Negative ion chemical ionization and collisionally activated decomposition mass spectra ofO-2,3,4,5,6-pentafluorobenzyloxime derivatives of prostaglandins

1994 ◽  
Vol 23 (2) ◽  
pp. 47-56 ◽  
Author(s):  
Horst Schweer ◽  
Sven Fischer
1997 ◽  
Vol 13 (2) ◽  
pp. 151-161 ◽  
Author(s):  
Kevin B. Thurbide ◽  
C. M. Elson ◽  
P. G. Sim

The negative‒ion chemical ionization mass spectra of a group of structural isomers of amphetamine have been studied using carbon dioxide as the reagent gas. Characteristic and reproducible differences are observed for each member of the set implying that this technique offers a means of distinguishing among groups of amphetamine isomers. Characteristic adducts to the molecular ion are observed in the form (M–[H]+[O]) and (M–[H]+[CO2]). Descriptions of some fragments are given based on the mass spectral behaviour of a set of analogue compounds and the results of oxygen-18 labelled carbon dioxide reagent gas experiments. Contents of the carbon dioxide plasma and their impact on various analytes is also discussed.


1984 ◽  
Vol 106 (23) ◽  
pp. 6877-6883 ◽  
Author(s):  
Seymour Meyerson ◽  
Donald J. Harvan ◽  
J. Ronald Hass ◽  
Fausto Ramirez ◽  
James F. Marecek

1982 ◽  
Vol 17 (12) ◽  
pp. 617-619 ◽  
Author(s):  
Gian Angelo Vaglio ◽  
Paolo Volpe ◽  
Lorenza Operti

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