Enhanced dielectric properties of sandwich‐structured biaxially oriented polypropylene by grafting hyper‐branched aromatic polyamide as surface layers

2020 ◽  
Vol 137 (34) ◽  
pp. 48990 ◽  
Author(s):  
Chengcheng Han ◽  
Xianhong Zhang ◽  
Dong Chen ◽  
Yuhong Ma ◽  
Changwen Zhao ◽  
...  
Author(s):  
Ilkka Rytöluoto ◽  
Mikael Ritamäki ◽  
Antonis Gitsas ◽  
Satu Pasanen ◽  
Kari Lahti

<p>This paper outlines our recent study on effects of cast film extrusion and biaxial orientation on the morphological development and dielectric performance of biaxially oriented polypropylene (PP) films based on two capacitor-grade isotactic PP (iPP) raw materials. Results on polymorphic composition, melting behavior, microstructure and dielectric properties are reported. Morphological development during film manufacturing is found to have a profound effect on film structure and dielectric characteristics. Formation of structural defects was traced back to beta --&gt; alfa crystal transformation upon biaxial stretching.</p>


Author(s):  
Ilkka Rytöluoto ◽  
Minna Niittymäki ◽  
Kari Lahti

The measurement and interpretation of high-field thermally stimulated depolarization current (TSDC) of capacitor-grade biaxially oriented polypropylene (BOPP) films are investigated in order to facilitate the derivation of trap parameters. Two main relaxations associable with the glass transition and detrapping of space charge from deep traps are observed, and their dependence on the polarization/depolarization conditions are studied. The complex bipolar nature of the space charge relaxation makes the derivation of trap parameters challenging. Lastly, a brief attempt is made to correlate the TSDC features with morphology and other short-term dielectric properties.


1988 ◽  
Vol 36 (5) ◽  
pp. 995-1009 ◽  
Author(s):  
Mitsuyoshi Fujiyama ◽  
Yoshimasa Kawamura ◽  
Tetsuo Wakino ◽  
Tomomi Okamoto

2008 ◽  
Vol 48 (4) ◽  
pp. 642-648 ◽  
Author(s):  
Y.J. Lin ◽  
P. Dias ◽  
H.Y. Chen ◽  
S. Chum ◽  
A. Hiltner ◽  
...  

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