scholarly journals Assessing the Ion Transport Properties of Highly Concentrated Non‐Flammable Electrolytes in a Commercial Li‐Ion Battery Cell

2019 ◽  
Vol 3 (1) ◽  
pp. 117-125 ◽  
Author(s):  
Fabian Sälzer ◽  
Lars Pateras Pescara ◽  
Felix Franke ◽  
Clemens Müller ◽  
Jacqueline Winkler ◽  
...  
Author(s):  
Satadru Dey ◽  
Beshah Ayalew

This paper proposes and demonstrates an estimation scheme for Li-ion concentrations in both electrodes of a Li-ion battery cell. The well-known observability deficiencies in the two-electrode electrochemical models of Li-ion battery cells are first overcome by extending them with a thermal evolution model. Essentially, coupling of electrochemical–thermal dynamics emerging from the fact that the lithium concentrations contribute to the entropic heat generation is utilized to overcome the observability issue. Then, an estimation scheme comprised of a cascade of a sliding-mode observer and an unscented Kalman filter (UKF) is constructed that exploits the resulting structure of the coupled model. The approach gives new real-time estimation capabilities for two often-sought pieces of information about a battery cell: (1) estimation of cell-capacity and (2) tracking the capacity loss due to degradation mechanisms such as lithium plating. These capabilities are possible since the two-electrode model needs not be reduced further to a single-electrode model by adding Li conservation assumptions, which do not hold with long-term operation. Simulation studies are included for the validation of the proposed scheme. Effect of measurement noise and parametric uncertainties is also included in the simulation results to evaluate the performance of the proposed scheme.


2016 ◽  
Author(s):  
Hiroki Nagai ◽  
Masahiro Morita ◽  
Koichi Satoh

2019 ◽  
Vol 25 (36) ◽  
pp. 253-262 ◽  
Author(s):  
Andreas Nyman ◽  
Tommy G. Zavalis ◽  
Ragna Elger ◽  
Maårten Behm ◽  
Göran Lindbergh

2015 ◽  
Vol 3 (42) ◽  
pp. 21343-21350 ◽  
Author(s):  
Stefan Breuer ◽  
Denise Prutsch ◽  
Qianli Ma ◽  
Viktor Epp ◽  
Florian Preishuber-Pflügl ◽  
...  

Impedance spectroscopy measurements down to very low temperatures allowed for resolving bulk ion transport properties in highly conducting ceramic electrolytes.


2014 ◽  
Vol 38 (11) ◽  
pp. 1424-1437 ◽  
Author(s):  
Yasir Abdul-Quadir ◽  
Tomi Laurila ◽  
Juha Karppinen ◽  
Kirsi Jalkanen ◽  
Kai Vuorilehto ◽  
...  

Energies ◽  
2020 ◽  
Vol 13 (9) ◽  
pp. 2387
Author(s):  
Van-Thanh Ho ◽  
Kyoungsik Chang ◽  
Sang Wook Lee ◽  
Sung Han Kim

This paper presents a three-dimensional modeling approach to simulate the thermal performance of a Li-ion battery module for a new urban car. A single-battery cell and a 52.3 Ah Li-ion battery module were considered, and a Newman, Tiedemann, Gu, and Kim (NTGK) model was adopted for the electrochemical modeling based on input parameters from the discharge experiment. A thermal–electrochemical coupled method was established to provide insight into the temperature variations over time under various discharge conditions. The distribution temperature of a single-battery cell was predicted accurately. Additionally, in a 5C discharge condition without a cooling system, the temperature of the battery module reached 114 °C, and the temperature difference increased to 25 °C under a 5C discharging condition. This condition led to the activation of thermal runaway and the possibility of an explosion. However, the application of a reasonable fan circulation and position reduced the maximum temperature to 49.7 °C under the 5C discharge condition. Moreover, accurate prediction of the temperature difference between cell areas during operation allowed for a clear understanding and design of an appropriate fan system.


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