Preparation and properties of a dispersing fluid loss additive based on humic acid graft copolymer suitable for cementing high temperature (200°C) oil wells

2013 ◽  
Vol 129 (5) ◽  
pp. 2544-2553 ◽  
Author(s):  
Oyewole Taye Salami ◽  
Johann Plank
Keyword(s):  
High Temperature ◽  
Humic Acid ◽  
Graft Copolymer ◽  
Oil Wells ◽  
Fluid Loss ◽  
Fluid Loss Additive

Research of Nanosilica Particles Grafted with Functional Polymer Used as Fluid Loss Additive for Cementing under Ultra-High Temperature

2016 ◽  
Vol 847 ◽  
pp. 497-504
Author(s):  
Xiu Jian Xia ◽  
Jin Tang Guo ◽  
Shuo Qiong Liu ◽  
Jian Zhou Jin ◽  
Yong Jin Yu ◽  
...  
Keyword(s):  
High Temperature ◽  
Salt Tolerance ◽  
Thermal Resistance ◽  
Fluid Loss ◽  
Cement Slurry ◽  
Silica Nanocomposite ◽  
Nanosilica Particles ◽  
Loss Control ◽  
Fluid Loss Additive ◽  
Ultra High Temperature

On account of that the domestic polymer fluid loss additive exists some severe problems, such as, inferior thermal resistance, poor salt tolerance, strong shear-and thermal thinning behavior, a novel polymer/silica nanocomposite PADMO-V@NS is used as ultra-high temperature fluid loss control additive for cementing. In the present study PADMO-V@NS was prepared through an in situ free radical copolymerization of 2-acrylamico-2-methylpropane sulfonic acid (AMPS), N,N-dimethylacryl amide (DMAM), maleic anhydride (MA), octadecyl dimethylallyl ammonium chloride (ODAAC) and triethoxyvinylsilane (VTS) modified nanosilica. The linear hydrophobic associated copolymer was regarded as the shell and the modified nanosilica as the core. The microstructure, compositions and thermal resistance of PADMO-V@NS were investigated through FTIR and TGA techniques. The results showed that the copolymer modified with nanosilica particles possessed more excellent thermal stability than that of PADMO, and the most rapid decomposing temperature of PADMO-V@NS was highly up to 396.9°C. The application performance of PADMO-V@NS in cement slurry exhibited that it had excellent fluid loss control capacity, good high temperature resistance, strong salt tolerance and mild shear-/ thermal thinning performance, and could be used in 220°C and saturated brine circumstances. Moreover, comparing to PADMO, the compressive strength of set cement containing the copolymer increased over 20 % at 80°C, atmosphere pressure and curing time of 1 day due to the reaction of residual silanol groups with Ca (OH)2. The laboratory research results indicated that the multi-functional fluid loss additive composed of hydrophobic associated polymer/silica nanocomposite had bestowed on the cement slurry systems good comprehensive properties, and may have extensive applications in deep & ultra-deep oil/gas wells cementing.

A Novel Cement Fluid Loss Additive P1402

2014 ◽  
Vol 941-944 ◽  
pp. 1203-1207 ◽  
Author(s):  
Qiang Xiao ◽  
Wen Fa Xiao ◽  
Xin Xin Liu
Keyword(s):  
Thermal Stability ◽  
Aqueous Solution ◽  
High Temperature ◽  
Reaction Time ◽  
Performance Testing ◽  
Fluid Loss ◽  
Solution Polymerization ◽  
Excellent Thermal Stability ◽  
Aqueous Solution Polymerization ◽  
Fluid Loss Additive

A novel cement fluid loss additive P1402, which synthesized using the monomers of 2-acrylamido-2-methyl-propane sulphonic acid (AMPS), acrylic acid (AA), N,N dimethyl acrylamide (DMAM) and N-Vinyl-2-pyrrolidone (NVP) by the method of aqueous solution polymerization. The ratio of monomers AMPS:AA:DMAM:NVP at 2:1.5:1:1, reaction PH at 10.8, reaction temperature at 65°Cand reaction time about 5 hours. The IR spectrum of P1402 show that the polymer with the structure of all the monomers .The fluid loss performance testing show that the forpolymers P1402 has an excellent thermal stability. The fluid loss additive P1402 has an excellent tolerance to salt and high temperature.

