An Efficient Visible and Near-Infrared (NIR) Emitting SmIIIMetal-Organic Framework (Sm-MOF) Sensitized by Excited-State Intramolecular Proton Transfer (ESIPT) Ligand

2016 ◽  
Vol 11 (12) ◽  
pp. 1765-1769 ◽  
Author(s):  
Ling Chen ◽  
Hao Zhang ◽  
Mei Pan ◽  
Zhang-Wen Wei ◽  
Hai-Ping Wang ◽  
...  
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Near Infrared ◽  
Intramolecular Proton Transfer ◽  
Organic Framework

Near-Infrared Organic Single-Crystal Lasers with Polymorphism-Dependent Excited State Intramolecular Proton Transfer

2017 ◽  
Vol 5 (12) ◽  
pp. 1700027 ◽  
Author(s):  
Xuedong Wang ◽  
Zhi-Zhou Li ◽  
Shi-Feng Li ◽  
Hui Li ◽  
Jianwei Chen ◽  
...  
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Single Crystal ◽  
Near Infrared ◽  
Intramolecular Proton Transfer ◽  
Organic Single Crystal

scholarly journals Near-Infrared Organic Single-Crystal Nanolaser Arrays Activated by Excited-State Intramolecular Proton Transfer

Matter ◽  
2020 ◽  
Vol 2 (5) ◽  
pp. 1233-1243 ◽  
Author(s):  
Jun-Jie Wu ◽  
Hanfei Gao ◽  
Runchen Lai ◽  
Ming-Peng Zhuo ◽  
Jiangang Feng ◽  
...  
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Single Crystal ◽  
Near Infrared ◽  
Intramolecular Proton Transfer ◽  
Organic Single Crystal

Near-infrared fluorescent dyes with large Stokes shifts: light generation in BODIPYs undergoing excited state intramolecular proton transfer

2017 ◽  
Vol 15 (19) ◽  
pp. 4072-4076 ◽  
Author(s):  
Qiang Fei ◽  
Xianfeng Gu ◽  
Yajing Liu ◽  
Ben Shi ◽  
Hengyan Liu ◽  
...  
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Near Infrared ◽  
Fluorescent Dyes ◽  
Stokes Shift ◽  
Intramolecular Proton Transfer ◽  
Large Stokes Shift ◽  
Light Generation ◽  
Stokes Shifts

New ESIPT-based BODIPYs are developed to render the NIR emissions with a large Stokes shift.

Cascaded excited‐state intramolecular proton transfer towards near‐infrared organic lasers beyond 850 nm

2021 ◽  
Author(s):  
Jun-Jie Wu ◽  
Ming-Peng Zhuo ◽  
Runchen Lai ◽  
Sheng-Nan Zou ◽  
Chang-Cun Yan ◽  
...  
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Near Infrared ◽  
Intramolecular Proton Transfer

Cascaded Excited‐State Intramolecular Proton Transfer Towards Near‐Infrared Organic Lasers Beyond 850 nm

2021 ◽  
Vol 60 (16) ◽  
pp. 9114-9119
Author(s):  
Jun‐Jie Wu ◽  
Ming‐Peng Zhuo ◽  
Runchen Lai ◽  
Sheng‐Nan Zou ◽  
Chang‐Cun Yan ◽  
...  
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Near Infrared ◽  
Intramolecular Proton Transfer

scholarly journals Red-Shift (2-Hydroxyphenyl)-Benzothiazole Emission by Mimicking the Excited-State Intramolecular Proton Transfer Effect

2021 ◽  
Vol 9 ◽  
Author(s):  
Yong Ren ◽  
Lei Zhou ◽  
Xin Li
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Near Infrared ◽  
Photophysical Properties ◽  
Molecular Size ◽  
Infrared Region ◽  
Intramolecular Proton Transfer ◽  
Quantum Yields ◽  
Organic Fluorophores ◽  
Imaging Probes

Novel strategies to optimize the photophysical properties of organic fluorophores are of great significance to the design of imaging probes to interrogate biology. While the 2-(2-hydroxyphenyl)-benzothiazole (HBT) fluorophore has attracted considerable attention in the field of fluorescence imaging, its short emission in the blue region and low quantum yield restrict its wide application. Herein, by mimicking the excited-state intramolecular proton transfer (ESIPT) effect, we designed a series of 2-(2-hydroxyphenyl)-benzothiazole (HBT) derivatives by complexing the heteroatoms therein with a boron atom to enhance the chance of the tautomerized keto-like resonance form. This strategy significantly red-shifted the emission wavelengths of HBT, greatly enhanced its quantum yields, and caused little effect on molecular size. Typically, compounds 12B and 13B were observed to emit in the near-infrared region, making them among the smallest organic structures with emission above 650 nm.

scholarly journals Facile Synthesis of an Organic Solid State Near-Infrared-Emitter with Large Stokes Shift via Excited-State Intramolecular Proton Transfer

ACS Omega ◽  
2018 ◽  
Vol 3 (10) ◽  
pp. 14341-14348 ◽  
Author(s):  
Abhishek Kumar Gupta ◽  
Ashwani Kumar ◽  
Ranjit Singh ◽  
Manisha Devi ◽  
Abhimanew Dhir ◽  
...  
Keyword(s):  
Excited State ◽  
Solid State ◽  
Proton Transfer ◽  
Near Infrared ◽  
Stokes Shift ◽  
Intramolecular Proton Transfer ◽  
Facile Synthesis ◽  
Large Stokes Shift ◽  
Organic Solid ◽  
Infrared Emitter
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