Janus Copper Mesh Film with Unidirectional Water Transportation Ability toward High Efficiency Oil/Water Separation

2017 ◽  
Vol 12 (16) ◽  
pp. 2085-2092 ◽  
Author(s):  
Zhongjun Cheng ◽  
Bohan Wang ◽  
Hua Lai ◽  
Pengchang Liu ◽  
Dongjie Zhang ◽  
...  
2016 ◽  
Vol 18 (2) ◽  
pp. 1317-1325 ◽  
Author(s):  
Luyan Liu ◽  
Chen Chen ◽  
Siyu Yang ◽  
Hua Xie ◽  
MaoGang Gong ◽  
...  

Synergistic superhydrophilic–underwater superoleophobic inorganic membranes were inventively created by a maneuverable galvanic displacement reaction on copper mesh.


2021 ◽  
Vol 8 (1) ◽  
Author(s):  
Yuanli Chen ◽  
Hui Fan ◽  
Xinlin Zha ◽  
Wenwen Wang ◽  
Yi Wu ◽  
...  

AbstractHigh efficiency and anti-pollution oil/water separation membrane has been widely explored and researched. There are a large number of hydroxyl groups on the surface of silica, which has good wettability and can be used for oil-water separation membranes. Hydrophilic silica nanostructures with different morphologies were synthesized by changing templates and contents of trimethylbenzene (TMB). Here, silica nanospheres with radical pores, hollow silica nanospheres and worm-like silica nanotubes were separately sprayed on the PVA-co-PE nanofiber membrane (PM). The abundance of hydroxyl groups and porous structures on PM surfaces enabled the absorption of silica nanospheres through hydrogen bonds. Compared with different silica nanostructures, it was found that the silica/PM exhibited excellent super-hydrophilicity in air and underwater “oil-hating” properties. The PM was mass-produced in our lab through melt-extrusion-phase-separation technique. Therefore, the obtained membranes not only have excellent underwater superoleophobicity but also have a low-cost production. The prepared silica/PM composites were used to separate n-hexane/water, silicone oil/water and peanut oil water mixtures via filtration. As a result, they all exhibited efficient separation of oil/water mixture through gravity-driven filtration.


2021 ◽  
Vol 18 (4) ◽  
pp. 887-899
Author(s):  
Yanling Tian ◽  
Jiekai Feng ◽  
Zexin Cai ◽  
Jiaqi Chao ◽  
Dawei Zhang ◽  
...  

AbstractReckless discharge of industrial wastewater and domestic sewage as well as frequent leakage of crude oil have caused serious environmental problems and posed severe threat to human survival. Various nature inspired superhy-drophobic surfaces have been successfully applied in oily water remediation. However, further improvements are still urgently needed for practical application in terms of facile synthesis process and long-term durability towards harsh environment. Herein, we propose a simple one-step dodecyl mercaptan functionalization method to fabricate Super-hydrophobic-Superoleophilic Copper Mesh (SSCM). The prepared SSCM possesses excellent water repellence and oil affinity, enabling it to successfully separate various oil-water mixtures with high separation efficiency (e.g., > 99% for hexadecane-water mixture). The SSCM retains high separating ability when hot water and strong corrosive aqueous solutions are used to simulate oil-water mixtures, indicating remarkable chemical durability of the dodecyl mercaptan functionalized copper mesh. Additionally, the efficiency can be well maintained during 50 cycles of separation, and the water repellence is even stable after storage in air for 120 days, demonstrating the reusability and long-term stability of the SSCM. Furthermore, the functionalized mesh also shows good mechanical robustness towards abrasion by sandpaper, and oil-water separation efficiency of > 96% can be obtained after 10 cycles of abrasion. The reported one-step dodecyl mercaptan functionalization could be a simple method for increasing the water repellence of copper mesh, and thereby be a great candidate for treating large-scale oily wastewater in harsh environments.


2021 ◽  
Author(s):  
Junjin Lai ◽  
Rui Zhou ◽  
Huangping Yan ◽  
Jingqin Cui ◽  
Zhekun Chen ◽  
...  

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