Graft copolymerization of methyl methacrylate from brominated poly(isobutylene-co-isoprene) via atom transfer radical polymerization

2016 ◽  
Vol 133 (19) ◽  
pp. n/a-n/a
Author(s):  
Jinyuan Wang ◽  
Chaoying Wan ◽  
Yong Zhang ◽  
Yinghao Zhai ◽  
Shiqiang Song ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Graft Copolymerization ◽  
Atom Transfer

Synthesis of Amylopectin Macro-Initiator for Graft Copolymerization of Amylopectin-g-Poly(Methyl Methacrylate) by ATRP (Atom Transfer Radical Polymerization)

2015 ◽  
Vol 827 ◽  
pp. 306-310 ◽  
Author(s):  
Aniek S. Handayani ◽  
Is Sulistyati Purwaningsih ◽  
Muhamad Chalid ◽  
Emil Budianto ◽  
Dedi Priadi
Keyword(s):  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Graft Copolymer ◽  
Graft Copolymerization ◽  
Homogeneous System ◽  
Hydroxyl Groups ◽  
Atom Transfer ◽  
Tert Butyl ◽  
Product Characterization

Graft copolymer of Amylopectin and PMMA was synthesized by atom transfer radical polymerization (ATRP) method. The hydroxyl groups of amylopectin partially substituted with tert-butyl a-bromoisobutyrate to form tert-butyl a-bromoisobutyrate (TBBiB ) groups. This compound is known as an efficient macro-initiator for ATRP process. This research, aimed to obtain a bio based polymer of Amylopectin, in which the amylopectin was used as macro-initiator in the ATRP of MMA. The experiment was carried out in the homogeneous system under temperature range of 40 – 70°C in DMSO solution using TEA as catalyst. The modified amylopectin-TBBiB then was grafted to methyl methacrylate trough ATRP. Product characterization indicates that the graft copolymer Amylopectin-g-PMMA is efficient and the obtained product owns well defined structures

Atom Transfer Radical Polymerization of Methyl Methacrylate Initiated by Alkyl Bromide and 2-Pyridinecarbaldehyde Imine Copper(I) Complexes

1997 ◽  
Vol 30 (7) ◽  
pp. 2190-2193 ◽  
Author(s):  
David M. Haddleton ◽  
Christina B. Jasieczek ◽  
Michael J. Hannon ◽  
Andrew J. Shooter
Keyword(s):  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Alkyl Bromide
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