Study on the synthesis of a macroporous ethylacrylate-divinylbenzene copolymer, its conversion into a bi-functional cation exchange resin and applications for extraction of toxic heavy metals from wastewater

2013 ◽  
Vol 129 (4) ◽  
pp. 2234-2243 ◽  
Author(s):  
Syed Wasim Ali ◽  
Farhat Waqar ◽  
Muhammad Arif Malik ◽  
Tariq Yasin ◽  
Bashir Muhammad
Polymers ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 2866
Author(s):  
Noor Fatima ◽  
Qi Zhang ◽  
Ruru Chen ◽  
Dongxia Yan ◽  
Qing Zhou ◽  
...  

Adsorption of heavy metals from degraded of Polyethylene terephthalate (PET) products by strong cation exchange resin AmberliteIR-120 under optimized conditions toward the selectivity removal of metals are in the following order: Al3+ > Zn2+ > Mg2+ > Fe2+ > Ni2+. Therefore, kinetic and adsorption isotherm models were applied for fitting experimental data. Comparatively, adsorption isotherm study revealed that Langmuir isotherm model better fits adsorption on surface of resin over than the Freundlich model. In summary, AmberliteIR-120 strong acid cation exchange resin can be used as an efficient adsorbent for heavy metals removal from depolymerized products bis(2-hydroxyethyl) terephthalate.


Eisei kagaku ◽  
1977 ◽  
Vol 23 (5) ◽  
pp. 314-318
Author(s):  
AKIRA ISHIMARU ◽  
SHINICHI ISHIWATA ◽  
YOSHIAKI SUYAMA ◽  
KOJI HIRANO ◽  
YOSUKE SHINO ◽  
...  

2019 ◽  
Vol 16 (2) ◽  
pp. 288-293
Author(s):  
Yogesh W. More ◽  
Sunil U. Tekale ◽  
Nitishkumar S. Kaminwar ◽  
László Kótai ◽  
Tibor Pasinszki ◽  
...  

Aim and Objective: The present study was performed with the aim to develop an efficient and environmentally benign protocol for the synthesis of biologically siginifcant 3, 4-dihydropyrano[c]chromenes using a new catalytic material. The protocol involves the use of a reusable, environment friendly materials and solvents with operational simplicity. Materials and Methods: Carbon microsphere supported copper nanoparticles (Cu-NP/C) prepared from loaded cation exchange resin were synthesized, characterized with well versed analytical techniques such as XRD, SEM and Raman spectroscopy and the synthesized material was used as a catalyst for the environmentally benign synthesis of 3,4-dihydropyrano[c]chromenes. Results: The formation of carbon microsphere supported copper nanoparticles (Cu-NP/C) prepared from loaded cation exchange resin was confirmed by XRD, SEM and Raman spectroscopy which was employed as a heterogeneous material for the synthesis of 3,4-dihydropyrano[c]chromenes. The products formed were characterized by the analysis of spectroscopic data - NMR, IR and mass. The safe catalytic system offers several advantages including operational simplicity, environmental friendliness, high yield, and reusability of catalyst and green chemical transformation. Conclusion: Herein we report an easy and efficient protocol for the one-pot synthesis of dihydropyrano[ c]chromenes using environmentally benign MCR approach in ethanol as the green solvent. The method developed herein constitutes a valuable addition to the existing methods for the synthesis of titled compounds.


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