Controllable preparation and near infrared optical limiting properties of fluorene-containing polyacetylenes

2018 ◽  
Vol 135 (18) ◽  
pp. 46100 ◽  
Author(s):  
Gang Zhao ◽  
Gang Wei ◽  
Weiju Zhu ◽  
Fuyou Ke ◽  
Shanyi Guang ◽  
...  
Keyword(s):  
Near Infrared ◽  
Optical Limiting ◽  
Controllable Preparation

scholarly journals Polyfluorenylacetylene for near-infrared laser protection: polymer synthesis, optical limiting mechanism and relationship between molecular structure and properties

RSC Advances ◽  
2017 ◽  
Vol 7 (85) ◽  
pp. 53785-53796 ◽  
Author(s):  
Gang Zhao ◽  
Yan Feng ◽  
Shanyi Guang ◽  
Hongyao Xu ◽  
Naibo Lin ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Near Infrared ◽  
Optical Limiting ◽  
High Thermal Stability ◽  
Photon Absorption ◽  
Structure And Properties ◽  
Absorption Mechanism ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Good Solubility

The incorporation of styryl/stilbene–fluorene into polyacetylenes not only endowed the polymers with novel near-infrared optical limiting properties based on a two-photon absorption mechanism but good solubility and high thermal stability.

Ultrafast broadband reverse saturation absorption in Al-doped InSe thin films for optical limiting at visible/near-infrared

2020 ◽  
Vol 108 ◽  
pp. 110171 ◽  
Author(s):  
Xiaoyan Yan ◽  
Xingzhi Wu ◽  
Yu Fang ◽  
Wenjun Sun ◽  
Chengbao Yao ◽  
...  
Keyword(s):  
Thin Films ◽  
Near Infrared ◽  
Optical Limiting ◽  
Reverse Saturation Absorption ◽  
Saturation Absorption

scholarly journals Graphene Oxide-Based Silico-Phosphate Composite Films for Optical Limiting of Ultrashort Near-Infrared Laser Pulses

Nanomaterials ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1638 ◽  
Author(s):  
Adrian Petris ◽  
Ileana Cristina Vasiliu ◽  
Petronela Gheorghe ◽  
Ana Maria Iordache ◽  
Laura Ionel ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Femtosecond Laser ◽  
Near Infrared ◽  
Substrate Surface ◽  
Sol Gel ◽  
Composite Films ◽  
Laser Pulses ◽  
Optical Limiting ◽  
Femtosecond Laser Pulses ◽  
Glassy Matrix

The development of graphene-based materials for optical limiting functionality is an active field of research. Optical limiting for femtosecond laser pulses in the infrared-B (IR-B) (1.4–3 μm) spectral domain has been investigated to a lesser extent than that for nanosecond, picosecond and femtosecond laser pulses at wavelengths up to 1.1 μm. Novel nonlinear optical materials, glassy graphene oxide (GO)-based silico-phosphate composites, were prepared, for the first time to our knowledge, by a convenient and low cost sol-gel method, as described in the paper, using tetraethyl orthosilicate (TEOS), H3PO4 and GO/reduced GO (rGO) as precursors. The characterisation of the GO/rGO silico-phosphate composite films was performed by spectroscopy (Fourier-transform infrared (FTIR), Ultraviolet–Visible-Near Infrared (UV-VIS-NIR) and Raman) and microscopy (atomic force microscopy (AFM) and scanning electron microscopy (SEM)) techniques. H3PO4 was found to reduce the rGO dispersed in the precursor’s solution with the formation of vertically agglomerated rGO sheets, uniformly distributed on the substrate surface. The capability of these novel graphene oxide-based materials for the optical limiting of femtosecond laser pulses at 1550 nm wavelength was demonstrated by intensity-scan experiments. The GO or rGO presence in the film, their concentrations, the composite films glassy matrix, and the film substrate influence the optical limiting performance of these novel materials and are discussed accordingly.

scholarly journals Conjugated polymer-fullerene blend with strong optical limiting in the near-infrared

2009 ◽  
Vol 17 (24) ◽  
pp. 22062 ◽  
Author(s):  
San-Hui Chi ◽  
Joel M. Hales ◽  
Matteo Cozzuol ◽  
Charles Ochoa ◽  
Madison Fitzpatrick ◽  
...  
Keyword(s):  
Conjugated Polymer ◽  
Near Infrared ◽  
Optical Limiting

COMPARATIVE STUDIES ON THE THIRD-ORDER NONLINEAR OPTICAL PROPERTIES OF THREE METAL-ORGANIC COMPOUNDS

2011 ◽  
Vol 20 (02) ◽  
pp. 229-236 ◽  
Author(s):  
PENGFEI ZHANG
Keyword(s):  
Near Infrared ◽  
Heavy Atom ◽  
Picosecond Laser ◽  
Laser Pulses ◽  
Optical Limiting ◽  
Infrared Region ◽  
Photon Absorption ◽  
Third Order ◽  
The Third ◽  
Planar Transition

The third-order optical nonlinearities of three planar transition metal ( Ni, Cu and Pd ) compounds with rigid quadridentate Schiff base derived from S-benzyl dithiocarbazate, were investigated systematically by Z-scan technique with picosecond laser pulses at 1064 nm. The three compounds exhibit both strong two-photon absorption and effective self-focusing performance. Due to the heavy atom effect, the second hyperpolarizability of PdZ molecule (〈γ〉 = 1.2 × 10-29 esu) was found to be the highest compared to that of the other two molecules. The optical limiting properties were also measured, and the results suggest that PdZ may be a promising candidate for the application to optical limiting in the near-infrared region.

MoS2 nanosheets covalently functionalized with polyacrylonitrile: synthesis and broadband laser protection performance

2017 ◽  
Vol 5 (45) ◽  
pp. 11920-11926 ◽  
Author(s):  
Makai Shi ◽  
Ningning Dong ◽  
Nan He ◽  
Yan Wan ◽  
Hongxia Cheng ◽  
...  
Keyword(s):  
Near Infrared ◽  
Optical Limiting ◽  
Mos2 Nanosheets ◽  
Broadband Laser

Highly soluble polyacrylonitrile (PAN)-covalently grafted MoS2 nanosheets (MoS2–PAN) were synthesized in situ. This material shows superior optical limiting response in the visible and near-infrared ranges.

scholarly journals Metalloporphyrin polymer with temporally agile, broadband nonlinear absorption for optical limiting in the near infrared

2009 ◽  
Vol 17 (21) ◽  
pp. 18478 ◽  
Author(s):  
Joel M. Hales ◽  
Matteo Cozzuol ◽  
Thomas E. O. Screen ◽  
Harry L. Anderson ◽  
Joseph W. Perry
Keyword(s):  
Nonlinear Absorption ◽  
Near Infrared ◽  
Optical Limiting
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