The characterization of porous solids by gas adsorption

1975 ◽  
Vol 79 (9) ◽  
pp. 724-730 ◽  
Author(s):  
Kenneth S. W. Sing
Keyword(s):  
Gas Adsorption ◽  
Porous Solids

scholarly journals Structure and Stability of Gas Adsorption Complexes in Periodic Porous Solids as Studied by VTIR Spectroscopy: An Overview

2020 ◽  
Vol 10 (23) ◽  
pp. 8589
Author(s):  
Montserrat R. Delgado
Keyword(s):  
Gas Adsorption ◽  
Variable Temperature ◽  
Spectroscopic Technique ◽  
Porous Solids ◽  
Large Temperature ◽  
Adsorption Complexes ◽  
The Stability ◽  
Standard Enthalpy Change

Variable-temperature infrared (VTIR) spectroscopy is an instrumental technique that enables structural characterization of gas-solid adsorption complexes by analysis of meaningful vibrational modes, and simultaneous determination of the standard enthalpy change (ΔH0) involved in the gas adsorption process, which allows one to quantify the stability of the corresponding complex. This is achieved by a van’t Hoff analysis of a set of IR spectra recorded over a sufficiently large temperature range. Herein, the use of this versatile spectroscopic technique is demonstrated by reviewing its application to the study of carbon monoxide, carbon dioxide and dinitrogen adsorption on several (alkaline) zeolites, which can be regarded as the archetype of periodic porous solids.

The Characterization of Porous Solids from Gas Adsorption Measurements

1995 ◽  
Vol 115 ◽  
pp. 21-44 ◽  
Author(s):  
C.K. Lee ◽  
Antony S.T. Chiang ◽  
C.S. Tsay
Keyword(s):  
Gas Adsorption ◽  
Porous Solids

scholarly journals Geologic characterization of a lower Cambrian marine shale: Implications for shale gas potential in northwestern Hunan, South China

2018 ◽  
Vol 6 (3) ◽  
pp. T635-T647 ◽  
Author(s):  
Zhenghui Xiao ◽  
Jisong Liu ◽  
Jingqiang Tan ◽  
Rongfeng Yang ◽  
Jason Hilton ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
South China ◽  
Lower Cambrian ◽  
Gas Adsorption ◽  
Vitrinite Reflectance ◽  
Mean Value ◽  
Hunan Province ◽  
Quartz Content ◽  
Gas Potential

We have investigated the geologic features of the lower Cambrian-aged Niutitang Shale in the northwestern Hunan province of South China. Our results indicate that the Niutitang Shale has abundant and highly mature algal kerogen with total organic carbon (TOC) content ranging from 0.6% to 18.2%. The equivalent vitrinite reflectance (equal-Ro) value is between 2.5% and 4.3%. Mineral constituents are dominated by quartz and clay. The average quartz content (62.8%) is much higher than that of clay minerals (26.1%), and this suggests a high brittleness index. Organic-matter pores, interparticle pores, intraparticle pores, interlaminated fractures, and structural fractures are all well developed. The porosity ranges from 0.6% to 8.8%, with an average of 4.8%, whereas the permeability varies from 0.0018 to [Formula: see text] (microdarcy) (averaging [Formula: see text]). The porosity of TOC- and clay-rich shale samples is generally higher than that of quartz-rich shale samples. The gas adsorption capacity of the Niutitang Shale varies from 2.26 to [Formula: see text], with a mean value of [Formula: see text]. The TOC content appears to significantly influence gas adsorption capacity. In general, TOC-rich samples exhibit a much higher adsorption capacity than TOC-poor samples.

High-Resolution Characterization of Preferential Gas Adsorption at the Graphene–Water Interface

Langmuir ◽  
2016 ◽  
Vol 32 (43) ◽  
pp. 11164-11171 ◽  
Author(s):  
Hsien-Chen Ko ◽  
Wei-Hao Hsu ◽  
Chih-Wen Yang ◽  
Chung-Kai Fang ◽  
Yi-Hsien Lu ◽  
...  
Keyword(s):  
High Resolution ◽  
Gas Adsorption ◽  
Water Interface
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