A ready‐to‐use fluorescence probe of Pd 2+ in water: novel tricyclic heterocyclic base on 1,3,4‐ Oxadiazole

Luminescence ◽  
2021 ◽  
Author(s):  
Ke Su ◽  
Xiaomei Huang ◽  
Wei Wei ◽  
Xiaotong Zeng ◽  
Siyu Xiang ◽  
...  
2020 ◽  
Author(s):  
Junxia Ren ◽  
Yaozu Liu ◽  
Xin Zhu ◽  
Yangyang Pan ◽  
Yujie Wang ◽  
...  

<p><a></a><a></a><a></a><a></a><a></a><a></a><a></a><a>The development of highly-sensitive recognition of </a><a></a><a></a><a></a><a></a><a>hazardous </a>chemicals, such as volatile organic compounds (VOCs) and polycyclic aromatic hydrocarbons (PAHs), is of significant importance because of their widespread social concerns related to environment and human health. Here, we report a three-dimensional (3D) covalent organic framework (COF, termed JUC-555) bearing tetraphenylethylene (TPE) side chains as an aggregation-induced emission (AIE) fluorescence probe for sensitive molecular recognition.<a></a><a> </a>Due to the rotational restriction of TPE rotors in highly interpenetrated framework after inclusion of dimethylformamide (DMF), JUC-555 shows impressive AIE-based strong fluorescence. Meanwhile, owing to the large pore size (11.4 Å) and suitable intermolecular distance of aligned TPE (7.2 Å) in JUC-555, the obtained material demonstrates an excellent performance in the molecular recognition of hazardous chemicals, e.g., nitroaromatic explosives, PAHs, and even thiophene compounds, via a fluorescent quenching mechanism. The quenching constant (<i>K</i><sub>SV</sub>) is two orders of magnitude better than those of other fluorescence-based porous materials reported to date. This research thus opens 3D functionalized COFs as a promising identification tool for environmentally hazardous substances.</p>


2013 ◽  
Vol 30 (5) ◽  
pp. 555
Author(s):  
Shaoguang GENG ◽  
Xiaoying JIANG ◽  
Fengling CUI ◽  
Lei SHI

1979 ◽  
Vol 44 (2) ◽  
pp. 613-625 ◽  
Author(s):  
Valentina I. Gulyaeva ◽  
Antonín Holý

The present paper studies the effect of the modification of heterocyclic base, sugar moiety and the presence of phosphate group on the nucleoside acceptors in the synthesis of dinucleoside phosphates from adenosine 2',3'-cyclic phosphate as donor, catalyzed by nonspecific acidic extracellular and intracellular ribonucleases from Penicillium claviforme. The enzyme binds specifically the acceptor molecule, preferring cytosine nucleosides. It requires the presence of the whole sugar moiety, an exact mutual orientation of the heterocyclic base and the reaction center (5'-hydroxy group), and a suitable conformation of the acceptor molecule. The enzyme-acceptor bond is homochiral and the presence of the N3-H group in the pyrimidine ring is important. The reaction between the donor and the acceptor is bimolecular and is competitively inhibited by some purine nucleosides.


2021 ◽  
Vol 188 (7) ◽  
Author(s):  
Yuedi Ding ◽  
Zhenqiang Fan ◽  
Bo Yao ◽  
Dong Xu ◽  
Minhao Xie ◽  
...  

2021 ◽  
Vol 235 ◽  
pp. 118056
Author(s):  
Rongzhi Chen ◽  
Kuo Zhan ◽  
Yizhou Xing ◽  
Zhaolong Wang ◽  
Yabin Zhu ◽  
...  
Keyword(s):  

Author(s):  
Haoyuan Yin ◽  
Haijun Chi ◽  
Zhuye Shang ◽  
Ali Qaitoon ◽  
Jianfei Yu ◽  
...  

Author(s):  
Jianbin Chao ◽  
Jiamin Zhao ◽  
Yongbin Zhang ◽  
Fangjun Huo ◽  
Caixia Yin ◽  
...  

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