Quantitative Detection of Visible Light on Hybrid Nanostructures of Two-dimension Porous Conjugated Polymers and Charge-Transfer Complexes by Field Emission

2016 ◽  
Vol 11 (19) ◽  
pp. 2778-2784 ◽  
Author(s):  
Juan Gao ◽  
Jiaofu Li ◽  
Zheng Xue ◽  
Huibiao Liu ◽  
Yongjun Li ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Visible Light ◽  
Conjugated Polymers ◽  
Field Emission ◽  
Hybrid Nanostructures ◽  
Quantitative Detection ◽  
Charge Transfer Complexes ◽  
Two Dimension

Iodinated Polystyrene for Polymeric Charge Transfer Complexes: Toward High-Performance Near-UV and Visible Light Macrophotoinitiators

2019 ◽  
Vol 52 (9) ◽  
pp. 3448-3453 ◽  
Author(s):  
Alexandre Baralle ◽  
Patxi Garra ◽  
Bernadette Graff ◽  
Fabrice Morlet-Savary ◽  
Céline Dietlin ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Visible Light ◽  
High Performance ◽  
Charge Transfer Complexes

scholarly journals Water-Soluble Visible Light Sensitive Photoinitiating System Based on Charge Transfer Complexes for the 3D Printing of Hydrogels

Polymers ◽  
2021 ◽  
Vol 13 (18) ◽  
pp. 3195
Author(s):  
Hong Chen ◽  
Mehdi Vahdati ◽  
Pu Xiao ◽  
Frédéric Dumur ◽  
Jacques Lalevée
Keyword(s):  
Charge Transfer ◽  
3D Printing ◽  
Visible Light ◽  
Water Solubility ◽  
Charge Transfer Complex ◽  
Water Soluble ◽  
Charge Transfer Complexes ◽  
Free Radical Photopolymerization ◽  
Potential Applications ◽  
A Charge

The development of visible-light 3D printing technology by using water-soluble initiating systems has attracted widespread attention due to their potential applications in the manufacture of hydrogels. Besides, at present, the preparation of water-soluble photoinitiators suitable for visible light irradiation (such as LEDs) still remains a challenge. Therefore, this work is devoted to developing water-soluble photoinitiators (PI)/photoinitiating systems (PIS) upon irradiation with a LED @ 405 nm. In detail, a new water-slightly-soluble chalcone derivative dye [(E)-3-(4-(dimethylamino) phenyl)-1-(4-(2-(2-(2-methoxyethoxy) ethoxy) ethoxy) phenyl) prop-2-en-1-one] was synthesized here and used as a PI with a water-soluble coinitiator, i.e., triethanolamine (TEA) which was also used as an electron donor. When combined together, a charge transfer complex (CTC) formed immediately which exhibited excellent initiating ability for the free radical photopolymerization of poly(ethyleneglycol)diacrylate (PEG-DA). In light of the powerful CTC effect, the [dye-TEA] CTC could not only exhibit enhanced water solubility and mechanical properties but could also be effectively applied for 3D printing. This CTC system is environmentally friendly and cost-saving which demonstrates a great potential to prepare hydrogels via photopolymerization.

Weak charge-transfer complexes based on conjugated polymers for plastic solar cells

2004 ◽  
Vol 147 (1-3) ◽  
pp. 221-225 ◽  
Author(s):  
A.A. Bakulin ◽  
S.G. Elizarov ◽  
A.N. Khodarev ◽  
D.S. Martyanov ◽  
I.V. Golovnin ◽  
...  
Keyword(s):  
Solar Cells ◽  
Charge Transfer ◽  
Conjugated Polymers ◽  
Charge Transfer Complexes ◽  
Weak Charge ◽  
Plastic Solar Cells

Field Emission Properties of Large-Area Nanowires of Organic Charge-Transfer Complexes

2005 ◽  
Vol 127 (4) ◽  
pp. 1120-1121 ◽  
Author(s):  
Huibiao Liu ◽  
Qing Zhao ◽  
Yuliang Li ◽  
Yang Liu ◽  
Fushen Lu ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Field Emission ◽  
Charge Transfer Complexes ◽  
Large Area ◽  
Emission Properties ◽  
Field Emission Properties

scholarly journals Ultrafast Charge Photogeneration Dynamics in Ground-State Charge-Transfer Complexes Based on Conjugated Polymers

2008 ◽  
Vol 112 (44) ◽  
pp. 13730-13737 ◽  
Author(s):  
Artem A. Bakulin ◽  
Dmitry S. Martyanov ◽  
Dmitry Yu. Paraschuk ◽  
Maxim S. Pshenichnikov ◽  
Paul H. M. van Loosdrecht
Keyword(s):  
Charge Transfer ◽  
Conjugated Polymers ◽  
Ground State ◽  
Charge Transfer Complexes ◽  
State Charge

scholarly journals Radical Perfluoroalkylation Enabled by a Catalytically Generated Halogen Bonding Complex and Visible Light Irradiation

2021 ◽  
Author(s):  
Tarannum Tasnim ◽  
Calvin Ryan ◽  
Miranda Christensen ◽  
Christopher Fennell ◽  
Spencer Pitre
Keyword(s):  
Charge Transfer ◽  
Complex Formation ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Redox Reactions ◽  
Charge Transfer Complex ◽  
Halogen Bonding ◽  
Charge Transfer Complexes ◽  
Computational Studies ◽  
The Many

Despite the many recent advances in exploiting stoichiometric charge-transfer complexes in visible light promoted single-electron redox reactions, catalytic approaches to charge-transfer complex formation remain limited. This report describes the radical perfluoroalkylation of electron-rich (hetero)arenes and iodoperfluoroalkylation of alkenes and alkynes promoted by a substituted hydroquinone catalyst. Mechanistic and computational studies indicate that the reaction is initiated by the formation of a visible light absorbing halogen bonding complex between the hydroquinone catalyst and the perfluoroalkyl iodide radical precursor.

scholarly journals Threshold-like complexation of conjugated polymers with small molecule acceptors in solution within the neighbor-effect model

2016 ◽  
Vol 18 (6) ◽  
pp. 4684-4696 ◽  
Author(s):  
Andrey Yu. Sosorev ◽  
Olga D. Parashchuk ◽  
Sergey A. Zapunidi ◽  
Grigoriy S. Kashtanov ◽  
Ilya V. Golovnin ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Conjugated Polymers ◽  
Small Molecule ◽  
Ground State ◽  
Cooperative Effect ◽  
Charge Transfer Complexes ◽  
Effect Model ◽  
Sharp Growth ◽  
Neighbor Effect ◽  
Electronic Ground

A pronounced cooperative effect leading to a sharp growth of charge-transfer complexes (CTCs) in the electronic ground state is observed.

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