Synthesis of 3,13‐diglycidyloxypropyloctaphenyl double‐decker polyhedral oligomeric silsesquioxane and the thermal reaction properties with thermosetting phenol‐formaldehyde resin

2020 ◽  
Vol 137 (44) ◽  
pp. 49376
Author(s):  
Zhaoqi Niu ◽  
Dan Tian ◽  
Long Yan ◽  
Xiaoyan Ma ◽  
Chengshuang Zhang ◽  
...  
Keyword(s):  
Phenol Formaldehyde ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
Phenol Formaldehyde Resin ◽  
Thermal Reaction ◽  
Formaldehyde Resin ◽  
Double Decker ◽  
Oligomeric Silsesquioxane

Purification of water contaminated with heavy metals by example of lead as promising material based on graphene nanostructures

2020 ◽  
pp. 34-43
Author(s):  
N. R. Memetov ◽  
◽  
A. V. Gerasimova ◽  
A. E. Kucherova ◽  
◽  
...  
Keyword(s):  
Adsorption Process ◽  
Phenol Formaldehyde ◽  
Phenol Formaldehyde Resin ◽  
Formaldehyde Resin ◽  
Parameter Estimates ◽  
Maximum Adsorption Capacity ◽  
Ecological Situation ◽  
Characteristic Parameters ◽  
Purification Of Water ◽  
Graphene Nanostructures

The paper evaluates the effectiveness of the use of graphene nanostructures in the purification of lead (II) ions to improve the ecological situation of water bodies. The mechanisms and characteristic parameters of the adsorption process were analyzed using empirical models of isotherms at temperatures of 298, 303, 313 and 323 K, which correspond to the following order (based on the correlation coefficient): Langmuir (0.99) > Temkin (0.97) > Dubinin – Radushkevich (0.90). The maximum adsorption capacity of the material corresponds to the range from 230 to 260 mg/g. We research the equilibrium at the level of thermodynamic parameter estimates, which indicates the spontaneity of the process, the endothermic nature and structure change of graphene modified with phenol-formaldehyde resin during the adsorption of lead (II) ions, leading to an increase in the disorder of the system.

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