Hydrogen-bonded supramolecular polymers as self-healing hydrogels: Effect of a bulky adamantyl substituent in the ureido-pyrimidinone monomer

2013 ◽  
Vol 131 (4) ◽  
pp. n/a-n/a ◽  
Author(s):  
Traian V. Chirila ◽  
Hui Hui Lee ◽  
Mathieu Oddon ◽  
Marko M. L. Nieuwenhuizen ◽  
Idriss Blakey ◽  
...  
Keyword(s):  
Supramolecular Polymers ◽  
Self Healing ◽  
Adamantyl Substituent ◽  
Hydrogen Bonded

scholarly journals 3D Printing of Solvent-Free Supramolecular Polymers

2021 ◽  
Vol 9 ◽  
Author(s):  
Harald Rupp ◽  
Wolfgang H. Binder
Keyword(s):  
3D Printing ◽  
Dynamic Properties ◽  
Polymeric Materials ◽  
Fundamental Principle ◽  
Supramolecular Polymers ◽  
Fused Deposition Modelling ◽  
Self Healing ◽  
Polymer Science ◽  
Fused Deposition ◽  
Molecular Ordering

Additive manufacturing has significantly changed polymer science and technology by engineering complex material shapes and compositions. With the advent of dynamic properties in polymeric materials as a fundamental principle to achieve, e.g., self-healing properties, the use of supramolecular chemistry as a tool for molecular ordering has become important. By adjusting molecular nanoscopic (supramolecular) bonds in polymers, rheological properties, immanent for 3D printing, can be adjusted, resulting in shape persistence and improved printing. We here review recent progress in the 3D printing of supramolecular polymers, with a focus on fused deposition modelling (FDM) to overcome some of its limitations still being present up to date and open perspectives for their application.

scholarly journals Aqueous interfacial gels assembled from small molecule supramolecular polymers

2017 ◽  
Vol 8 (2) ◽  
pp. 1350-1355 ◽  
Author(s):  
Alexander S. Groombridge ◽  
Aniello Palma ◽  
Richard M. Parker ◽  
Chris Abell ◽  
Oren A. Scherman
Keyword(s):  
Small Molecules ◽  
Small Molecule ◽  
Self Assembly ◽  
Hyperbranched Polymer ◽  
Soft Matter ◽  
Supramolecular Polymers ◽  
Supramolecular Network ◽  
Self Healing ◽  
Liquid Interfaces ◽  
Stimuli Responsive

The successful self-assembly of a stimuli-responsive aqueous supramolecular hyperbranched polymer from small molecules and the macrocyclic host cucurbit[8]uril (CB[8]) is reported. This self-healing supramolecular network can act as a soft matter barrier at liquid–liquid interfaces.

Constructing Electrically and Mechanically Self-Healing Elastomers by Hydrogen Bonded Intermolecular Network

Langmuir ◽  
2020 ◽  
Vol 36 (12) ◽  
pp. 3029-3037 ◽  
Author(s):  
Ruiyu Yang ◽  
Yujin Yao ◽  
Zaihua Duan ◽  
Zhen Yuan ◽  
Huiling Tai ◽  
...  
Keyword(s):  
Self Healing ◽  
Hydrogen Bonded

scholarly journals Hierarchical formation of helical supramolecular polymers via stacking of hydrogen-bonded pairs in water

2002 ◽  
Vol 99 (8) ◽  
pp. 4977-4982 ◽  
Author(s):  
L. Brunsveld ◽  
J. A. J. M. Vekemans ◽  
J. H. K. K. Hirschberg ◽  
R. P. Sijbesma ◽  
E. W. Meijer
Keyword(s):  
Supramolecular Polymers ◽  
Hydrogen Bonded
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