Proton‐Conducting Hydrogen‐Bonded 3D Frameworks of Imidazo‐Pyridine‐Based Coordination Complexes Containing Naphthalene Disulfonates in Rhomboid Channels

2019 ◽  
Vol 14 (23) ◽  
pp. 4389-4394 ◽  
Author(s):  
Abhijit Garai ◽  
Anaparthi Ganesh Kumar ◽  
Susanta Banerjee ◽  
Kumar Biradha
Keyword(s):  
Coordination Complexes ◽  
Proton Conducting ◽  
Hydrogen Bonded

Proton-Conducting Hydrogen-Bonded Organic Frameworks

2021 ◽  
pp. 4431-4453
Author(s):  
Shyam Chand Pal ◽  
Debolina Mukherjee ◽  
Rupam Sahoo ◽  
Supriya Mondal ◽  
Madhab C. Das
Keyword(s):  
Proton Conducting ◽  
Hydrogen Bonded

Synthesis and proton-conducting performance of crystalline hydrogen-bonded organic networks

2020 ◽  
Vol 290 ◽  
pp. 121550
Author(s):  
Mei-Jie Wei ◽  
Bo Li ◽  
Heng-Ye Li ◽  
Lin Zhang ◽  
Yu-Ting Luo ◽  
...  
Keyword(s):  
Proton Conducting ◽  
Organic Networks ◽  
Hydrogen Bonded

Hydrogen-Bonded Networks Featuring Yttrium(III) Complexes of N,N’-Dimethylurea (DMU): Preparation and Characterization of [Y(DMU)6][YCl6] and [Y(NO3)3(DMU)3]

2005 ◽  
Vol 60 (4) ◽  
pp. 363-372 ◽  
Author(s):  
Athanassios K. Boudalis ◽  
Vassilios Nastopoulos ◽  
Catherine P. Raptopoulou ◽  
Aris Terzis ◽  
Spyros P. Perlepes
Keyword(s):  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Single Crystal ◽  
Crystal Engineering ◽  
Coordination Complexes ◽  
3D Network ◽  
3D Architecture ◽  
Intramolecular Hydrogen ◽  
Hydrogen Bonded

In order to examine the possibility of using yttrium(III) in the crystal engineering of hydrogenbonded coordination complexes and to compare the molecular and supramolecular YIII/Cl3 or NO3-/DMU chemistry with the already well-developed LnIII/Cl− or NO3−/DMU chemistry (LnIII = lanthanide, DMU = N,N’-dimethylurea), compounds [Y(DMU)6][YCl6] (1) and [Y(NO3)3(DMU)3] (2) have been prepared. The structures of both compounds have been determined by single-crystal Xray diffraction. The structure of 1 consists of octahedral [Y(DMU)6]3+ and [YCl6]3− ions. The YIII ion in 2 is nine-coordinate and ligation is provided by three O-bonded DMU ligands and three bidentate chelating nitrato groups; the coordination polyhedron about the metal can be viewed as a distorted, monocapped square antiprism. The [Y(DMU)6]3+ cations and [YCl6]3− anions self-assemble to form a hydrogen-bonded 3D architecture in 1. Most of the hydrogen-bonding functionalities on the components of 2 create also a 3D network. Two motifs of interionic/intramolecular hydrogen-bonds have been observed: N-H···Cl in 1 and N-H···O(NO3−) in 2. The IR data are discussed in terms of the nature of bonding and the structures of the two complexes

Changes of coordination modes of Cu-based coordination complexes as tuneable proton-conducting solid electrolytes

2017 ◽  
Vol 5 (3) ◽  
pp. 1085-1093 ◽  
Author(s):  
Mei-Jie Wei ◽  
Jia-Qi Fu ◽  
Yi-Di Wang ◽  
Jing-Yang Gu ◽  
Bai-Ling Liu ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Coordination Compounds ◽  
Solid Electrolytes ◽  
Coordination Complexes ◽  
Sulfonate Group ◽  
Halide Ions ◽  
Proton Conducting ◽  
Coordination Modes ◽  
Group Coordination

We have synthesised three proton-conducting coordination complexes as solid proton-conducting electrolytes. Changes of sulfonate group coordination modes and different packing modes, as well as introduction of halide ions may remarkably enhance the proton conductivity of coordination compounds.

The crystal design of polar one-dimensional hydrogen-bonded copper coordination complexes

2016 ◽  
Vol 45 (8) ◽  
pp. 3398-3406 ◽  
Author(s):  
Kiyonori Takahashi ◽  
Norihisa Hoshino ◽  
Takashi Takeda ◽  
Koichiro Satomi ◽  
Yasutaka Suzuki ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Crystal Structures ◽  
Harmonic Generation ◽  
Coordination Complexes ◽  
Second Order ◽  
One Dimensional ◽  
Hydrogen Bonding Interactions ◽  
Copper Coordination ◽  
Crystal Design ◽  
Hydrogen Bonded

The crystal structures, polarities, and second-order harmonic generation activities of one-dimensional copper coordination complexes with hydrogen-bonding interactions were investigated.

Thermal solid state synthesis of coordination complexes from hydrogen bonded precursors

2005 ◽  
pp. 2457 ◽  
Author(s):  
Christopher J. Adams ◽  
Paul C. Crawford ◽  
A. Guy Orpen ◽  
Thomas J. Podesta ◽  
Benjamin Salt
Keyword(s):  
Solid State ◽  
Coordination Complexes ◽  
Solid State Synthesis ◽  
Hydrogen Bonded

Hydrogen bonded networks of coordination complexes

CrystEngComm ◽  
2001 ◽  
Vol 3 (51) ◽  
pp. 243 ◽  
Author(s):  
Alicia M. Beatty
Keyword(s):  
Coordination Complexes ◽  
Hydrogen Bonded

Diverse structural assemblies of silver–thiophene-2,5-dicarboxylate coordination complexes contribute to different proton-conducting performances

CrystEngComm ◽  
2016 ◽  
Vol 18 (40) ◽  
pp. 7814-7822 ◽  
Author(s):  
Xiao-Feng Zheng ◽  
Wen-Qiang Li ◽  
Jun Du ◽  
Xian-Zhu Luo ◽  
Miao-Miao Liu ◽  
...  
Keyword(s):  
Coordination Complexes ◽  
Proton Conducting

Water mediated proton conductance in a hydrogen-bonded Ni(ii)-bipyridine-glycoluril chloride self-assembled framework

CrystEngComm ◽  
2018 ◽  
Vol 20 (8) ◽  
pp. 1094-1100 ◽  
Author(s):  
Sakharam B. Tayade ◽  
Satish S. Bhat ◽  
Rajith Illathvalappil ◽  
Vishal M. Dhavale ◽  
Vitthal A. Kawade ◽  
...  
Keyword(s):  
Proton Conductance ◽  
Proton Conducting ◽  
Porous Framework ◽  
Self Assembled ◽  
Hydrogen Bonded

Proton conducting properties have been investigated in a new Ni(ii)-based hydrogen-bonded porous framework synthesized using bipyridine-glycoluril (BPG) tecton.

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