Thermally stable poly (acrylic acid‐acrylamide‐biomass‐fly ash) composites with improved temperature resistance and salt resistance

2021 ◽  
Vol 139 (4) ◽  
pp. 51533
Author(s):  
Yanxia Liu ◽  
Yangtian Yan ◽  
Lin Zhao ◽  
Yagang Zhang ◽  
Letao Zhang ◽  
...  
Keyword(s):  
Fly Ash ◽  
Acrylic Acid ◽  
Salt Resistance ◽  
Thermally Stable ◽  
Temperature Resistance ◽  
Biomass Fly Ash ◽  
Poly Acrylic Acid

Preparation and swelling properties of poly(acrylic acid-co-acrylamide) composite hydrogels

e-Polymers ◽  
2017 ◽  
Vol 17 (1) ◽  
pp. 95-106 ◽  
Author(s):  
Wei-Min Cheng ◽  
Xiang-Ming Hu ◽  
Yan-Yun Zhao ◽  
Ming-Yue Wu ◽  
Zun-Xiang Hu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Salt Tolerance ◽  
Acrylic Acid ◽  
Water Absorption ◽  
Crosslinking Agent ◽  
Salt Resistance ◽  
Composite Hydrogel ◽  
Swelling Properties ◽  
Unfavorable Effect ◽  
Poly Acrylic Acid

AbstractIn order to study the effect of composite clays on the mechanical properties, water absorption and salt tolerance of a hydrogel, a poly(acrylic acid-co-acrylamide)/bentonite/kaolin composite hydrogel was prepared. Acrylic acid and acrylamide have been used as water absorbent monomers. N,N′-methylene bisacrylamide was used as a crosslinking agent while potassium persulfate was used as an initiator. The water preserving capability, repeated water absorption, salt resistance and the mechanical properties of the composite hydrogel are analyzed and discussed. The results show that a small quantity of bentonite can increase the storage modulus of the composite hydrogel, whereas the excess clay had an unfavorable effect on the mechanical strength of the composite hydrogel. Both bentonite and kaolin significantly improved the water preserving capability, repeated water absorption and salt resistance of the composite hydrogel. Optimum values for the amounts of bentonite and kaolin were found to be 10% and 5%, respectively.

Synthesis and Properties of Potassium-Containing Poly(Acrylic Acid Sodium-Co-Acrylamide)Fly Ash-Illite Superabsorbent Composite

2011 ◽  
Vol 239-242 ◽  
pp. 59-63
Author(s):  
Shang Yue Shen ◽  
Kai Sheng Xia ◽  
Hui Ling ◽  
Li Ren Fan
Keyword(s):  
Fly Ash ◽  
Acrylic Acid ◽  
Tap Water ◽  
Low Cost ◽  
Absorption Spectrometry ◽  
Soil Improvement ◽  
Good Effect ◽  
Republic Of China ◽  
Superabsorbent Composite ◽  
Poly Acrylic Acid

The fly ash with a loose and porous structure has definite absorbent ability, which has a good effect on soil improvement. Illite belongs to clay minerals, it has absorbent ability and higher potassium, which can improve the soil fertility. In this study, poly(acrylic acid sodium-co-acrylamide)(PAANa-AM)/fly ash-illite superabsorbent composite was firstly prepared by solution polymerization. The structures were characterized using scanning electron microscope, X-ray diffraction, and infrared spectrum. The results showed that the fly ash and illite dispersed well in the composite. The K+ in illite was replaced by Na+ in acrylic acid sodium and thus the illite structure turned into paragonite during the process of preparing composite, however, the structure of fly ash was maintained in the composite. Moreover, the hydroxide radical in illite reacted with the carbonyl group in acrylic acid during polymerization. The best absorbent capacities of the composite in distilled water, tap water and normal saline were 1695, 445 and 106 g/g, respectively, which exceeded the requirements of The National 863 Program and Ministry of Agriculture of People’s Republic of China. The potassium release was measured using atomic absorption spectrometry and the results indicated that the composite can release 12.80% of the potassium ion in fly ash and illite. The superabsorbent material has low cost and favors improvement of soil and potassium-deficiency.

scholarly journals Preparation and Applications of Salt-Resistant Superabsorbent Poly (Acrylic Acid-Acrylamide/Fly Ash) Composite

