scholarly journals The Hiyama Cross‐Coupling Reaction at Parts Per Million Levels of Pd: In Situ Formation of Highly Active Spirosilicates in Glycol Solvents

2019 ◽  
Vol 14 (21) ◽  
pp. 3850-3854 ◽  
Author(s):  
Shun Ichii ◽  
Go Hamasaka ◽  
Yasuhiro Uozumi
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Highly Active ◽  
Cross Coupling Reaction ◽  
In Situ Formation

Synthesis, Characterization and Catalytic Utilization of a Ferrocene Diamidodiphosphane

2007 ◽  
Vol 72 (4) ◽  
pp. 453-467 ◽  
Author(s):  
Petr Štěpnička ◽  
Jiří Schulz ◽  
Ivana Císařová ◽  
Karla Fejfarová
Keyword(s):  
Phenylboronic Acid ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
Aryl Chlorides ◽  
Highly Active ◽  
Aryl Bromides ◽  
Cross Coupling Reaction

Amidation of 1'-(diphenylphosphanyl)ferrocene-1-carboxylic acid (Hdpf) with ethane-1,2-diamine afforded N,N'-ethylenebis[1'-(diphenylphosphanyl)ferrocene-1-carboxamide] (1), which was isolated in free and solvated form, 1·2AcOH. Both 1 and Hdpf were further converted to their respective phosphane sulfides, 2·2AcOH and 3 that were structurally characterized. Testing of the amidophosphane ligands in Suzuki-Miyaura cross-coupling reaction between phenylboronic acid and various aryl halides revealed that catalyst formed in situ from 1 and palladium(II) acetate is highly active in coupling reactions of aryl bromides whilst the corresponding aryl chlorides showed no or only poor conversions. The catalyst based on 2·2AcOH gave markedly lower yields of the coupling products.

scholarly journals Efficient in situ N-heterocyclic carbene palladium(ii) generated from Pd(OAc)2 catalysts for carbonylative Suzuki coupling reactions of arylboronic acids with 2-bromopyridine under inert conditions leading to unsymmetrical arylpyridine ketones: synthesis, characterization and cytotoxic activities

RSC Advances ◽  
2018 ◽  
Vol 8 (70) ◽  
pp. 40000-40015 ◽  
Author(s):  
Nedra Touj ◽  
Abdullah S. Al-Ayed ◽  
Mathieu Sauthier ◽  
Lamjed Mansour ◽  
Abdel Halim Harrath ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Suzuki Coupling ◽  
Boronic Acids ◽  
Cytotoxic Activities ◽  
Coupling Reactions ◽  
Component System ◽  
Arylboronic Acids ◽  
Cross Coupling Reaction

The in situ prepared four component system Pd(OAc)2, 1,3-dialkylbenzimidazolium halides 2a–i and 4a–i, K2CO3 under CO atmosphere catalyses carbonylative cross-coupling reaction of 2-bromopyridine with various boronic acids to yield unsymmetrical arylpyridine ketones.

scholarly journals A urea-modified tryptophan basedin situreducing and stabilizing agent for the fabrication of gold nanoparticles as a Suzuki–Miyaura cross-coupling catalyst in water

2019 ◽  
Vol 1 (4) ◽  
pp. 1380-1386 ◽  
Author(s):  
Supriya Sasmal ◽  
Mintu Debnath ◽  
Sujay Kumar Nandi ◽  
Debasish Haldar
Keyword(s):  
Gold Nanoparticles ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Stabilizing Agent ◽  
Cross Coupling Reaction ◽  
Reaction In Water

Urea modified tryptophan has been used as anin situreducing and stabilizing agent for the fabrication of gold nanoparticles and the gold nanoparticles efficiently catalyzed the Suzuki–Miyaura cross-coupling reaction in water.

Palladium nanoparticles supported on 1,3-dicyclohexylguanidine functionalized mesoporous silica SBA-15 as highly active and reusable catalyst for the Suzuki–Miyaura cross-coupling reaction

RSC Advances ◽  
2015 ◽  
Vol 5 (26) ◽  
pp. 20098-20107 ◽  
Author(s):  
Hojat Veisi ◽  
Abbas Amini Manesh ◽  
Neda Eivazi ◽  
Ali Reza Faraji
Keyword(s):  
Mesoporous Silica ◽  
Palladium Nanoparticles ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Reusable Catalyst ◽  
Suzuki Reactions ◽  
Highly Active ◽  
Functionalized Mesoporous Silica ◽  
Cross Coupling Reaction ◽  
Nano Catalyst

The synthesis and application of SBA-15/1,3-DCG/Pd as a novel heterogeneous and reusable nano catalyst in Suzuki reactions was described.

Analysis of the water extract of waste papaya bark ash and its implications as an in situ base in the ligand-free recyclable Suzuki–Miyaura coupling reaction

RSC Advances ◽  
2016 ◽  
Vol 6 (34) ◽  
pp. 28981-28985 ◽  
Author(s):  
Manashi Sarmah ◽  
Anindita Dewan ◽  
Manoj Mondal ◽  
Ashim J. Thakur ◽  
Utpal Bora
Keyword(s):  
Room Temperature ◽  
Water Extract ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Basic Medium ◽  
Low Temperature Combustion ◽  
Cross Coupling Reaction ◽  
Ligand Free ◽  
Temperature Combustion

The conversion of waste papaya-bark to ash–water extract via low-temperature combustion, and its utilization as an efficient and eco-friendly in situ basic medium for Suzuki–Miyaura cross-coupling reaction at room temperature are reported.

Sign in / Sign up

Export Citation Format

Share Document