Physical properties of poly lactic acid/clay nanocomposite films: Effect of filler content and annealing treatment

2013 ◽  
Vol 131 (2) ◽  
pp. n/a-n/a ◽  
Author(s):  
Pietro Russo ◽  
Sara Cammarano ◽  
Emiliano Bilotti ◽  
Ton Peijs ◽  
Pierfrancesco Cerruti ◽  
...  
2015 ◽  
Vol 264 ◽  
pp. 538-546 ◽  
Author(s):  
Li Zhang ◽  
Yinfeng Li ◽  
Huanhuan Wang ◽  
Yadong Qiao ◽  
Jinzhou Chen ◽  
...  

2015 ◽  
Vol 659 ◽  
pp. 570-574 ◽  
Author(s):  
Apinya Musidang ◽  
Nantana Jiratumnukul

UV-curable process is widely used for paints, inks and adhesives due to its rapid curing, low energy consumption, high efficiency and low volatile organic compounds (VOCs). The objective of this research is to prepare poly(lactic acid) (PLA) based UV-curable coating by using glycolyzed PLA. PLA was glycolyzed by ethylene glycol (EG) at 170°C for 90 minutes. The obtained glycolyzed PLA was reacted with methacrylic anhydride (MAAH) to provide PLA acrylate oligomer. The obtained PLA acrylate oligomer was used in coating formulations with various amounts of photoinitiator and cured under UV radiation. Physical properties of cured coating film were investigated such as pencil hardness, gloss and haze. The results showed that poly(lactic acid) (PLA) based UV-curable coating provided good physical properties.


2012 ◽  
Vol 20 (12) ◽  
pp. 1300-1306 ◽  
Author(s):  
Jun Yong Park ◽  
Sung Yeon Hwang ◽  
Won Jae Yoon ◽  
Eui Sang Yoo ◽  
Seung Soon Im

Materials ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 2346 ◽  
Author(s):  
Stanislav Kotsilkov ◽  
Evgeni Ivanov ◽  
Nikolay Vitanov

Nanoparticles of graphene and carbon nanotubes are attractive materials for the improvement of mechanical and barrier properties and for the functionality of biodegradable polymers for packaging applications. However, the increase of the manufacture and consumption increases the probability of exposure of humans and the environment to such nanomaterials; this brings up questions about the risks of nanomaterials, since they can be toxic. For a risk assessment, it is crucial to know whether airborne nanoparticles of graphene and carbon nanotubes can be released from nanocomposites into the environment at their end-life, or whether they remain embedded in the matrix. In this work, the release of graphene and carbon nanotubes from the poly(lactic) acid nanocomposite films were studied for the scenarios of: (i) biodegradation of the matrix polymer at the disposal of wastes; and (ii) combustion and fire of nanocomposite wastes. Thermogravimetric analysis in air atmosphere, transmission electron microscopy (TEM), atomic force microscopy (AFM) and scanning electron microscope (SEM) were used to verify the release of nanoparticles from nanocomposite films. The three factors model was applied for the quantitative and qualitative risk assessment of the release of graphene and carbon nanotubes from nanocomposite wastes for these scenarios. Safety concern is discussed in respect to the existing regulations for nanowaste stream.


2020 ◽  
Author(s):  
Nurfarahin Mohd Nordin ◽  
Hazleen Anuar ◽  
Yose Fachmi Buys ◽  
Fathilah Ali ◽  
Sabu Thomas ◽  
...  

2011 ◽  
Vol 335-336 ◽  
pp. 153-156
Author(s):  
Xue Li Wu ◽  
Jian Hui Qiu ◽  
Lin Lei ◽  
Yang Zhao ◽  
Eiichi Sakai

To consider the effective utilization of plastics and agricultural wastes, rice straw fibre was extracted from agricultural wastes, and then composited with polylactic acid(PLA). The thermal stability of straw/poly(lactic acid)(straw/PLA) composites decreased (Thermogravimetric Analysis, TGA). Tensile strength, fracture strain and sharply impact strength of straw/PLA were decreased with the increase of filler content and grain size of straw. Yong’s modulus were increased as the increasing of straw content.


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