Design and properties of polyarylene ether nitrile copolymers with improved elongation at break

2021 ◽  
pp. 50522
Author(s):  
Shuning Liu ◽  
Chenchen Liu ◽  
Zhongxiang Bai ◽  
Weixi Zhang ◽  
Lifen Tong ◽  
...  
Keyword(s):  
Elongation At Break ◽  
Polyarylene Ether Nitrile

Determination of Combined and Second Order Factor Effects for Simultaneous Optimization of Physical and Mechanical Properties of NR/BR Blend System

2014 ◽  
Vol 42 (4) ◽  
pp. 290-304
Author(s):  
Rajarajan Aiyengar ◽  
Jyoti Divecha
Keyword(s):  
Physical And Mechanical Properties ◽  
Second Order ◽  
Simultaneous Optimization ◽  
Order Effects ◽  
Elongation At Break ◽  
Five Factors ◽  
Rubber Compounds ◽  
Polybutadiene Rubber ◽  
Contour Plots

ABSTRACT The blends of natural rubber (NR), polybutadiene rubber (BR), and other forms of rubbers are widely used for enhancing the mechanical and physical properties of rubber compounds. Lots of work has been done in conditioning and mixing of NR/BR blends to improve the properties of its rubber compounds and end products such as tire tread. This article employs response surface methodology designed experiments in five factors; high abrasion furnace carbon black (N 330), aromatic oil, NR/BR ratio, sulfur, and N-oxydiethylene-2-benzothiazole sulfenamide for determination of combined and second order effects of the significant factors leading to simultaneous optimization of the NR/BR blend system. One of the overall optimum of eight properties existed at carbon 44 phr, oil 6.1 phr, NR/BR 78/22 phr with the following values of properties: tensile strength (22 MPa), elongation at break (528%), tear resistance (30 kg/mm), rebound resilience (67%), moderate hardness (68 International rubber hardness degrees) with low heat buildup (17 °C), permanent set (12%), and abrasion loss (57 mm3). More optimum combinations can easily be determined from the NR/BR blend system models contour plots.

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