Electron-Transfer Processes in Non-Aqueous Solutions and Some Intermediate Complexes

1963 ◽  
Vol 67 (8) ◽  
pp. 763-774 ◽  
Author(s):  
M. Szwarc
Keyword(s):  
Electron Transfer ◽  
Aqueous Solutions ◽  
Transfer Processes ◽  
Electron Transfer Processes

A study of the mechanism of photochemical electron transfer processes in solution

1959 ◽  
Vol 253 (1273) ◽  
pp. 154-162 ◽  
Keyword(s):  
Electron Transfer ◽  
Aqueous Solutions ◽  
Potassium Hydroxide ◽  
Flash Photolysis ◽  
Water Solution ◽  
Solvent Molecule ◽  
Methyl Cyanide ◽  
Transfer Processes ◽  
Production Of Hydrogen ◽  
Electron Transfer Processes

The flash photolysis of halide solutions yields unstable species believed to be the dihalide ion the absorption spectrum of which we have observed and photographed. This transient has been noted during the photolysis of ( а ) the aqueous solutions of KCl, KBr, KI, HCl, NaCl, NaBr, NH 4 C1, MgCl 2 , HgCl 2 , CaCl 2 and SrCl 2 , ( b ) the ethyl and methyl alcoholic solutions of KBr and KI, ( c ) the methyl cyanide solution of KI. The effect of the addition of sulphuric acid, potassium hydroxide and Mn 2+ ion to certain of the solutions has also been studied. Our interpretation of the results of the flash photolysis of KI in solution, based on the Rigg & Weiss mechanism of electron transfer, involves the postulation of the splitting of the solvent molecule. In water solution, this would mean the formation of hydrogen. The production of hydrogen in aqueous solutions of KI of pH 6 to 7 has been confirmed by an investigation of the steady state photolysis.

Electron-transfer processes induced by the triplet state of pterins in aqueous solutions

2010 ◽  
Vol 49 (6) ◽  
pp. 1014-1022 ◽  
Author(s):  
M. Laura Dántola ◽  
Mariana Vignoni ◽  
Constanza González ◽  
Carolina Lorente ◽  
Patricia Vicendo ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Aqueous Solutions ◽  
Triplet State ◽  
Transfer Processes ◽  
Electron Transfer Processes

scholarly journals RuIII(edta) complexes as molecular redox catalysts in chemical and electrochemical reduction of dioxygen and hydrogen peroxide: inner-sphere versus outer-sphere mechanism

RSC Advances ◽  
2021 ◽  
Vol 11 (35) ◽  
pp. 21359-21366
Author(s):  
Debabrata Chatterjee ◽  
Marta Chrzanowska ◽  
Anna Katafias ◽  
Maria Oszajca ◽  
Rudi van Eldik
Keyword(s):  
Hydrogen Peroxide ◽  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Molecular Oxygen ◽  
Outer Sphere ◽  
Transfer Processes ◽  
Edta Complexes ◽  
Inner Sphere ◽  
Electron Transfer Processes ◽  
Sphere Mechanism

[RuII(edta)(L)]2–, where edta4– =ethylenediaminetetraacetate; L = pyrazine (pz) and H2O, can reduce molecular oxygen sequentially to hydrogen peroxide and further to water by involving both outer-sphere and inner-sphere electron transfer processes.

Photoinduced electron transfer in mechanically interlocked suit[3]ane systems

2021 ◽  
Author(s):  
Anton J Stasyuk ◽  
Olga A. Stasyuk ◽  
Miquel Solà ◽  
Alexander Voityuk
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
New Class ◽  
Transfer Processes ◽  
Two Component ◽  
Electron Transfer Processes

Suitanes, a new class of two-component mechanically interlocked systems, have recently been developed. In this work, we report a detailed study of photoinduced electron transfer processes in the suit[3]anes consisting...

scholarly journals Regulation of electron transfer processes affects phototrophic mat structure and activity

2015 ◽  
Vol 6 ◽  
Author(s):  
Phuc T. Ha ◽  
Ryan S. Renslow ◽  
Erhan Atci ◽  
Patrick N. Reardon ◽  
Stephen R. Lindemann ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Transfer Processes ◽  
Electron Transfer Processes ◽  
Structure And Activity

Effects of electron-transfer processes on conformation

1986 ◽  
Vol 19 (10) ◽  
pp. 300-306 ◽  
Author(s):  
Walter Huber ◽  
Klaus Muellen
Keyword(s):  
Electron Transfer ◽  
Transfer Processes ◽  
Electron Transfer Processes
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