Identification of a new electronic transition in the Z form of poly(dG-dC)·poly(dG-dc) by infrared absorption and resonance Raman spectroscopy

Biopolymers ◽  
1984 ◽  
Vol 23 (10) ◽  
pp. 1931-1942 ◽  
Author(s):  
L. Chinsky ◽  
B. Jolles ◽  
A. Laigle ◽  
P. Y. Turpin ◽  
J. Taboury ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Infrared Absorption ◽  
Electronic Transition ◽  
Resonance Raman Spectroscopy ◽  
Resonance Raman

Biological applications of resonance Raman spectroscopy: haem proteins

1975 ◽  
Vol 345 (1640) ◽  
pp. 89-105 ◽  
Keyword(s):  
Raman Spectroscopy ◽  
Electronic Transition ◽  
Resonance Raman Spectroscopy ◽  
Resonance Raman ◽  
Structural Features ◽  
Symmetry Properties ◽  
State Changes ◽  
Resonance Raman Spectra ◽  
A Site ◽  
Haem Proteins

Resonance Raman spectroscopy involves laser excitation within an absorption band of the sample. Certain vibrational modes, those which couple to the electronic transition, exhibit greatly increased Raman scattering in the resulting spectrum. Sensitivity approaches that of absorption spectrophotometry, while the high resolution characteristic of vibrational spectroscopy is preserved, even in solution at room temperature. If the resonant electronic transition is associated with a site of biological activity, then the technique offers a sensitive probe for structural features of the site. Haem proteins afford particularly informative resonance Raman spectra, with a rich assortment of porphyrin ring vibrations, which can be classified and analysed via their symmetry properties. Certain of these frequencies are sensitive to the structural concomitants of spin- and oxidation-state changes of the haem group. These can be used to monitor the structural consequences of ligation or electron transfer in haem proteins.

Insights into the charge-transfer character of electronic transitions in RCp2Ti(C2Fc)2 complexes using solvatochromism, resonance Raman spectroscopy, and TDDFT

2021 ◽  
Vol 50 (6) ◽  
pp. 2233-2242
Author(s):  
Elizabeth S. Carlton ◽  
Joshua J. Sutton ◽  
Ariel G. Gale ◽  
George C. Shields ◽  
Keith C. Gordon ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Charge Transfer ◽  
Electronic Transition ◽  
Resonance Raman Spectroscopy ◽  
Resonance Raman ◽  
Electronic Transitions

Augmented with TDDFT, solvatochromism and resonance Raman spectroscopy of RCp2Ti(C2Fc)2 complexes are consistent with the characterization of the lowest-energy electronic transition as a delocalized ethynylferrocene to TiIV charge transfer.

scholarly journals Structure of the retinal chromophore in sensory rhodopsin I from resonance Raman spectroscopy

1989 ◽  
Vol 264 (31) ◽  
pp. 18280-18283
Author(s):  
S P Fodor ◽  
R Gebhard ◽  
J Lugtenburg ◽  
R A Bogomolni ◽  
R A Mathies
Keyword(s):  
Raman Spectroscopy ◽  
Resonance Raman Spectroscopy ◽  
Resonance Raman ◽  
Sensory Rhodopsin ◽  
Retinal Chromophore ◽  
Sensory Rhodopsin I
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