P. Diehl et al. (Eds.): NMR Basic Principles and Progress, Vol. 15: A. Steigel and H. W. Spiess: Dynamic NMR Spectroscopy. Springer Verlag, Berlin, Heidelberg, New York 1978

1978 ◽  
Vol 82 (10) ◽  
pp. 1121-1121
Keyword(s):  
New York ◽  
Nmr Spectroscopy ◽  
Dynamic Nmr ◽  
Basic Principles ◽  
Dynamic Nmr Spectroscopy

scholarly journals Über die Konformation yon 1.2.4.5-Tetrathian / On the Conformation of 1,2,4,5-Tetrathiane

1982 ◽  
Vol 37 (2) ◽  
pp. 234-235 ◽  
Author(s):  
Rudy Susilo ◽  
Rolf Gmelin
Keyword(s):  
Experimental Data ◽  
Nmr Spectroscopy ◽  
Force Field ◽  
Excellent Agreement ◽  
Dynamic Nmr ◽  
Force Field Calculations ◽  
Chair Form ◽  
Dynamic Nmr Spectroscopy ◽  
Twist Form

Abstract The conformation of 1,2,4,5-tetrathian was determined by means of dynamic NMR spectroscopy. The barrier (ilG+) of the chair/twist equilibration is 14.5 kcal/mol and the chair form is more stable than the twist form in this molecule by 1.4 kcal/mol. These experimental data are in excellent agreement with force field calculations

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