Evaluation of CO2 adsorption capacity of electrospun carbon fibers with thermal and chemical activation

2017 ◽  
Vol 134 (47) ◽  
pp. 45534 ◽  
Author(s):  
Dong Woo Kim ◽  
Dong Won Jung ◽  
Adedeji A. Adelodun ◽  
Young Min Jo
Keyword(s):  
Adsorption Capacity ◽  
Carbon Fibers ◽  
Co2 Adsorption ◽  
Chemical Activation ◽  
Co2 Adsorption Capacity

CO2 adsorption capacity and kinetics in nitrogen-enriched activated carbon fibers prepared by different methods

2015 ◽  
Vol 281 ◽  
pp. 704-712 ◽  
Author(s):  
Noel Díez ◽  
Patricia Álvarez ◽  
Marcos Granda ◽  
Clara Blanco ◽  
Ricardo Santamaría ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Adsorption Capacity ◽  
Carbon Fibers ◽  
Co2 Adsorption ◽  
Activated Carbon Fibers ◽  
Co2 Adsorption Capacity

scholarly journals Development of Rubber Seed Shell–Activated Carbon Using Impregnated Pyridinium-Based Ionic Liquid for Enhanced CO2 Adsorption

Processes ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 1161
Author(s):  
Nawwarah Mokti ◽  
Azry Borhan ◽  
Siti Zaine ◽  
Hayyiratul Mohd Zaid
Keyword(s):  
Ionic Liquid ◽  
Activated Carbon ◽  
Adsorption Capacity ◽  
Co2 Adsorption ◽  
Chemical Activation ◽  
Total Pore Volume ◽  
Isosteric Heat ◽  
Rubber Seed ◽  
Study Results ◽  
Co2 Adsorption Capacity

In this study, rubber seed shell was used for the production of activated carbon by chemical activation using an ionic liquid, [C4Py][Tf2N] as an activating agent. Sample RSS-IL 800 shows the highest specific surface area of 393.99 m2/g, a total pore volume of 0.206 cm3/g, and a micropore volume of 0.172 cm3/g. The performance of AC samples as an adsorbent for CO2 was also studied using a static volumetric technique evaluated at a temperature of 25 °C and 1 bar pressure. The CO2 adsorption capacity for sample RSS-IL 800 was 2.436 mmol/g, comparable with reported data from the previous study. Results also show that the CO2 adsorption capacity decreased at a higher temperature between 50 and 100 °C and increased at elevated pressure due to its exothermic behavior. The Langmuir model fits the adsorption data well, and the isosteric heat of adsorption proved that the physisorption process and exothermic behavior occur.

EVALUATION OF MODIFIED FLY ASH BASED NAA-ZEOLITE: EFFECT OF CRYSTALLINITY ON CO2 ADSORPTION CAPACITY

2019 ◽  
Vol 19 (3) ◽  
pp. 475-483 ◽  
Author(s):  
Muvumbu Jean-Luc Mukaba ◽  
Alechine Emmanuel Ameh ◽  
Chuks Paul Eze ◽  
Leslie Felicia Petrik
Keyword(s):  
Fly Ash ◽  
Adsorption Capacity ◽  
Co2 Adsorption ◽  
Naa Zeolite ◽  
Co2 Adsorption Capacity ◽  
Modified Fly Ash

scholarly journals The Increase of the Micoporosity and CO2 Adsorption Capacity of the Commercial Activated Carbon CWZ-22 by KOH Treatment

10.5772/63672 ◽  
2016 ◽  
Author(s):  
Joanna Srenscek-Nazzal ◽  
Urszula Narkiewicz ◽  
Antoni W. Morawski ◽  
Rafal J. Wróbel ◽  
Beata Michalkiewicz
Keyword(s):  
Activated Carbon ◽  
Adsorption Capacity ◽  
Co2 Adsorption ◽  
Co2 Adsorption Capacity

Physico-chemical modification of natural mordenite-clinoptilolite zeolites and their enhanced CO2 adsorption capacity

