Influence of the 6-trimethylsilyl group on the fragmentation of the trimethylsilyl derivatives of some 6-hydroxy- and 3,6-dihydroxy-steroids and related compounds

1979 ◽  
Vol 6 (4) ◽  
pp. 135-143 ◽  
Author(s):  
David J. Harvey ◽  
Paul Vouros
Keyword(s):  
Trimethylsilyl Group ◽  
Trimethylsilyl Derivatives ◽  
Derivatives Of ◽  
Related Compounds

scholarly journals Application of trimethylsilyl derivatives of biologically related compounds to fast atom bombardment mass spectrometry and tandem mass spectrometry.

1996 ◽  
Vol 45 (6) ◽  
pp. 457-463
Author(s):  
Takeshi KINOSHITA ◽  
Kayoko TORII ◽  
Tomio ISHIKAWA ◽  
Yasuko MARUYAMA ◽  
Tomoko TAKAZAWA ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Tandem Mass Spectrometry ◽  
Fast Atom Bombardment ◽  
Tandem Mass ◽  
Trimethylsilyl Derivatives ◽  
Derivatives Of ◽  
Related Compounds

scholarly journals Trimethylsilylverbindungen der Vb-Elemente, HI [1]. Tris(trimethylsilyl)- und Tris(trimethylstannyl)bismutan sowie Tetrakis(trimethylsilyl)dibismutan / Trimethylsilyl Derivatives of Vb-Elements, III [1]. Tris(trimethylsilyl)- and Tris(trimethylstannyl)bismuthine as well as Tetrakis(trimethylsilyl)dibismuthine

1982 ◽  
Vol 37 (1) ◽  
pp. 91-96 ◽  
Author(s):  
Gerd Becker ◽  
Michael Rößler
Keyword(s):  
Organic Solvents ◽  
Colour Change ◽  
Trimethylsilyl Group ◽  
Sodium Potassium ◽  
Halogen Exchange ◽  
Trimethylsilyl Derivatives ◽  
Derivatives Of

Abstract Chlorotrimethylsilane and sodium/potassium bismuthide, easily prepared from finely powdered bismuth and sodium potassium alloy in 1,2-dimethoxyethane (DME), react to give tris(trimethylsilyl)bismuthine (1) in 48% yield. When compound 1 is treated with chlorotrimethylstannane all trimethylsilyl substituents are successively replaced by stannyl groups, and tris(trimethylstannyl)bismuthine (4) is obtained. As in analogous reactions of other tris(trimethylsilyl) derivatives of Vb-elements with methyl lithium in diethylether/tetrahydrofuran (THF), one trimethylsilyl group of tris (trimethylsilyl)-bismuthine (1) can also be removed, and lithium bis(trimethylsilyl)bismuthide · 2 THF (5) is formed. With 1,2-dibromoethane bismuthide 6 reacts with metal halogen exchange to give green lustrous needles of tetrakis(trimethylsilyl)dibismuthine (6). In contrast to other dibismuthines described in the literature, this compound is thermally rather stable and can be isolated in preparative amounts. Similar to several distibines a colour change from green to red, resp. orange-red occurs on melting or dissolving dibismuthine 6 in organic solvents.

ChemInform Abstract: TRIMETHYLSILYL DERIVATIVES OF TITANIUM

1978 ◽  
Vol 9 (19) ◽  
Author(s):  
G. A. RAZUVAEV ◽  
V. N. LATYAEVA ◽  
L. I. VYSHINSKAYA ◽  
A. V. MALYSHEVA ◽  
G. A. VASI'EVA
Keyword(s):  
Trimethylsilyl Derivatives ◽  
Derivatives Of

Synthesis of 5,7-dihydroxynaphthoquinone derivatives and their reactions with nucleophiles: Nitration of 2,3-dimethylnaphthalene and subsequent transformations

1976 ◽  
Vol 29 (10) ◽  
pp. 2247 ◽  
Author(s):  
HJ Banks ◽  
DW Cameron ◽  
MJ Crossley ◽  
EL Samuel
Keyword(s):  
Unusual Reaction ◽  
Nitro Derivatives ◽  
Reactions With Nucleophiles ◽  
Derivatives Of ◽  
Related Compounds ◽  
Benzenoid Ring

5,7-Dihydroxy-2,3-dimethyl-l,4-naphthoquinone (5) and related compounds have been synthesized. The quinone affords an accessible substrate for studying an unusual reaction with nucleophiles, which involves attack at the 8-position, i.e. at the benzenoid ring. An unsuccessful approach to (5) has led to tri- and tetra-nitro derivatives of 2,3-dimethylnaphthalene. Reduction of the former and subsequent conversions have given aminonaphthoquinone and perimidinone derivatives.

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