Nucleophilic Substitution Reactions of 2,4-Dinitrophenyl X-Substituted-Benzenesulfonates and Y-Substituted-Phenyl 4-Nitrobenzenesulfonates with Azide Ion: Regioselectivity and Reaction Mechanism

2015 ◽  
Vol 36 (5) ◽  
pp. 1360-1365 ◽  
Author(s):  
Ji-Hyun Moon ◽  
Min-Young Kim ◽  
So-Yeop Han ◽  
Ik-Hwan Um
Keyword(s):  
Reaction Mechanism ◽  
Nucleophilic Substitution ◽  
Substitution Reactions ◽  
Nucleophilic Substitution Reactions ◽  
Azide Ion

Mechanistic pathways of aromatic nucleophilic substitution in conventional solvents and ionic liquids

2014 ◽  
Vol 38 (6) ◽  
pp. 2611-2618 ◽  
Author(s):  
Marcela Gazitúa ◽  
Ricardo A. Tapia ◽  
Renato Contreras ◽  
Paola R. Campodónico
Keyword(s):  
Ionic Liquids ◽  
Reaction Mechanism ◽  
Nucleophilic Substitution ◽  
Substitution Reactions ◽  
Aromatic Nucleophilic Substitution ◽  
Solvation Effects ◽  
Nucleophilic Substitution Reactions

Solvation effects on the reaction mechanism for nucleophilic substitution reactions have been kinetically evaluated in conventional solvents and ionic liquids.

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