In Situ Controlled Promotion of Catalyst Surfaces Via Solid Electrolytes: The NEMCA Effect

1995 ◽  
Vol 99 (11) ◽  
pp. 1393-1401 ◽  
Author(s):  
Constantinos G. Vayenas ◽  
Ioannis V. Yentekakis ◽  
Symeon I. Bebelis ◽  
Stylianos G. Neophytides
Keyword(s):  
Solid Electrolytes ◽  
Nemca Effect ◽  
Catalyst Surfaces

ChemInform Abstract: Solid Electrolytes for in situ Promotion of Catalyst Surfaces: The NEMCA Effect

ChemInform ◽  
2010 ◽  
Vol 24 (49) ◽  
pp. no-no ◽  
Author(s):  
C. G. VAYENAS ◽  
S. BEBELIS ◽  
I. V. YENTEKAKIS ◽  
P. TSIAKARAS ◽  
H. KARASALI ◽  
...  
Keyword(s):  
Solid Electrolytes ◽  
Nemca Effect ◽  
Catalyst Surfaces

In situ controlled promotion of catalyst surfaces via solid electrolytes: Ethylene oxidation on Rh and propylene oxidation on Pt

Ionics ◽  
1995 ◽  
Vol 1 (2) ◽  
pp. 159-164 ◽  
Author(s):  
A. C. Kaloyannis ◽  
C. A. Pliangos ◽  
I. V. Yentekakis ◽  
C. G. Vayenas
Keyword(s):  
Solid Electrolytes ◽  
Ethylene Oxidation ◽  
Propylene Oxidation ◽  
Catalyst Surfaces

In situ infrared approach to unravel reaction intermediates and pathways on catalyst surfaces

2019 ◽  
Vol 45 (12) ◽  
pp. 5831-5847 ◽  
Author(s):  
Jaelynne King ◽  
Cheng Liu ◽  
Steven S. C. Chuang
Keyword(s):  
Reaction Intermediates ◽  
Catalyst Surfaces

scholarly journals In Situ Investigation of Interphase and Microstructure Effects on the Chemo-Mechanics of Thiophosphate Solid Electrolytes

2020 ◽  
Author(s):  
Marm Dixit ◽  
Nikhilendra Singh ◽  
James Horwath ◽  
Pavel Shevchenko ◽  
Eric Stach ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Solid Electrolytes ◽  
Mechanical Performance ◽  
Iodine Doping ◽  
Fracture Region ◽  
In Situ Investigation ◽  
Electrochemical Cycling ◽  
Solid State Batteries ◽  
Processing Techniques

<p>Lithium thiophosphates (Li3PS4, LPS) are promising solid electrolytes for safe, energy dense solid-state batteries. However, chemo-mechanical transformations within the bulk solid electrolyte and at solidjsolid interfaces can lead to lithium filament formation and fracture-induced failure. The interdependent role of kinetically stable interphases and electrolyte microstructures on the onset and propagation of fracture is not clearly understood. Here, we investigate the effect of interphase chemistry and microstructure on the chemo-mechanical performance of LPS electrolytes. Kinetically metastable interphases are engineered with iodine doping and microstructural control is achieved using milling and annealing processing techniques. In situ transmission electron microscopy reveals how iodine diffuses to the interphase and upon electrochemical cycling pores are formed in the interphase region. Pores/voids formed in the interphase are chemo-mechanically driven via directed ion transport. In situ synchrotron tomography reveals that interphase pore formation drives edge fracture events which are the origin of through-plane fracture failure. Active Li metal has a tendency to fill the fracture region. Cycling lithium in fracture sites leads to localized stress within the solid electrolyte which accumulates and ultimately leads to catastrophic failure. Fractures in thiophosphate electrolytes actively grow toward regions of higher porosity and are impacted by heterogenity in solid electrolyte microstructure (e.g. porosity factor).</p>

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