):  
Silvia R. González Carrazán ◽  
Robert Wojcieszak ◽  
Raquel. M. Blanco ◽  
Cecilia Mateos-Pedrero ◽  
Patricio Ruiz
Keyword(s):  
Partial Oxidation ◽  
Oxidation Of Methanol ◽  
Partial Oxidation Of Methanol

scholarly journals Partial Oxidation of Methanol Over Highly Dispersed Vanadia Supported on Silica SBA-15

2005 ◽  
Vol 105 (1-2) ◽  
pp. 1-8 ◽  
Author(s):  
C. Hess ◽  
Ian J. Drake ◽  
James D. Hoefelmeyer ◽  
T. Don Tilley ◽  
Alex T. Bell
Keyword(s):  
Partial Oxidation ◽  
Oxidation Of Methanol ◽  
Partial Oxidation Of Methanol ◽  
Highly Dispersed

Partial oxidation of methanol to produce hydrogen over CuZn-based catalysts

1997 ◽  
Vol 162 (1-2) ◽  
pp. 281-297 ◽  
Author(s):  
L. Alejo ◽  
R. Lago ◽  
M.A. Peña ◽  
J.L.G. Fierro
Keyword(s):  
Partial Oxidation ◽  
Oxidation Of Methanol ◽  
Partial Oxidation Of Methanol
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