2020 ◽  
Vol 294 ◽  
pp. 109871 ◽  
Author(s):  
Satriyo Krido Wahono ◽  
Joseph Stalin ◽  
Jonas Addai-Mensah ◽  
William Skinner ◽  
Ajayan Vinu ◽  
...  
Keyword(s):  
Chemical Modification ◽  
Adsorption Capacity ◽  
Co2 Adsorption ◽  
Physico Chemical ◽  
Co2 Adsorption Capacity

scholarly journals Supercritical CO2 Exposure-Induced Surface Property, Pore Structure, and Adsorption Capacity Alterations in Various Rank Coals

Energies ◽  
2019 ◽  
Vol 12 (17) ◽  
pp. 3294 ◽  
Author(s):  
Zhenjian Liu ◽  
Zhenyu Zhang ◽  
Xiaoqian Liu ◽  
Tengfei Wu ◽  
Xidong Du
Keyword(s):  
Coal Seam ◽  
Pore Structure ◽  
Adsorption Capacity ◽  
Surface Property ◽  
Supercritical Co2 ◽  
Co2 Adsorption ◽  
Low Pressure ◽  
Coal Seam Gas ◽  
Adsorption Sites ◽  
Co2 Adsorption Capacity

Carbon dioxide (CO2) has been used to replace coal seam gas for recovery enhancement and carbon sequestration. To better understand the alternations of coal seam in response to CO2 sequestration, the properties of four different coals before and after supercritical CO2 (ScCO2) exposure at 40 °C and 16 MPa were analyzed with Fourier Transform infrared spectroscopy (FTIR), low-pressure nitrogen, and CO2 adsorption methods. Further, high-pressure CO2 adsorption isotherms were performed at 40 °C using a gravimetric method. The results indicate that the density of functional groups and mineral matters on coal surface decreased after ScCO2 exposure, especially for low-rank coal. With ScCO2 exposure, only minimal changes in pore shape were observed for various rank coals. However, the micropore specific surface area (SSA) and pore volume increased while the values for mesopore decreased as determined by low-pressure N2 and CO2 adsorption. The combined effects of surface property and pore structure alterations lead to a higher CO2 adsorption capacity at lower pressures but lower CO2 adsorption capacity at higher pressures. Langmuir model fitting shows a decreasing trend in monolayer capacity after ScCO2 exposure, indicating an elimination of the adsorption sites. The results provide new insights for the long-term safety for the evaluation of CO2-enhanced coal seam gas recovery.

scholarly journals CVD Synthesis, Functionalization and CO2 Adsorption Attributes of Multiwalled Carbon Nanotubes

Processes ◽  
2019 ◽  
Vol 7 (9) ◽  
pp. 634 ◽  
Author(s):  
Shazia Shukrullah ◽  
Muhammad Yasin Naz ◽  
Norani M. Mohamed ◽  
Khalid A. Ibrahim ◽  
Nasser M. AbdEl-Salam ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Nanotubes ◽  
Adsorption Capacity ◽  
Multiwalled Carbon Nanotubes ◽  
Functional Groups ◽  
Co2 Adsorption ◽  
Breakthrough Curves ◽  
Multiwalled Carbon ◽  
Amine Functionalized ◽  
Co2 Adsorption Capacity

Carbon dioxide is one of the major greenhouse gases and a leading source of global warming. Several adsorbent materials are being tested for removal of carbon dioxide (CO2) from the atmosphere. The use of multiwalled carbon nanotubes (MWCNTs) as a CO2 adsorbent material is a relatively new research avenue. In this study, Fe2O3/Al2O3 composite catalyst was used to synthesize MWCNTs by cracking ethylene gas molecules in a fluidized bed chemical vapor deposition (CVD) chamber. These nanotubes were treated with H2SO4/HNO3 solution and functionalized with 3-aminopropyl-triethoxysilane (APTS). Chemical modification of nanotubes removed the endcaps and introduced some functional groups along the sidewalls at defected sites. The functionalization of nanotubes with amine introduced carboxylic groups on the tube surface. These functional groups significantly enhance the surface wettability, hydrophilicity and CO2 adsorption capacity of MWCNTs. The CO2 adsorption capacity of as-grown and amine-functionalized CNTs was computed by generating their breakthrough curves. BELSORP-mini equipment was used to generate CO2 breakthrough curves. The oxidation and functionalization of MWCNTs revealed significant improvement in their adsorption capacity. The highest CO2 adsorption of 129 cm3/g was achieved with amine-functionalized MWCNTs among all the tested samples.

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