Defect-Free Mixed-Matrix Membranes with Hydrophilic Metal-Organic Polyhedra for Efficient Carbon Dioxide Separation

2018 ◽  
Vol 13 (6) ◽  
pp. 631-635 ◽  
Author(s):  
Yang No Yun ◽  
Muhammad Sohail ◽  
Jong-Ho Moon ◽  
Tae Woo Kim ◽  
Kyeng Min Park ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Carbon Dioxide Separation ◽  
Metal Organic ◽  
Matrix Membranes

scholarly journals Metal Organic Framework — Based Mixed Matrix Membranes for Carbon Dioxide Separation: Recent Advances and Future Directions

2020 ◽  
Vol 8 ◽  
Author(s):  
Vengatesan Muthukumaraswamy Rangaraj ◽  
Mohammad A. Wahab ◽  
K. Suresh Kumar Reddy ◽  
George Kakosimos ◽  
Omnya Abdalla ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Framework ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Future Directions ◽  
Carbon Dioxide Separation ◽  
Recent Advances ◽  
Metal Organic ◽  
Organic Framework ◽  
Matrix Membranes

Amino-silane-grafted NH2-MIL-53(Al)/polyethersulfone mixed matrix membranes for CO2/CH4 separation

2019 ◽  
Vol 48 (36) ◽  
pp. 13555-13566 ◽  
Author(s):  
Farhad Ahmadijokani ◽  
Salman Ahmadipouya ◽  
Hossein Molavi ◽  
Mohammad Arjmand
Keyword(s):  
Carbon Dioxide ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Carbon Dioxide Separation ◽  
Amino Silane ◽  
Matrix Membranes

Mixed-matrix membranes (MMMs) are promising candidates for carbon dioxide separation.

scholarly journals Functionalized nanodiamonds in polyurethane mixed matrix membranes for carbon dioxide separation

2021 ◽  
pp. 100243
Author(s):  
AmirM. Norouzi ◽  
Ebrahim Nemati Lay ◽  
Arman Arabloonareh ◽  
Adel Hosseinkhani ◽  
Masoumeh Chapalaghi
Keyword(s):  
Carbon Dioxide ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Carbon Dioxide Separation ◽  
Matrix Membranes

Long-Term Stable Metal Organic Framework (MOF) Based Mixed Matrix Membranes for Ultrafiltration

2020 ◽  
Author(s):  
Muayad Al-shaeli ◽  
Stefan J. D. Smith ◽  
Shanxue Jiang ◽  
Huanting Wang ◽  
Kaisong Zhang ◽  
...  
Keyword(s):  
Contact Angle ◽  
Water Contact Angle ◽  
Mixed Matrix Membranes ◽  
Recovery Ratio ◽  
Mixed Matrix ◽  
Water Contact ◽  
Membrane Performance ◽  
Metal Organic ◽  
Matrix Membranes

<p>In this study, novel <a>mixed matrix polyethersulfone (PES) membranes</a> were synthesized by using two different kinds of metal organic frameworks (MOFs), namely UiO-66 and UiO-66-NH<sub>2</sub>. The composite membranes were characterised by SEM, EDX, FTIR, PXRD, water contact angle, porosity, pore size, etc. Membrane performance was investigated by water permeation flux, flux recovery ratio, fouling resistance and anti-fouling performance. The stability test was also conducted for the prepared mixed matrix membranes. A higher reduction in the water contact angle was observed after adding both MOFs to the PES and sulfonated PES membranes compared to pristine PES membranes. An enhancement in membrane performance was observed by embedding the MOF into PES membrane matrix, which may be attributed to the super-hydrophilic porous structure of UiO-66-NH<sub>2</sub> nanoparticles and hydrophilic structure of UiO-66 nanoparticles that could accelerate the exchange rate between solvent and non-solvent during the phase inversion process. By adding the MOFs into PES matrix, the flux recovery ratio was increased greatly (more than 99% for most mixed matrix membranes). The mixed matrix membranes showed higher resistance to protein adsorption compared to pristine PES membranes. After immersing the membranes in water for 3 months, 6 months and 12 months, both MOFs were stable and retained their structure. This study indicates that UiO-66 and UiO-66-NH<sub>2</sub> are great candidates for designing long-term stable mixed matrix membranes with higher anti-fouling performance.</p>

scholarly journals The Effect of the Temperature and Moisture to the Permeation Properties of PEO-Based Membranes for Carbon-Dioxide Separation

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2053
Author(s):  
Dragutin Nedeljkovic
Keyword(s):  
Carbon Dioxide ◽  
Partial Pressure ◽  
Carbon Dioxide Emission ◽  
Combustion Products ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix Membrane ◽  
Mixed Matrix ◽  
Gas Treatment ◽  
Carbon Dioxide Separation ◽  
Different Temperatures

An increased demand for energy in recent decades has caused an increase in the emissions of combustion products, among which carbon-dioxide is the most harmful. As carbon-dioxide induces negative environmental effects, like global warming and the greenhouse effect, a decrease of the carbon-dioxide emission has emerged as one of the most urgent tasks in engineering. In this work, the possibility for the application of the polymer-based, dense, mixed matrix membranes for flue gas treatment was tested. The task was to test a potential decrease in the permeability and selectivity of a mixed-matrix membrane in the presence of moisture and at elevated temperature. Membranes are based on two different poly(ethylene oxide)-based polymers filled with two different zeolite powders (ITR and IWS). An additive of detergent type was added to improve the contact properties between the zeolite and polymer matrix. The measurements were performed at three different temperatures (30, 60, and 90 °C) under wet conditions, with partial pressure of the water equal to the vapor pressure of the water at the given temperature. The permeability of carbon-dioxide, hydrogen, nitrogen, and oxygen was measured, and the selectivity of the carbon-dioxide versus other gases was determined. Obtained results have shown that an increase of temperature and partial pressure of the vapor slightly increase both the selectivity and permeability of the synthesized membranes. It was also shown that the addition of the zeolite powder increases the permeability of carbon-dioxide while maintaining the selectivity, compared to hydrogen, oxygen, and nitrogen.

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