Polyurethane foaming with CO
            2
            adducts from C
            8
            alkyl grafted polyethyleneimines: Optimization of the grafting rate and application of the blowing agents

Xiang Da; Chao Liu; Yuanzhu Long; Xingyi Xie

doi:10.1002/app.48752

Polyurethane foaming with CO 2 adducts from C 8 alkyl grafted polyethyleneimines: Optimization of the grafting rate and application of the blowing agents

Journal of Applied Polymer Science ◽

10.1002/app.48752 ◽

2019 ◽

Vol 137 (22) ◽

pp. 48752

Author(s):

Xiang Da ◽

Chao Liu ◽

Yuanzhu Long ◽

Xingyi Xie

Keyword(s):

Blowing Agents ◽

Polyurethane Foaming

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Polyurethane foaming with engineered CO2-releasing nanoparticles: From the thickening effect to the industrial applications of the blowing agents

Polymer ◽

10.1016/j.polymer.2018.04.009 ◽

2018 ◽

Vol 143 ◽

pp. 69-78 ◽

Cited By ~ 4

Author(s):

Yuanzhu Long ◽

Shuai Yuan ◽

Yaning Wang ◽

Xingyi Xie

Keyword(s):

Industrial Applications ◽

Blowing Agents ◽

Polyurethane Foaming

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Monitoring Polyurethane Foaming Reactions Using Near-Infrared Hyperspectral Imaging

Applied Spectroscopy ◽

10.1177/0003702820941877 ◽

2020 ◽

Vol 75 (1) ◽

pp. 46-56

Author(s):

Xiaoyun Chen ◽

Kshitish A. Patankar ◽

Matthew Larive

Keyword(s):

Hyperspectral Imaging ◽

Near Infrared ◽

Mixing Time ◽

Building Blocks ◽

Acquisition Time ◽

Blowing Agents ◽

Spectral Changes ◽

Methylene Diphenyl Diisocyanate ◽

Polyurethane Foaming ◽

Pu Foams

Polyurethane (PU) foams are finding increasingly wider applications ranging from memory foams and mattresses to cushions and insulation materials. They are prepared by reactions between multifunctional isocyanates and polyols as the two main building blocks, along with other additives, including the blowing agents. A non-contact near-infrared (NIR) hyperspectral imaging (HSI) camera was used in this study to monitor PU foaming reactions between a polymeric methylene diphenyl diisocyanate, polyol, and water. Five foams were prepared with three process variables: water content, mixing time, and catalyst levels. Spectral changes characteristic of the PU reactions were observed and clear difference in kinetics could be effectively extracted from such NIR HSI results. The NIR HSI technology offers two substantial advantages over the conventional Fourier transform- (FT-) NIR systems: (i) faster spectral acquisition time and (ii) higher spatial resolution of line images rather than the point measurement. Examples are provided to illustrate these two advantages. The potential to acquire chemical images of PU foams is also demonstrated.

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In situ synthesis of CO2 adducts of modified polyethylenimines in polyether polyols for polyurethane foaming

Journal of Cellular Plastics ◽

10.1177/0021955x20987153 ◽

2021 ◽

pp. 0021955X2098715

Author(s):

Shuai Yuan ◽

Yuanzhu Long ◽

Xingyi Xie

Keyword(s):

Propylene Glycol ◽

Monomethyl Ether ◽

Universal Method ◽

Molecular Weights ◽

Blowing Agents ◽

Hydrophobically Modified ◽

The Matrix ◽

Poly Propylene ◽

Polyurethane Foaming

CO2 adducts from hydrophobically-modified polyethylenimines (PEIs) in powder form are newly-developed environment-friendly blowing agents for polyurethanes (PUs). However, they are difficult to disperse into foaming systems that usually contain polyether polyols as the PU soft segments. Herein, we employ mixtures of di(propylene glycol) monomethyl ether-grafted polyethylenimines (DPG-PEIs) and poly(propylene glycol) (PPG) polyols to absorb CO2, with in situ formation of the CO2 adduct particles as PU blowing agents. Their CO2 saturation degrees, revealed by thermogravimetry, scatter in the range of 93–98%. The DPG side chains tend to be exposed at the particle–matrix interface to stabilize the particles. In addition, some PPG oligomers in the matrix might entangle with the CO2 adduct macromolecules during the in situ particle formation. The entangled PPG chains could further stabilize the suspending particles. The high grafting rate and high molecular weight of the PEI backbones could result in small particles, which largely thicken the foaming systems. The optimized blowing agents, with grafting rates between 5% and 8% and PEI backbone molecular weights not higher than 10k Da, show particle sizes from several hundreds of nanometers to ∼1 μm. The resultant foams demonstrate densities below 50 kg/m3 and compressive strengths over 200 kPa, comparable to the values from industrial foams. This in situ CO2 adduction has potential as a universal method suitable for PU foaming at an industrial scale.

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