scholarly journals Pyridine Complexes as Tailored Precursors for Rapid Synthesis of Thiophosphate Superionic Conductors

2021 ◽  
Author(s):  
Michael Ghidiu ◽  
Roman Schlem ◽  
Wolfgang G. Zeier
Keyword(s):  
Superionic Conductors ◽  
Rapid Synthesis ◽  
Pyridine Complexes

Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries

2020 ◽  
Vol 13 (5) ◽  
pp. 1429-1461 ◽  
Author(s):  
Xiaona Li ◽  
Jianwen Liang ◽  
Xiaofei Yang ◽  
Keegan R. Adair ◽  
Changhong Wang ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Lithium Batteries ◽  
Electrochemical Stability ◽  
Superionic Conductors ◽  
Fundamental Understanding ◽  
Potential Applications ◽  
Synthesis Routes

This review focuses on fundamental understanding, various synthesis routes, chemical/electrochemical stability of halide-based lithium superionic conductors, and their potential applications in energy storage as well as related challenges.

Modified Solid-Phase Methods for the Rapid Synthesis of Opioid Peptides

1991 ◽  
Author(s):  
Richard A. Houghten ◽  
◽  
John M. Ostresh ◽  
Suzanne M. Pratt
Keyword(s):  
Opioid Peptides ◽  
Solid Phase ◽  
Rapid Synthesis

Features of the thermodynamics of superionic conductors

1982 ◽  
Vol 136 (4) ◽  
pp. 693 ◽  
Author(s):  
Yu.Ya. Gurevich ◽  
Yu.I. Kharkats
Keyword(s):  
Superionic Conductors

Exogenous Directing Group Free, Ligand-Enabled gamma-C(sp3)–H Arylation of Free Primary Aliphatic Amines and α-Amino Esters

2019 ◽  
Author(s):  
Yongzheng Ding ◽  
Shuai Fan ◽  
Xiaoxi Chen ◽  
yuzhen gao ◽  
Gang Li
Keyword(s):  
Amino Acids ◽  
Large Scale ◽  
Free Ligand ◽  
Aliphatic Amines ◽  
Rapid Synthesis ◽  
Amino Esters ◽  
Directing Group ◽  
Large Scale Synthesis ◽  
Primary Aliphatic Amines

A Pdᴵᴵ-catalyzed, ligand-enabled gamma-C(sp3)–H arylation of free primary aliphatic amines and amino esters without using an exogenous directing group is reported. This reaction is compatible with unhindered free aliphatic amines, and it is also be applicable to the rapid synthesis of biologically and synthetically valuable unnatural α-amino acids. Large scale synthesis is also feasible using this method.<br>

Rapid Crystallization and Kinetic Freezing of Site-Disorder in the Lithium Superionic Argyrodite Li6PS5Br

2019 ◽  
Author(s):  
Ajay Gautam ◽  
Marcel Sadowski ◽  
Nils Prinz ◽  
Henrik Eickhoff ◽  
Nicolo Minafra ◽  
...  
Keyword(s):  
Elevated Temperatures ◽  
Synthesis Method ◽  
Reaction Times ◽  
Ionic Conductivities ◽  
Ionic Transport ◽  
High Energy ◽  
Superionic Conductors ◽  
Rapid Crystallization ◽  
Site Disorder ◽  
Fast Cooling

<p>Lithium argyrodite superionic conductors are currently being investigated as solid electrolytes for all-solid-state batteries. Recently, in the lithium argyrodite Li<sub>6</sub>PS<sub>5</sub>X (X = Cl, Br, I), a site-disorder between the anionsS<sup>2–</sup>and X<sup>–</sup>has been observed, which strongly affects the ionic transport and appears to be a function of the halide present. In this work, we show how such disorder in Li<sub>6</sub>PS<sub>5</sub>Br can be engineered <i>via</i>the synthesis method. By comparing fast cooling (<i>i.e. </i>quenching) to more slowly cooled samples, we find that anion site-disorder is higher at elevated temperatures, and that fast cooling can be used to kinetically trap the desired disorder, leading to higher ionic conductivities as shown by impedance spectroscopy in combination with <i>ab-initio</i>molecular dynamics. Furthermore, we observe that after milling, a crystalline lithium argyrodite can be obtained within one minute of heat treatment. This rapid crystallization highlights the reactive nature of mechanical milling and shows that long reaction times with high energy consumption are not needed in this class of materials. The fact that site-disorder induced <i>via</i>quenching is beneficial for ionic transport provides an additional approach for the optimization and design of lithium superionic conductors.</p>

Rapid Synthesis of Mesoporous Nickel Phosphates under Microwave Assisted Hydrothermal Condition

2012 ◽  
Vol 27 (5) ◽  
pp. 501-506
Author(s):  
Xu-Ying LI ◽  
Juan TAN ◽  
Jian-Hua YANG ◽  
Jing LIU ◽  
Fei YANG
Keyword(s):  
Hydrothermal Condition ◽  
Rapid Synthesis ◽  
Microwave Assisted ◽  
Nickel Phosphates

A Facile and Microwave-assisted Rapid Synthesis of 2-Arylamino-4-(3′-indolyl)- thiazoles as Apoptosis Inducing Cytotoxic Agents

2017 ◽  
Vol 17 (3) ◽  
pp. 442-455 ◽  
Author(s):  
Mukund Tantak ◽  
Dipanwita Mukherjee ◽  
Anil Kumar ◽  
Gopal Chakrabarti ◽  
Dalip Kumar
Keyword(s):  
Cytotoxic Agents ◽  
Rapid Synthesis ◽  
Microwave Assisted

Microwave-assisted Iodine-catalyzed Rapid Synthesis of 6H-indolo[2,3-b] quinolines: Formal Synthesis of Cryptotackieine

2017 ◽  
Vol 4 (3) ◽  
Author(s):  
Prakash T. Parvatkar ◽  
Perunninakulath S. Parameswaran ◽  
Debasish Bandyopadhyay ◽  
Sanghamitra Mukherjee ◽  
Bimal K. Banik
Keyword(s):  
Rapid Synthesis ◽  
Formal Synthesis ◽  
Microwave Assisted
Sign in / Sign up

Export Citation Format

Share Document