Thermodynamics of the formation of aromatic radical anions and thermodynamics of solvated electrons in liquid ammonia

1981 ◽  
Vol 85 (2) ◽  
pp. 112-116 ◽  
Author(s):  
W. Gross ◽  
U. Schindewolf
Keyword(s):  
Liquid Ammonia ◽  
Radical Anions ◽  
Solvated Electrons ◽  
Aromatic Radical

Stabile Radikalanionen von Aromaten: Strahlenchemische Erzeugung in Gegenwart von Natrium-dihydridobis( 2-methoxyethoxy) aluminat

1990 ◽  
Vol 45 (2) ◽  
pp. 157-160 ◽  
Author(s):  
Nikola Getoff ◽  
Matthias W. Haenel ◽  
Knut Hildenbrand ◽  
Udo-Burckhard Richter ◽  
Sonja Solar
Keyword(s):  
Ionizing Radiation ◽  
Room Temperature ◽  
Radical Anions ◽  
X Rays ◽  
Solvated Electrons ◽  
Aromatic Radical ◽  
Counter Ions ◽  
Vis Spectroscopy

AbstractArenes are reduced at room temperature to their very long-lived radical anions by exposing the solution of the arene and NaAlH2(OCH2CH2OCH3 )2 (1) in dimethoxyethane (DME) to an ionizing radiation (electrons, gamma- or X-rays) for few minutes:Thereby 1 is acting as a scavenger for the solvent counter ions which are produced concomitantly to solvated electrons by the radiolysis. The method is very convenient for the ESR and UV-VIS spectroscopy of aromatic radical anions.

Electron affinities of benzaldehydes. Substituent effects on stabilities of aromatic radical anions

1993 ◽  
Vol 34 (26) ◽  
pp. 4223-4226 ◽  
Author(s):  
Masaaki Mishima ◽  
Chul Huh ◽  
Hirotaka Nakamura ◽  
Mizue Fujio ◽  
Yuho Tsuno
Keyword(s):  
Substituent Effects ◽  
Radical Anions ◽  
Electron Affinities ◽  
Aromatic Radical

ChemInform Abstract: Polarized Absorption Spectra of Some Aromatic Radical Anions in Stretched Polyethylene Films

ChemInform ◽  
1990 ◽  
Vol 21 (3) ◽  
Author(s):  
Y. KUBOZONO ◽  
M. ATA ◽  
M. AOYAGI ◽  
T. FUJITA ◽  
N. FUKAMI ◽  
...  
Keyword(s):  
Absorption Spectra ◽  
Radical Anions ◽  
Polyethylene Films ◽  
Aromatic Radical

Electron affinities of acetophenones and methyl benzoates. Varying resonance demand of aromatic radical anions

1995 ◽  
Vol 36 (13) ◽  
pp. 2265-2268 ◽  
Author(s):  
Masaaki Mishima ◽  
Chul Huh ◽  
Hai Whang Lee ◽  
Hirotaka Nakamura ◽  
Mizue Fujio ◽  
...  
Keyword(s):  
Radical Anions ◽  
Electron Affinities ◽  
Aromatic Radical

Effects of quaternary ammonium salts on reactions of aromatic radical anions formed in tetrahydrofuran by pulse radiolysis

1984 ◽  
Vol 88 (11) ◽  
pp. 2368-2372 ◽  
Author(s):  
Yukio Yamamoto ◽  
Shoichi Nishida ◽  
Katsuyoshi Yabe ◽  
Koichiro Hayashi ◽  
Seishi Takeda ◽  
...  
Keyword(s):  
Quaternary Ammonium ◽  
Pulse Radiolysis ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
Radical Anions ◽  
Aromatic Radical
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