Engineering hydrophobically associated hydrogels with rapid self‐recovery and tunable mechanical properties using metal‐ligand interactions

2020 ◽  
Vol 137 (48) ◽  
pp. 49590
Author(s):  
Prachishree Panda ◽  
Agniva Dutta ◽  
Debabrata Ganguly ◽  
Santanu Chattopadhyay ◽  
Rajat K. Das
Keyword(s):  
Mechanical Properties ◽  
Ligand Interactions ◽  
Tunable Mechanical Properties ◽  
Metal Ligand

Using metal–ligand interactions to access biomimetic supramolecular polymers with adaptive and superb mechanical properties

2013 ◽  
Vol 1 (37) ◽  
pp. 4809 ◽  
Author(s):  
Jinchun Yuan ◽  
Huan Zhang ◽  
Guangning Hong ◽  
Yinjun Chen ◽  
Guohua Chen ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Supramolecular Polymers ◽  
Ligand Interactions ◽  
Metal Ligand

scholarly journals 3D Printing of High Viscosity Reinforced Silicone Elastomers

Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2239
Author(s):  
Nicholas Rodriguez ◽  
Samantha Ruelas ◽  
Jean-Baptiste Forien ◽  
Nikola Dudukovic ◽  
Josh DeOtte ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
High Performance ◽  
New Technologies ◽  
Three Dimensional ◽  
High Viscosity ◽  
Layer By Layer ◽  
Silicone Elastomers ◽  
Uv Curable ◽  
Octet Truss ◽  
Tunable Mechanical Properties

Recent advances in additive manufacturing, specifically direct ink writing (DIW) and ink-jetting, have enabled the production of elastomeric silicone parts with deterministic control over the structure, shape, and mechanical properties. These new technologies offer rapid prototyping advantages and find applications in various fields, including biomedical devices, prosthetics, metamaterials, and soft robotics. Stereolithography (SLA) is a complementary approach with the ability to print with finer features and potentially higher throughput. However, all high-performance silicone elastomers are composites of polysiloxane networks reinforced with particulate filler, and consequently, silicone resins tend to have high viscosities (gel- or paste-like), which complicates or completely inhibits the layer-by-layer recoating process central to most SLA technologies. Herein, the design and build of a digital light projection SLA printer suitable for handling high-viscosity resins is demonstrated. Further, a series of UV-curable silicone resins with thiol-ene crosslinking and reinforced by a combination of fumed silica and MQ resins are also described. The resulting silicone elastomers are shown to have tunable mechanical properties, with 100–350% elongation and ultimate tensile strength from 1 to 2.5 MPa. Three-dimensional printed features of 0.4 mm were achieved, and complexity is demonstrated by octet-truss lattices that display negative stiffness.

scholarly journals Different manifestations of enhanced π-acceptor ligation at every redox level of [Os(9-OP)L2]n, n = 2+, +, 0, − (9-OP− = 9-oxidophenalenone and L = bpy or pap)

2016 ◽  
Vol 45 (45) ◽  
pp. 18241-18251 ◽  
Author(s):  
Arijit Singha Hazari ◽  
Alexa Paretzki ◽  
Jan Fiedler ◽  
Stanislav Zalis ◽  
Wolfgang Kaim ◽  
...  
Keyword(s):  
Donor And Acceptor ◽  
Ligand Interactions ◽  
Redox Level ◽  
Metal Ligand

Enhanced metal–ligand and ligand–ligand interactions are promoted in an osmium complex with non-innocent donor and acceptor ligands.

Biomimetic porous Mg with tunable mechanical properties and biodegradation rates for bone regeneration

2019 ◽  
Vol 84 ◽  
pp. 453-467 ◽  
Author(s):  
Min-Ho Kang ◽  
Hyun Lee ◽  
Tae-Sik Jang ◽  
Yun-Jeong Seong ◽  
Hyoun-Ee Kim ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Bone Regeneration ◽  
Tunable Mechanical Properties

scholarly journals Reversible Assembly of Terpyridine Incorporated Norbornene-Based Polymer via a Ring-Opening Metathesis Polymerization and Its Self-Healing Property

Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1173 ◽  
Author(s):  
Jookyeong Lee ◽  
Hwi Moon ◽  
Keewook Paeng ◽  
Changsik Song
Keyword(s):  
Ring Opening ◽  
Transition Metal Ions ◽  
Self Healing ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization ◽  
Ligand Interactions ◽  
Healing Agent ◽  
Healing Property ◽  
External Stimuli ◽  
Metal Ligand

We induced a terpyridine moiety into a norbornene-based polymer to demonstrate its self-healing property, without an external stimulus, such as light, heat, or healing agent, using metal–ligand interactions. We synthesized terpyridine incorporated norbornene-based polymers using a ring-opening metathesis polymerization. The sol state of diluted polymer solutions was converted into supramolecular assembled gels, through the addition of transition metal ions (Ni2+, Co2+, Fe2+, and Zn2+). In particular, a supramolecular complex gel with Zn2+, which is a metal with a lower binding affinity, demonstrated fast self-healing properties, without any additional external stimuli, and its mechanical properties were completely recovered.

Plastic-like Hydrogels with Reversible Conversion of Elasticity and Plasticity and Tunable Mechanical Properties

2019 ◽  
Vol 11 (44) ◽  
pp. 41659-41667 ◽  
Author(s):  
Jinrong Wang ◽  
Zhuo Chen ◽  
Xueyan Li ◽  
Mingjie Liu ◽  
Ying Zhu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tunable Mechanical Properties

Role of Metal–Ligand Bond Strength and Phase Separation on the Mechanical Properties of Metallopolymer Films

2013 ◽  
Vol 46 (14) ◽  
pp. 5416-5422 ◽  
Author(s):  
Aaron C. Jackson ◽  
Frederick L. Beyer ◽  
Samuel C. Price ◽  
B. Christopher Rinderspacher ◽  
Robert H. Lambeth
Keyword(s):  
Mechanical Properties ◽  
Phase Separation ◽  
Bond Strength ◽  
Metal Ligand ◽  
Ligand Bond
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