Studies of Intermolecular Interactions by Matrix Isolation Vibrational Spectroscopy

1978 ◽  
Vol 82 (1) ◽  
pp. 45-46 ◽  
Author(s):  
A. J. Barnes
Keyword(s):  
Intermolecular Interactions ◽  
Vibrational Spectroscopy ◽  
Matrix Isolation

Alkene-halogen complexes studied by matrix isolation vibrational spectroscopy

1982 ◽  
Vol 12 (2) ◽  
pp. 162-164 ◽  
Author(s):  
S. Holroyd ◽  
A. J. Barnes ◽  
S. Suzuki ◽  
W. J. Orville-Thomas
Keyword(s):  
Vibrational Spectroscopy ◽  
Matrix Isolation

Hydrogen sulphide – halogen complexes studied by matrix isolation vibrational spectroscopy

1985 ◽  
Vol 63 (7) ◽  
pp. 1705-1707 ◽  
Author(s):  
U. P. Agarwal ◽  
A. J. Barnes ◽  
W. J. Orville-Thomas
Keyword(s):  
Low Temperature ◽  
Vibrational Spectroscopy ◽  
Infrared Spectra ◽  
Hydrogen Sulphide ◽  
Matrix Isolation ◽  
Reaction Products ◽  
Hydrogen Halides ◽  
Stretching Vibration

Infrared spectra are reported of mixtures of hydrogen sulphide with chlorine or bromine in low-temperature argon or nitrogen matrices. The H2S … Cl2 and H2S … Br2 complexes were identified from the perturbed halogen stretching vibration. Absorptions due to the corresponding hydrogen halides provided evidence that reaction was occurring between the hydrogen sulphide and halogen (despite the use of a twin-jet deposition), and other reaction products were tentatively identified from the observed absorptions.

Analytical Applications of Matrix Isolation Fourier Transform Infrared Spectroscopy

1982 ◽  
Vol 36 (4) ◽  
pp. 339-347 ◽  
Author(s):  
G. Mamantov ◽  
A. A. Garrison ◽  
E. L. Wehry
Keyword(s):  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Fourier Transform Infrared Spectroscopy ◽  
Vibrational Spectroscopy ◽  
Matrix Isolation ◽  
Fourier Transform Infrared ◽  
Chromatographic Separations ◽  
Analytical Applications ◽  
Matrix Isolation Spectroscopy ◽  
Ft Ir

A review of analytical applications of matrix isolation Fourier transform infrared spectroscopy is presented. The characteristics of matrix isolation spectroscopy are discussed along with practical techniques for obtaining analytically useful results. A few studies relating to matrix isolation used in conjunction with Raman and conventional IR spectroscopy are reviewed. The majority of analytical applications of matrix isolation vibrational spectroscopy has entailed the use of FT-IR techniques. Qualitative and quantitative results from a number of sample types are presented. The coupling of matrix isolation vibrational spectroscopy with chromatographic separations is reviewed.

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