Atropisomeric Binaphthalene-Core Phosphacyclic Derivatives in Coordination Chemistry and Homogeneous Catalysis

1997 ◽  
Vol 130 (5) ◽  
pp. 543-554 ◽  
Author(s):  
Serafino Gladiali ◽  
Davide Fabbri
Keyword(s):  
Coordination Chemistry ◽  
Homogeneous Catalysis

scholarly journals Unraveling the coordination structure-performance relationship in Pt1/Fe2O3 single-atom catalyst

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Yujing Ren ◽  
Yan Tang ◽  
Leilei Zhang ◽  
Xiaoyan Liu ◽  
Lin Li ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Homogeneous Catalysis ◽  
Catalytic Performance ◽  
Inert Atmosphere ◽  
Single Atom ◽  
Unique Role ◽  
Local Coordination ◽  
Single Atoms ◽  
Heterogeneous And Homogeneous Catalysis

Abstract Heterogeneous single-atom catalyst (SAC) opens a unique entry to establishing structure–performance relationship at the molecular level similar to that in homogeneous catalysis. The challenge lies in manipulating the coordination chemistry of single atoms without changing single-atom dispersion. Here, we develop an efficient synthetic method for SACs by using ethanediamine to chelate Pt cations and then removing the ethanediamine by a rapid thermal treatment (RTT) in inert atmosphere. The coordination chemistry of Pt single atoms on a Fe2O3 support is finely tuned by merely adjusting the RTT temperature. With the decrease in Pt-O coordination number, the oxidation state of Pt decreases, and consequently the hydrogenation activity increases to a record level without loss of chemoselectivity. The tunability of the local coordination chemistry, oxidation states of the metal, and the catalytic performance of single atoms reveals the unique role of SACs as a bridge between heterogeneous and homogeneous catalysis.

Lower- and upper-rim-modified derivatives of 1,3,5-triaza-7-phosphaadamantane: Coordination chemistry and applications in catalytic reactions in water

2012 ◽  
Vol 85 (2) ◽  
pp. 385-396 ◽  
Author(s):  
Luca Gonsalvi ◽  
Antonella Guerriero ◽  
Frédéric Hapiot ◽  
Donald A. Krogstad ◽  
Eric Monflier ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Homogeneous Catalysis ◽  
Water Soluble ◽  
Catalytic Reactions ◽  
Water Soluble Phosphine ◽  
Upper Rim ◽  
Derivatives Of

In this article, a brief review of the recent functionalizations of the cage-like water-soluble phosphine 1,3,5-triaza-7-phosphaadamantane (PTA), involving N-quaternization (lower rim) and introduction of a side arm in C-6 position (upper rim) will be presented, highlighting selected examples in their use as ligands for ruthenium(II), iridium(I), and rhodium(I) moieties together with applications of the related complexes in homogeneous catalysis.

1,3-P,N hybrid ligands in mononuclear coordination chemistry and homogeneous catalysis

2019 ◽  
Vol 380 ◽  
pp. 1-16 ◽  
Author(s):  
Mark K. Rong ◽  
Flip Holtrop ◽  
J. Chris Slootweg ◽  
Koop Lammertsma
Keyword(s):  
Coordination Chemistry ◽  
Homogeneous Catalysis ◽  
Hybrid Ligands

scholarly journals Sir Geoffrey Wilkinson. 14 July 1921 — 26 September 1996

2000 ◽  
Vol 46 ◽  
pp. 593-606 ◽  
Author(s):  
M.L.H. Green ◽  
W.P. Griffith
Keyword(s):  
Inorganic Chemistry ◽  
Coordination Chemistry ◽  
Organometallic Chemistry ◽  
Homogeneous Catalysis ◽  
Periodic Table ◽  
Entire Period ◽  
Major Contributor ◽  
Scientific Career ◽  
Individual Contributions

Geoffrey Wilkinson was one of the most influential chemists of the postwar era, a major contributor to the renaissance of inorganic chemistry and probably the most influential founder of modern organometallic chemistry. His scientific career spanned more than fifty years and he worked throughout that entire period with undiminished enthusiasm and intellectual vigour. His work covered most of the elements in the Periodic Table, and he made remarkable and highly individual contributions to radiochemistry, organometallic chemistry, coordination chemistry and homogeneous catalysis.

scholarly journals Phosphomolybdic acid supported atomically dispersed transition metal atoms (M = Fe, Co, Ni, Cu, Ru, Rh, Pd, Ag, Os, Ir, Pt, and Au): stable single atom catalysts studied by density functional theory

RSC Advances ◽  
2017 ◽  
Vol 7 (40) ◽  
pp. 24925-24932 ◽  
Author(s):  
Shujiao Wang ◽  
Yingxin Feng ◽  
Sen Lin ◽  
Hua Guo
Keyword(s):  
Density Functional Theory ◽  
Coordination Chemistry ◽  
Transition Metal ◽  
Homogeneous Catalysis ◽  
Density Functional ◽  
Phosphomolybdic Acid ◽  
Single Atom ◽  
Functional Theory ◽  
Metal Atoms ◽  
Transition Metal Atoms

This study will provide a guideline for designing stable single atom catalysts by taking advantage of coordination chemistry and homogeneous catalysis.

Sign in / Sign up

Export Citation Format

Share Document