Toughening-modified epoxy-amine system: Cure kinetics, mechanical behavior, and shape memory performances

2014 ◽  
Vol 131 (19) ◽  
pp. n/a-n/a ◽  
Author(s):  
Xianghai Jing ◽  
Yuyan Liu ◽  
Yuxi Liu ◽  
Zhenguo Liu ◽  
Huifeng Tan
2012 ◽  
Vol 51 (6) ◽  
pp. 2586-2595 ◽  
Author(s):  
Jyotishkumar Parameswaran Pillai ◽  
Jürgen Pionteck ◽  
Rüdiger Häßler ◽  
Christophe Sinturel ◽  
Viju Susan Mathew ◽  
...  

2009 ◽  
Vol 58 (8) ◽  
pp. 954-961 ◽  
Author(s):  
Eskandar Mounif ◽  
Genhai G Liang ◽  
Wayne D Cook ◽  
Veronique Bellenger ◽  
Aabbas Tcharkhatchi

Author(s):  
Maryam Jouyandeh ◽  
Mohammad Reza Ganjali ◽  
Mehdi Mehrpooya ◽  
Otman Abida ◽  
Karam Jabbour ◽  
...  

There was a question on “how lanthanides doping in iron oxide affects cure kinetics of epoxy-based nanocomposites?” To answer, we synthesized samarium (Sm)-doped Fe3O4 nanoparticles via electrochemical method and characterized it using FTIR, XRD, FE-SEM, EDX, TEM, and XPS analyses. The magnetic particles were uniformly dispersed in epoxy resin to increase the curability of the epoxy/amine system. The effect of the lanthanide dopant on the curing reaction of epoxy with amine was explored by modeling DSC experimental data based on model-free methodology. It was found that Sm3+ in the structure of Fe3O4 crystal participates in cross-linking of epoxy by catalyzing the reaction between epoxide rings and amine groups of curing agents. In addition, the etherification reaction of active OH groups on the surface of nanoparticles reacts with epoxy rings which prolongs the reaction time at the late stage of reaction where diffusion is the dominant mechanism.


Author(s):  
David L. Safranski ◽  
Jennifer M. Boothby ◽  
Cambre N. Kelly ◽  
Kyle Beatty ◽  
Nishant Lakhera ◽  
...  

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