scholarly journals Synthetical modification of plant oil‐based plasticizer with CO 2 leads to reduced migration from NBR rubber

2021 ◽  
pp. 51854
Author(s):  
Irfan Shahzad ◽  
Md Mahbubur Rahman ◽  
Sergei Wittchen ◽  
Katrin Reincke ◽  
Beate Langer ◽  
...  
Keyword(s):  
2018 ◽  
Vol 44 (2) ◽  
pp. 56-65
Author(s):  
M. E. Bondarchuk ◽  
◽  
V. V. Kozlova ◽  

2015 ◽  
Vol 11 (1) ◽  
Author(s):  
Zulaicha Dwi Hastuti ◽  
Dwi Husodo Prasetyo ◽  
Erlan Rosyadi
Keyword(s):  
Palm Oil ◽  

Asam lemak bebas (alb) dalam Crude Palm Oil (CPO) merupakan salah satu parameter kualitas CPO.Munculnya asamlemak bebas ini dapat berasal dari faktor pemanenan dan penyimpanan. Asamlemak bebas yang tinggi dalam CPO dapat menurunkan harga CPO. Minyak mentah sawit inimerupakan salah satu sumber energi terbarukan yang diolah, antara lain, menjadi pure plant oil (PPO)dan biodiesel. Namun,masalah utama CPO sebagai bahan baku PPO dan biodiesel adalah asamlemak bebas. Asam lemak bebas dalam CPO yang dapat digunakan untuk PPO dan biodiesel tidakboleh lebih dari 1%. Oleh karena itu, dalam penelitian ini dilakukan usaha untuk menurunkan asamlemak bebas dalam CPO sehingga dapat dimanfaatkan sebagai bahan bakar. Metoda yang digunakanadalah esterifikasi. Asam lemak bebas dikonversi menjadi metil ester. Campuran metil ester dengantrigliserida ini merupakan bahan bakar yang dapat digunakan untuk pengganti BBM. Kondisi yangoptimal untuk proses esterifikasi CPO alb tinggi adalah sebagai berikut : suhu 65oC, waktu 360 menit,katalis 0,25%, dan perbandingan mol metanol 8:1. Dengan proses ini, asam lemak bebas dapatditurunkan menjadi 2,76% (konversi 89,39%). Pada kondisi yang sama dengan katalis yangditingkatkan menjadi 0,5%, asam lemak bebas dapat diturunkan menjadi 1,86% (konversi 92,85%).Pada kondisi yang sama, dengan katalis yang ditingkatkan menjadi 1%, asam lemak bebas dapatditurunkan menjadi 1,75% (konversi 93,28%).Kata kunci: asam lemak bebas, CPO, esterifikasi, PPO, biodiesel


2020 ◽  
Vol 04 ◽  
Author(s):  
Lívia Gonçalves Ferreira Rodrigues ◽  
Juliana Falcão Alves de Carvalho ◽  
Cristal dos Santos Cerqueira Pinto ◽  
Elisabete Pereira Santos ◽  
Claudia Regina Elias Mansur

Background:: The use of polymers in hair care products is widespread, and silicones in particular are extensively used in cosmetic formulations. In addition, plant oils can also be used for hair treatment. Objective: In the present work, oil-in-water (O/W) nanoemulsions were prepared to repair chemical damage to human hair samples, to investigate the combined use of a silicone polyether copolymer (surfactant) that has a branch composed of poly(ethylene oxide) in its chains, and two types of plant oils: coconut and ojon oil. Materials and Methods:: Surfactant-oil-water formulations were obtained by ultrasonic processing. The nanoemulsions were then applied to human hair strands previously damaged with sodium hydroxide, to compare the treated strands with untreated ones. The efficacy of the formulations was investigated by scanning electron microscopy, thermogravimetric analysis and mechanical tests. Results and Discussion:: Stables nanoemulsions were obtained with average size of the dispersed droplets up to 400 nm. The micrographs suggest that the action mechanism of the nanoemulsions depends not only on the type of plant oil used and size of the droplets dispersed in the system, but also on the type of hair that receives the treatment. The thermal analysis showed that the use of nanoemulsion changed the temperature of keratin interconversion to higher values, which can make hair fibers more resistant to heat. Hair resistance was improved when comparing virgin samples to the damaged ones. Conclusion:: The nanoemulsions were efficient in the treatment of the hair samples, which showed a significant improvement of their mechanical properties.


