High-temperature-resistant polymer gel system with metal-organic mixed cross-linking agents

2015 ◽  
Vol 132 (29) ◽  
pp. n/a-n/a ◽  
Author(s):  
Xiaoyun Zhang ◽  
Sisi Zhang ◽  
Liang Li ◽  
Ruonan Wu ◽  
Dongming Liu ◽  
...  
Keyword(s):  
High Temperature ◽  
Cross Linking ◽  
Polymer Gel ◽  
Metal Organic ◽  
Gel System

Development of a Polymer Gel System for Improved Sweep Efficiency and Injection Profile Modification of IOR/EOR Treatments

2014 ◽  
Author(s):  
Freddy Crespo ◽  
B. R. Reddy ◽  
Larry Eoff ◽  
Christopher Lewis ◽  
Natalie Pascarella
Keyword(s):  
Polymer Gel ◽  
Sweep Efficiency ◽  
Profile Modification ◽  
Gel System

scholarly journals HKUST-1@IL-Li Solid-state Electrolyte with 3D Ionic Channels and Enhanced Fast Li+ Transport for Lithium Metal Batteries at High Temperature

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 736
Author(s):  
Man Li ◽  
Tao Chen ◽  
Seunghyun Song ◽  
Yang Li ◽  
Joonho Bae
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid Electrolyte ◽  
Metal Organic Framework ◽  
Ionic Channels ◽  
Transference Numbers ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Metal Organic ◽  
Organic Framework

The challenge of safety problems in lithium batteries caused by conventional electrolytes at high temperatures is addressed in this study. A novel solid electrolyte (HKUST-1@IL-Li) was fabricated by immobilizing ionic liquid ([EMIM][TFSI]) in the nanopores of a HKUST-1 metal–organic framework. 3D angstrom-level ionic channels of the metal–organic framework (MOF) host were used to restrict electrolyte anions and acted as “highways” for fast Li+ transport. In addition, lower interfacial resistance between HKUST-1@IL-Li and electrodes was achieved by a wetted contact through open tunnels at the atomic scale. Excellent high thermal stability up to 300 °C and electrochemical properties are observed, including ionic conductivities and Li+ transference numbers of 0.68 × 10-4 S·cm-1 and 0.46, respectively, at 25 °C, and 6.85 × 10-4 S·cm-1 and 0.68, respectively, at 100 °C. A stable Li metal plating/stripping process was observed at 100 °C, suggesting an effectively suppressed growth of Li dendrites. The as-fabricated LiFePO4/HKUST-1@IL-Li/Li solid-state battery exhibits remarkable performance at high temperature with an initial discharge capacity of 144 mAh g-1 at 0.5 C and a high capacity retention of 92% after 100 cycles. Thus, the solid electrolyte in this study demonstrates promising applicability in lithium metal batteries with high performance under extreme thermal environmental conditions.

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