scholarly journals Inside Cover: Metal-Organic-Framework-Templated Polyelectrolyte Nanocapsules for the Encapsulation and Delivery of Small-Molecule-Polymer Conjugates (Chem. Asian J. 12/2016)

2016 ◽  
Vol 11 (12) ◽  
pp. 1748-1748
Author(s):  
Shuo Liu ◽  
Jianbin Chen ◽  
Xiaojia Bao ◽  
Tao Li ◽  
Yunyang Ling ◽  
...  
Keyword(s):  
Small Molecule ◽  
Metal Organic Framework ◽  
Polymer Conjugates ◽  
Metal Organic ◽  
Organic Framework

Metal-Organic-Framework-Templated Polyelectrolyte Nanocapsules for the Encapsulation and Delivery of Small-Molecule-Polymer Conjugates

2016 ◽  
Vol 11 (12) ◽  
pp. 1811-1820 ◽  
Author(s):  
Shuo Liu ◽  
Jianbin Chen ◽  
Xiaojia Bao ◽  
Tao Li ◽  
Yunyang Ling ◽  
...  
Keyword(s):  
Small Molecule ◽  
Metal Organic Framework ◽  
Polymer Conjugates ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Backbonding contributions to small molecule chemisorption in a metal–organic framework with open copper(i) centers

2021 ◽  
Author(s):  
Gregory M. Su ◽  
Han Wang ◽  
Brandon R. Barnett ◽  
Jeffrey R. Long ◽  
David Prendergast ◽  
...  
Keyword(s):  
Fine Structure ◽  
Small Molecule ◽  
Metal Organic Framework ◽  
X Ray ◽  
Metal Site ◽  
Absorption Fine ◽  
Metal Organic ◽  
X Ray Absorption ◽  
Organic Framework

In situ near edge X-ray absorption fine structure spectroscopy directly probes unoccupied states associated with backbonding interactions between the open metal site in a metal–organic framework and various small molecule guests.

Optimized Metal–Organic-Framework Nanospheres for Drug Delivery: Evaluation of Small-Molecule Encapsulation

ACS Nano ◽  
2014 ◽  
Vol 8 (3) ◽  
pp. 2812-2819 ◽  
Author(s):  
Jia Zhuang ◽  
Chun-Hong Kuo ◽  
Lien-Yang Chou ◽  
De-Yu Liu ◽  
Eranthie Weerapana ◽  
...  
Keyword(s):  
Drug Delivery ◽  
Small Molecule ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Biomimetic O2 adsorption in an iron metal–organic framework for air separation

2020 ◽  
Vol 11 (6) ◽  
pp. 1698-1702 ◽  
Author(s):  
Douglas A. Reed ◽  
Dianne J. Xiao ◽  
Henry Z. H. Jiang ◽  
Khetpakorn Chakarawet ◽  
Julia Oktawiec ◽  
...  
Keyword(s):  
Gas Separation ◽  
Small Molecule ◽  
Metal Organic Framework ◽  
Air Separation ◽  
Small Molecule Activation ◽  
O2 Adsorption ◽  
Iron Metal ◽  
Metal Organic ◽  
Organic Framework

Bio-inspired motifs for gas binding and small molecule activation can be used to design more selective adsorbents for gas separation applications.

scholarly journals Structural, elastic, thermal, and electronic responses of small-molecule-loaded metal–organic framework materials

2015 ◽  
Vol 3 (3) ◽  
pp. 986-995 ◽  
Author(s):  
Pieremanuele Canepa ◽  
Kui Tan ◽  
Yingjie Du ◽  
Hongbing Lu ◽  
Yves J. Chabal ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Ab Initio ◽  
Small Molecule ◽  
Metal Organic Framework ◽  
Nano Indentation ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework

We combine infrared spectroscopy, nano-indentation measurements, and ab initio simulations to study the evolution of structural, elastic, thermal, and electronic responses of the metal–organic framework MOF-74-Zn when loaded with H2, CO2, CH4, and H2O.

A multi-responsive luminescent sensor for organic small-molecule pollutants and metal ions based on a 4d–4f metal–organic framework

2017 ◽  
Vol 46 (11) ◽  
pp. 3526-3534 ◽  
Author(s):  
Huili Ma ◽  
Lu Wang ◽  
Jinghuo Chen ◽  
Xuejing Zhang ◽  
Liang Wang ◽  
...  
Keyword(s):  
Metal Ions ◽  
Small Molecule ◽  
Metal Organic Framework ◽  
Luminescent Sensor ◽  
Metal Organic ◽  
Organic Framework

A multi-responsive luminescent sensor for organic small-molecule pollutants and metal ions based on a metal–organic framework is reported.

Multifunctional metal–organic framework heterostructures for enhanced cancer therapy

2021 ◽  
Author(s):  
Jintong Liu ◽  
Jing Huang ◽  
Lei Zhang ◽  
Jianping Lei
Keyword(s):  
Cancer Therapy ◽  
General Principle ◽  
Biomedical Applications ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Functional Modulation ◽  
Organic Framework

We review the general principle of the design and functional modulation of nanoscaled MOF heterostructures, and biomedical applications in enhanced therapy.

Magnetic Ordering via Itinerant Ferromagnetism in a Metal-Organic Framework

2020 ◽  
Author(s):  
Jesse Park ◽  
Brianna Collins ◽  
Lucy Darago ◽  
Tomce Runcevski ◽  
Michael Aubrey ◽  
...  
Keyword(s):  
Charge Transport ◽  
Magnetic Order ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Magnetic Ordering ◽  
Double Exchange ◽  
Itinerant Ferromagnetism ◽  
Organic Solids ◽  
Metal Organic ◽  
Organic Framework

<b>Materials that combine magnetic order with other desirable physical attributes offer to revolutionize our energy landscape. Indeed, such materials could find transformative applications in spintronics, quantum sensing, low-density magnets, and gas separations. As a result, efforts to design multifunctional magnetic materials have recently moved beyond traditional solid-state materials to metal–organic solids. Among these, metal–organic frameworks in particular bear structures that offer intrinsic porosity, vast chemical and structural programmability, and tunability of electronic properties. Nevertheless, magnetic order within metal–organic frameworks has generally been limited to low temperatures, owing largely to challenges in creating strong magnetic exchange in extended metal–organic solids. Here, we employ the phenomenon of itinerant ferromagnetism to realize magnetic ordering at <i>T</i><sub>C</sub> = 225 K in a mixed-valence chromium(II/III) triazolate compound, representing the highest ferromagnetic ordering temperature yet observed in a metal–organic framework. The itinerant ferromagnetism is shown to proceed via a double-exchange mechanism, the first such observation in any metal–organic material. Critically, this mechanism results in variable-temperature conductivity with barrierless charge transport below <i>T</i><sub>C</sub> and a large negative magnetoresistance of 23% at 5 K. These observations suggest applications for double-exchange-based coordination solids in the emergent fields of magnetoelectrics and spintronics. Taken together, the insights gleaned from these results are expected to provide a blueprint for the design and synthesis of porous materials with synergistic high-temperature magnetic and charge transport properties. </b>

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