Effect of the compatibility on dielectric performance and breakdown strength of poly(vinylidene fluoride)/low-density polyethylene blends

2015 ◽  
Vol 132 (36) ◽  
pp. n/a-n/a ◽  
Author(s):  
Xiang Lin ◽  
Li-Li Fan ◽  
Jun Zhao ◽  
Zhi-Min Dang ◽  
Dong-Yun Ren
Keyword(s):  
Vinylidene Fluoride ◽  
Breakdown Strength ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Polyethylene Blends ◽  
Dielectric Performance ◽  
Poly Vinylidene Fluoride

scholarly journals Preparation of the high dielectric performance flexible materials achieved by polyacrylamide/poly(vinylidene fluoride) blends

e-Polymers ◽  
2011 ◽  
Vol 11 (1) ◽  
Author(s):  
Rui Li ◽  
Chuanxi Xiong ◽  
Lijie Dong
Keyword(s):  
Dielectric Constant ◽  
Flexible Electronics ◽  
High Dielectric Constant ◽  
Vinylidene Fluoride ◽  
Volume Fraction ◽  
Breakdown Strength ◽  
Dielectric Behavior ◽  
Dielectric Performance ◽  
Poly Vinylidene Fluoride ◽  
High Dielectric

AbstractA novel all-polymeric material with high dielectric constant (k) has been developed by blending poly(vinylidene fluoride) (PVDF) with polyacrylamide (PAM). The dependence of the dielectric constant on frequency and polymer volume fraction was investigated. When the weight fraction of PAM is 1wt%, the dielectric constant of the blend could be up to 24, and the dielectric loss tanδ can be lowered to 0.06. The SEM investigations suggest that the enhanced dielectric behavior originates from significant interfacial interactions of polymer-polymer. XRD and FTIR demonstrate that blending PAM with PVDF affects the crystalline behavior of each component. Our finding suggests that the created high-k polymeric blends represent a novel type of material that are flexible and easy to process, and is of relatively high dielectric constant and high breakdown strength; moreover find applications as flexible electronics.

Melt rheology of poly(vinylidene fluoride) (PVDF)/low density polyethylene (LDPE) blends

2015 ◽  
Vol 57 (2) ◽  
pp. 233-238 ◽  
Author(s):  
Mosab Kaseem ◽  
Kotiba Hamad ◽  
Hae Woong Yang ◽  
Yong Hwan Lee ◽  
Fawaz Deri ◽  
...  
Keyword(s):  
Vinylidene Fluoride ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Melt Rheology ◽  
Poly Vinylidene Fluoride

scholarly journals Effects of Interfacial Charge on the DC Dielectric Properties of Nanocomposites

2016 ◽  
Vol 2016 ◽  
pp. 1-11 ◽  
Author(s):  
Jiaming Yang ◽  
Congji Liu ◽  
Changji Zheng ◽  
Hong Zhao ◽  
Xuan Wang ◽  
...  
Keyword(s):  
Dielectric Properties ◽  
Breakdown Strength ◽  
Interface Layer ◽  
Low Density Polyethylene ◽  
X Ray ◽  
X Ray Scattering ◽  
Scattering Effects ◽  
Dielectric Performance ◽  
Positive Effect ◽  
Interfacial Charge

The interfacial charge phenomenon of MgO/low-density polyethylene (LDPE) and SiO2/LDPE nanocomposites was measured by synchrotron radiation small-angle X-ray scattering. Based on the Porod theory, the Porod curve of SiO2/LDPE nanocomposite shows negative divergence but the LDPE and MgO/LDPE do not, which reveals that interfacial charge may exist in the SiO2/LDPE nanocomposite. The DC dielectric properties of the nanocomposites are closely related to the interfacial charge. Experimental results show that the SiO2/LDPE nanocomposite has lower DC conductivity, less space charge, and higher DC breakdown strength than the MgO/LDPE nanocomposite. It is thought that the interfacial charge has a positive effect on the DC dielectric performance of nanocomposites, and the mechanism could be attributed to the scattering effects of the interfacial charge on the carrier migration. There is no obvious interfacial charge in the MgO/LDPE nanocomposite, but it still has excellent DC dielectric properties compared with LDPE, which indicates that the interfacial charge is not the only factor affecting the dielectric properties; the dipole interface layer and the reduction of free volume can also inhibit the migration of carriers and decrease electrons free path, improving the dielectric performance.

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