New Diblock Copolymers as Fluid Loss Additive for High Temperature Cementing

2016 ◽  
Author(s):  
A. Cadix ◽  
J. Wilson ◽  
Ch. Phan ◽  
L. Villafane ◽  
J. -R. Gomez ◽  
...  
Keyword(s):  
High Temperature ◽  
Diblock Copolymers ◽  
Fluid Loss ◽  
Fluid Loss Additive

Synthesis and Characterization of Substituted-Ammonium Humic Acid Fluid Loss Additive for Oil-Based Drilling Fluids

2014 ◽  
Vol 1004-1005 ◽  
pp. 623-626 ◽  
Author(s):  
Cha Ma ◽  
Long Li ◽  
Gang Wang ◽  
Xu Bo Yuan
Keyword(s):  
Humic Acid ◽  
New Product ◽  
Extreme Condition ◽  
Fluid Loss ◽  
Drilling Fluids ◽  
Reaction Conditions ◽  
Acid Fluid ◽  
Optimal Reaction ◽  
Fluid Loss Additive

Using widely distributed and cheap lignite as starting material, humic acid was modified by octadecylamine, and a new kind of humic acid acetamide was prepared. The optimal reaction conditions of the humic acid acetamide polymer were obtained through laboratory tests as follow: the ratio of of humic acid and octadecylamine was 1:1.5, the reaction temperature was 150 °C, and the reaction time was 16~18 h. The new product was characterized by IR, and the results showed that this substituted-ammonium humic acid was successfully prepared by reacting parts of carboxyl group of humic acid with octadecylamine. HTHP filtration experiments demonstrated that the substituted-ammonium humic acid had good fluid loss properties. As a result, this substituted-ammonium humic acid polymer is an excellent fluid loss additive, and it could meet the requirement of drilling operation under extreme condition.

A New Type of Fluid Loss Additive P1301 for Oil Field Cementing

2014 ◽  
Vol 881-883 ◽  
pp. 131-139
Author(s):  
Qiang Xiao ◽  
Wen Fa Xiao ◽  
Xin Xin Liu ◽  
Li Tao Dong
Keyword(s):  
High Temperature ◽  
Performance Test ◽  
Orthogonal Experiment ◽  
Salt Content ◽  
Performance Testing ◽  
Oil Field ◽  
Optimum Process ◽  
Fluid Loss ◽  
Excellent Thermal Stability ◽  
Fluid Loss Additive

A novel cement fluid loss additive P1301, which can resist high temperature and high salt content, was synthesized using the monomers of 2-acrylamido-2-methyl-propane sulphonic acid (AMPS), acrylic acid (AA), acrylamide (AM) and n-vinyl-2-pyrrolidone (NVP) by the method of aqueous solution polymerization. Through the orthogonal experiment find the optimum process: the ratio of monomers AMPS: AA: AM: NVP at 4:3:2:1, reaction PH at 11, reaction temperature at 60°C and reaction time about 4 hours. The IR spectrum show that the polymer with the structure of all the monomers. The aging test, thermal performance test and the fluid loss performance testing show that the forpolymers P1301 has an excellent thermal stability that can be used in 240°Cand strong salt tolerance. The fluid loss additive P1301 has an excellent tolerance to salt and high temperature.

Improving Oil well Cement Slurry Performance Using Hydroxypropylmethylcellulose Polymer

2013 ◽  
Vol 787 ◽  
pp. 222-227 ◽  
Author(s):  
Ghulam Abbas ◽  
Sonny Irawan ◽  
Sandeep Kumar ◽  
Ahmed A.I. Elrayah
Keyword(s):  
Compressive Strength ◽  
High Temperature ◽  
Rheological Properties ◽  
Elevated Temperatures ◽  
Free Water ◽  
Oil Wells ◽  
Fluid Loss ◽  
Cement Slurry ◽  
Multifunctional Additive ◽  
Wide Range

At present, high temperature oil wells are known as the most problematic for cementing operation due to limitations of polymer. The polymers are significantly used as mutlifunctional additives for improving the properties of cement slurry. At high temperature, viscosity of polymer decreases and unable to obtained desired properties of cement slurry. It becomes then major cause of fluid loss and gas migration during cementing operations. Thus, it necessitates for polymers that can able to enhance viscosity of slurry at elevated temperatures. This paper is aiming to study Hydroxypropylmethylcellulose (HPMC) polymer at high temperature that is able to increase the viscosity at elevated temperature. In response, experiments were conducted to characterize rheological properties of HPMC at different temperatures (30 to 100 °C). Then it was incorporated as multifunctional additive in cement slurry for determining API properties (fluid loss, free water, thickening time and compressive strength). It was observed that HPMC polymer has remarkable rheological properties that can have higher viscosity with respect to high temperatures. The best concentration of HPMC was found from 0.30 to 0.50 gallon per sack. This concentration showed minimal fluid loss, zero free water, high compressive strength and wide range of thickening time in cement slurry. The results signified that HPMC polymer is becoming multifunctional additive in cement slurry to improve the API properties of cement slurry and unlock high temperature oil wells for cementing operations.

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