Dependence of alcohol vapor-induced crystallization on gas and vapor permeabilities of poly(lactic acid) films

2013 ◽  
Vol 131 (8) ◽  
pp. n/a-n/a ◽  
Author(s):  
Shuichi Sato ◽  
Takayuki Wada ◽  
Ryohei Ido ◽  
Yoshiyuki Murakoshi ◽  
Shinji Kanehashi ◽  
...  
Author(s):  
Y. Moriizumi ◽  
K. Nagai

In this study, the sorption amount of alcohols (ethanol, 1-propanol, and 2-propanol) vapors on poly(lactic acid) (PLA) membrane was measured resulting in high increase in sorption. Sorption amount increases as the molecular volume of vapor decreases in the low-pressure region. The sorption amount of branched 2-propanol is lower than that of linear 1-propanol. In the high-pressure region, the PLA film tends to swell or plasticize as the cluster size increases, thereby increasing sorption. In addition, the alcohol vapor sorbed in the PLA film causes vapor-induced crystallization, which is in contrast to solvent- and thermally-induced crystallization, and forms an unknown crystal structure.


2012 ◽  
Vol 261 ◽  
pp. 528-535 ◽  
Author(s):  
Jian Gao ◽  
Lingyan Duan ◽  
Guanghui Yang ◽  
Qin Zhang ◽  
Mingbo Yang ◽  
...  

2015 ◽  
Vol 133 (6) ◽  
pp. n/a-n/a ◽  
Author(s):  
Zhefeng Chen ◽  
Shuyang Zhang ◽  
Feng Wu ◽  
Wei Yang ◽  
Zhengying Liu ◽  
...  

2019 ◽  
Vol 119 ◽  
pp. 410-420 ◽  
Author(s):  
Amirjalal Jalali ◽  
Michel A. Huneault ◽  
Mohammadreza Nofar ◽  
Patrik C. Lee ◽  
Chul B. Park

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