Materials ◽  
2019 ◽  
Vol 12 (4) ◽  
pp. 596 ◽  
Author(s):  
Wenjuan Zhu ◽  
Yagang Zhang ◽  
Penglei Wang ◽  
Zhiyong Yang ◽  
Akram Yasin ◽  
...  
Keyword(s):  
Fly Ash ◽  
Acrylic Acid ◽  
Pure Water ◽  
Polymerization Temperature ◽  
Mass Ratio ◽  
Nacl Solution ◽  
Absorption Performance ◽  
Ft Ir ◽  
Optimized Conditions ◽  
Poly Acrylic Acid

Solution polymerization synthesized alt-resistant superabsorbent poly (acrylic acid-acrylamide/fly ash) composites. The mass ratio of acrylic acid (AA) to acrylamide (AM), the concentration of crosslinker, the neutralization degree (ND) of AA, and the polymerization temperature were investigated by single-factor method. Optimized conditions for the synthesis of poly (acrylic acid-acrylamide/fly ash) (PAA-AM/FA) are, as following: m (AA)/m (AM) is 1.5, the content of crosslinker N, N-methylenebisacrylamide. (MBA) is 0.7%, neutralization degree of AA is 70%, polymerization temperature is 70 °C, and fly ash (FA) content is 50%. The prepared PAA-AM/FA demonstrated superior water absorption performance. The absorption capacities of PAA-AM/FA for pure water and 0.9% NaCl solution were found to be 976 g·g−1 and 81 g·g−1, respectively. Furthermore, PAA-AM/FA was found to have excellent adsorption capacity (148 mg·g−1) for Rhodamine B in water. Fourier Transform-Infrared Spectroscopy (FT-IR), Thermogravimetric Analysis (TGA), and Scanning Electron Microscopy (SEM) characterized the prepared materials. Results showed that fly ash was incorporated into the macromolecular polymer matrix and played a key role in improving the performance of the polymer composites.

Soft ionic liquid based resistive memory characteristics in a two terminal discrete polydimethylsiloxane cylindrical microchannel

2020 ◽  
Vol 8 (38) ◽  
pp. 13368-13374
Author(s):  
Muhammad Umair Khan ◽  
Gul Hassan ◽  
Jinho Bae
Keyword(s):  
Ionic Liquid ◽  
Acrylic Acid ◽  
Sodium Hydroxide ◽  
Sodium Salt ◽  
Resistive Memory ◽  
Cylindrical Microchannel ◽  
Memory Characteristics ◽  
Poly Acrylic Acid

This paper proposes a novel soft ionic liquid (IL) electrically functional device that displays resistive memory characteristics using poly(acrylic acid) partial sodium salt (PAA-Na+:H2O) solution gel and sodium hydroxide (NaOH) in a thin polydimethylsiloxane (PDMS) cylindrical microchannel.

Reactions of macroions with ester and carboxylic groups of polymers

1987 ◽  
Vol 52 (9) ◽  
pp. 2194-2203
Author(s):  
Miloslav Kučera ◽  
Dušan Kimmer ◽  
Karla Majerová ◽  
Josef Majer
Keyword(s):  
Maleic Anhydride ◽  
Acrylic Acid ◽  
Methyl Methacrylate ◽  
Bond Formation ◽  
Covalent Bond ◽  
The Other ◽  
Poly Methyl Methacrylate ◽  
Other Hand ◽  
Carboxylic Groups ◽  
Poly Acrylic Acid

In the reaction of dianions with poly(methyl methacrylate), only an insignificant amount of insoluble crosslinked product is obtained. If, however, the concentration of grafting dianions approaches that of ester groups, the amount of poly(methyl methacrylate) which may thus be crosslinked becomes quite significant. Dications, too, can bring about crosslinking of only an insignificant number of poly(methyl methacrylate) chains. Carboxylic groups in poly(acrylic acid) react with dianions and dications in an anhydrous medium similarly to ester groups. On the other hand, in the presence of a cocatalytic amount of water dications are more readily bound to carboxylic groups, forming a covalent bond. The relatively highest efficiency was observed in the bond formation between dication and the poly[styrene-alt-(maleic anhydride)], both in an anhydrous medium and in the presence of H2O.

Fabrication and Characterization of Chitosan-Poly(acrylic acid) Magnetic Nanospheres

2009 ◽  
Vol 9 (2) ◽  
pp. 1287-1290 ◽  
Author(s):  
Yuqing Ge ◽  
Song Zhang ◽  
Shiying He ◽  
Yu Zhang ◽  
Ning Gu
Keyword(s):  
Acrylic Acid ◽  
Magnetic Nanospheres ◽  
Fabrication And Characterization ◽  
Poly Acrylic Acid
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