Network regulation and properties optimization of glycidyl azide polymer‐based materials as a candidate of solid propellant binder via alternating the functionality of propargyl‐terminated polyether

2019 ◽  
Vol 136 (40) ◽  
pp. 48016 ◽  
Author(s):  
Chun Qi ◽  
Gen Tang ◽  
Xiang Guo ◽  
Changhua Liu ◽  
Ai‐min Pang ◽  
...  
Keyword(s):  
Solid Propellant ◽  
Glycidyl Azide Polymer ◽  
Glycidyl Azide ◽  
Propellant Binder

Energetic interpenetrating polymer network based on orthogonal azido–alkyne click and polyurethane for potential solid propellant

RSC Advances ◽  
2015 ◽  
Vol 5 (79) ◽  
pp. 64478-64485 ◽  
Author(s):  
Abbas Tanver ◽  
Mu-Hua Huang ◽  
Yunjun Luo ◽  
Syed Khalid ◽  
Tariq Hussain
Keyword(s):  
Low Temperature ◽  
Mechanical Strength ◽  
Solid Propellant ◽  
Polymer Network ◽  
Aerospace Industry ◽  
Interpenetrating Polymer Network ◽  
Glycidyl Azide Polymer ◽  
Energetic Polymer ◽  
Glycidyl Azide

High energetic propellants with synergistic mechanical strength are the prerequisites for aerospace industry and missile technology; though glycidyl azide polymer (GAP) is a renowned and a promising energetic polymer which shows poor mechanical and low-temperature properties.

DEVELOPMENT OF A DIRECT INJECTION GAS-HYBRID ROCKET SYSTEM USING GLYCIDYL AZIDE POLYMER

2019 ◽  
Vol 18 (2) ◽  
pp. 157-170
Author(s):  
Yutaka Wada ◽  
S. Hatano ◽  
Ayana Banno ◽  
Yo Kawabata ◽  
Hiroshi Hasegawa ◽  
...  
Keyword(s):  
Direct Injection ◽  
Hybrid Rocket ◽  
Glycidyl Azide Polymer ◽  
Rocket System ◽  
Glycidyl Azide

scholarly journals The Effect of Glycidyl Azide Polymer Grafted Tetrafunctional Isocyanate on Polytriazole Polyethylene Oxide-Tetrahydrofuran Elastomer and its Propellant Properties

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 278 ◽  
Author(s):  
Jinghui Hu ◽  
Weiqiang Tang ◽  
Yonghui Li ◽  
Jiyu He ◽  
Xiaoyan Guo ◽  
...  
Keyword(s):  
Mechanical Strength ◽  
Polyethylene Oxide ◽  
Mechanical Test ◽  
Glycidyl Azide Polymer ◽  
Interface Interaction ◽  
Ft Ir ◽  
Glycidyl Azide

A new energetic curing reagent, Glycidyl azide polymer grafted tetrafunctional isocyanate (N100-g-GAP) was synthesized and characterized by FT-IR and GPC approaches. Polytriazole polyethylene oxide-tetrahydrofuran (PTPET) elastomer was prepared by N100-g-GAP and alkynyl terminated polyethylene oxide-tetrahydrofuran (ATPET). The resulting PTPET elastomer was fully characterized by TGA, DMA, FTIR and mechanical test. The above analysis indicates that PTPET elastomers using N100-g-GAP as curing reagent have the potential for use in propellants. The overall formulation test of the composite propellants shows that this curing system can effectively enhance mechanical strength and bring a significant improvement in the interface interaction between the RDX & AP particles and binder matrix.

Studies on structure property correlation of cross-linked glycidyl azide polymer

2009 ◽  
Vol 114 (6) ◽  
pp. 3360-3368 ◽  
Author(s):  
S. K. Manu ◽  
T. L. Varghese ◽  
S. Mathew ◽  
K. N. Ninan
Keyword(s):  
Structure Property ◽  
Glycidyl Azide Polymer ◽  
Property Correlation ◽  
Glycidyl Azide

Preparation and curing behavior of high-stress solid propellant binder based on polydicyclopentadiene

2016 ◽  
Vol 29 (8) ◽  
pp. 931-936 ◽  
Author(s):  
Qili Sun ◽  
Song Ma ◽  
Zhen Ge ◽  
Yunjun Luo
Keyword(s):  
Ring Opening ◽  
Solid Propellant ◽  
First Generation ◽  
High Stress ◽  
Mechanical Analysis ◽  
Polymerization Reaction ◽  
Curing Behavior ◽  
Maximum Value ◽  
Cure Time ◽  
Propellant Binder

The ring-opening metathesis polymerization reaction of dicyclopentadiene (DCPD) was carried out using Grubbs first generation catalyst. Fourier transform infrared (FTIR), dynamic-thermo mechanical analysis (DMA), and Raman spectroscopy were used to investigate the curing behavior of this polymer. The FTIR results showed that DCPD had not cured completely and the polymers were composed of linear and cross-linked polydicyclopentadiene (PDCPD). The DMA test showed that the polymer possesses the glass transition temperature of linear PDCPD and cross-linked PDCPD, which had also proved the FTIR result. Furthermore, in order to explain the strange phenomenon that the band at 3004 cm−1 should have been detected in infrared spectrum, the Raman spectrum of PDCPD was applied to analyze the bonding mechanism of =C–H bond in the process of polymerization. Moreover, the real-time FTIR result cure formula showed that the cure degree increases first then constants trend with cure time of increasing, the cure degree reached the maximum value (96.76%) at 60°C for 192 h.

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