Plants ◽  
2021 ◽  
Vol 10 (1) ◽  
pp. 143
Author(s):  
Vera Breiing ◽  
Jennifer Hillmer ◽  
Christina Schmidt ◽  
Michael Petry ◽  
Brigitte Behrends ◽  
...  

As biorationals, plant oils offer numerous advantages such as being natural products, with low ecotoxicological side effects, and high biodegradability. In particular, drying glyceride plant oils, which are rich in unsaturated fatty acids, might be promising candidates for a more sustainable approach in the discussion about plant protection and the environment. Based on this, we tested the protective and curative efficacy of an oil-in-water-emulsion preparation using drying plant oils (linseed oil, tung oil) and a semi-drying plant oil (rapeseed oil) separately and in different mixtures. Plant oils were tested in greenhouse experiments (in vivo) on green beans (Phaseolus vulgaris L.) against bean rust (Uromyces appendiculatus). We observed that a 2% oil concentration showed no or very low phytotoxic effects on green beans. Both tested drying oils showed a protective control ranging from 53–100% for linseed oil and 32–100% for tung oil. Longer time intervals of 6 days before inoculation (6dbi) were less effective than shorter intervals of 2dbi. Curative efficacies were lower with a maximum of 51% for both oils when applied 4 days past inoculation (4dpi) with the fungus. Furthermore, the results showed no systemic effects. These results underline the potential of drying plant oils as biorationals in sustainable plant protection strategies.


2021 ◽  
Author(s):  
Jonathan Tellers ◽  
Nicolas SBIRRAZZUOLI ◽  
Nathanael Guigo

Bio-based hardeners that are not amine or anhydride based are of particular interest to avoid health concerns associated with both. In the present study, a recently developed furfural based cross-linker...


Water ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1215
Author(s):  
László Berzi-Nagy ◽  
Attila Mozsár ◽  
Flórián Tóth ◽  
Dénes Gál ◽  
Zoltán Nagy ◽  
...  

Semi-intensive common carp (Cyprinus carpio) farm technology uses several feed types affecting the growth performance; however, we know less about their long-term effects on water quality. Herein, we evaluated the effects of three commonly used feeds—moderate levels of fish meal and fish oil feed (FF), plant meal and plant oil feed (PF), and cereal feed (CF) on the nutrient (total nitrogen (TN), total phosphorus (TP) and organic matter (OM)) content of the pond water. The experiment was carried out over three consecutive years from juveniles to market-sized fish. The type of feed affected the net yields, but generally, it did not affect the water quality. The year of sampling, however, was a significant factor affecting TN, TP, and OM, whose concentrations decreased during the three years. Our findings highlight that the age of the stocked fish on water quality has a more pronounced effect than the nutrient profile of the supplementary feed. Additionally, the plant-based feed could provide comparable net yields as the fish meal-based feed without additional nutrient loading in the water column, reinforcing the sustainability of alternative feeds in semi-intensive carp farming.


2014 ◽  
Vol 66 (3) ◽  
Author(s):  
W. B. Wan Nik ◽  
F. Zulkifli ◽  
S. S. Lam ◽  
M. M. Rahman ◽  
A. A. Yusof ◽  
...  

Development of environmental friendly hydraulic fluid has a major influence in ecologically benign environment. The use of plant oil as hydraulic fluid would help to minimize hazardous pollution caused by accidental spillage, lower disposal costs of the used fluid and meet the environmental regulations. Hydraulic test rig was built to conduct endurance test where it can be operated continuously with several safety features. This research was conducted to evaluate the rheology elements and hydraulic performance of palm based hydraulic fluid. The palm oil shows decreasing trend in volumetric efficiency as the pressure increase while the mechanical efficiency increases as the pressure increase. Properties and characteristics of palm based hydraulic fluid were evaluated via rheology study. The effect of viscosity with temperature and shear rate was studied. The influence of shear rate and temperature on the variation of viscosity was clearly observed but temperature has more significant influence. Interpretations of rheological models indicate that this palm based hydraulic fluid belongs to pseudo-plastic category. Further analysis was done to fit the experimental data with two models and the findings show that Cross rheological model fits well with the experiment data. The plant oil was used in 1000 hours operation in a hydraulic system built in Universiti Malaysia Terengganu. The overall results suggest the potential substitution of palm oil as hydraulic fluid in marine applications.


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