Synthesis and photo-polymerization of bio-based furanic compounds functionalized by 2-hydroxypropyl methacrylate group(s)

2012 ◽  
Vol 127 (4) ◽  
pp. 2483-2489 ◽  
Author(s):  
Jaewon Jeong ◽  
Bora Kim ◽  
Seunghan Shin ◽  
Baekjin Kim ◽  
Jae-Soung Lee ◽  
...  
Keyword(s):  
Photo Polymerization ◽  
Hydroxypropyl Methacrylate ◽  
Methacrylate Group ◽  
Furanic Compounds

scholarly journals Patterned waveguide liquid crystal displays

RSC Advances ◽  
2020 ◽  
Vol 10 (68) ◽  
pp. 41693-41702
Author(s):  
Yunho Shin ◽  
Jinghua Jiang ◽  
Guangkui Qin ◽  
Qian Wang ◽  
Ziyuan Zhou ◽  
...  
Keyword(s):  
Liquid Crystal ◽  
Switching Time ◽  
Contrast Ratio ◽  
Liquid Crystal Displays ◽  
High Contrast ◽  
High Brightness ◽  
Photo Polymerization ◽  
Ultrafast Switching ◽  
Light Waveguide ◽  
Polymer Stabilized

A polymer stabilized LC based light waveguide display is reported. Performance is improved by patterned photo-polymerization or electrode. It has high brightness, ultrafast switching time, high contrast ratio, and high transmittance for transparent and augmented displays.

scholarly journals Self-Sensitization and Photo-Polymerization of Diacetylene Molecules Self-Assembled on a Hexagonal-Boron Nitride Nanosheet

Polymers ◽  
2018 ◽  
Vol 10 (2) ◽  
pp. 206 ◽  
Author(s):  
Elisseos Verveniotis ◽  
Yuji Okawa ◽  
Kenji Watanabe ◽  
Takashi Taniguchi ◽  
Takaaki Taniguchi ◽  
...  
Keyword(s):  
Boron Nitride ◽  
Hexagonal Boron Nitride ◽  
Photo Polymerization ◽  
Boron Nitride Nanosheet ◽  
Self Assembled

scholarly journals Effect of Photoinitiator on Precursory Stability and Curing Depth of Thiol-Ene Clickable Gelatin

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1877
Author(s):  
Kai-Hung Yang ◽  
Gabriella Lindberg ◽  
Bram Soliman ◽  
Khoon Lim ◽  
Tim Woodfield ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Visible Light ◽  
Rheological Properties ◽  
Swelling Ratio ◽  
Sodium Persulfate ◽  
Photo Polymerization ◽  
Gelation Kinetics ◽  
The Stability ◽  
Over Time

Recent advances highlight the potential of photopolymerizable allylated gelatin (GelAGE) as a versatile hydrogel with highly tailorable properties. It is, however, unknown how different photoinitiating system affects the stability, gelation kinetics and curing depth of GelAGE. In this study, sol fraction, mass swelling ratio, mechanical properties, rheological properties, and curing depth were evaluated as a function of time with three photo-initiating systems: Irgacure 2959 (Ig2959; 320–500 nm), lithium phenyl-2,4,6-trimethylbenzoylphosphinate (LAP; 320–500 nm), and ruthenium/sodium persulfate (Ru/SPS; 400–500 nm). Results demonstrated that GelAGE precursory solutions mixed with either Ig2959 or LAP remained stable over time while the Ru/SPS system enabled the onset of controllable redox polymerization without irradiation during pre-incubation. Photo-polymerization using the Ru/SPS system was significantly faster (<5 s) compared to both Ig2959 (70 s) and LAP (50 s). Plus, The Ru/SPS system was capable of polymerizing a thick construct (8.88 ± 0.94 mm), while Ig2959 (1.62 ± 0.49 mm) initiated hydrogels displayed poor penetration depth with LAP (7.38 ± 2.13 mm) in between. These results thus support the use of the visible light based Ru/SPS photo-initiator for constructs requiring rapid gelation and a good curing depth while Ig2959 or LAP can be applied for photo-polymerization of GelAGE materials requiring long-term incubation prior to application if UV is not a concern.

scholarly journals Catalytic approach via retro-aldol condensation of glucose to furanic compounds

2021 ◽  
Author(s):  
Rui Zhang ◽  
Aleksi Eronen ◽  
Xiangze Du ◽  
Enlu Ma ◽  
Ming Guo ◽  
...  
Keyword(s):  
Aldol Condensation ◽  
Catalytic Conversion ◽  
New Type ◽  
Furanic Compounds

The synthesis of new type furan-based compounds other than 5-hydroxymethylfurfural from glucose is a very attractive yet underexploited strategy. We report here a catalytic conversion of glucose with acetylacetone (acac)...

Performance and Friction Properties of Injection Hybrid Moulds with Stereolithography Moulding Zones

2006 ◽  
Vol 514-516 ◽  
pp. 1673-1677 ◽  
Author(s):  
Mathias G. Westphal ◽  
António Sergio Pouzada ◽  
Gean V. Salmoria ◽  
Carlos H. Ahrens
Keyword(s):  
Structural Integrity ◽  
Chemical Properties ◽  
Rapid Manufacturing ◽  
Mechanical And Thermal Properties ◽  
Layer By Layer ◽  
Metallic Materials ◽  
Moulding Process ◽  
Photo Polymerization ◽  
Geometric Precision ◽  
And Chemical Properties

Stereolithography is a rapid manufacturing process that builds objects layer-by-layer based on the photo polymerization of a liquid resin. Due to the good geometric precision, this process has been used in Rapid Tooling for injection moulding. These tools are suitable for the production of short runs of parts and prototypes, where without resorting to the manufacture of a conventional metallic mould. The mechanical and thermal properties of the stereolitography resins, used in the manufacture of hybrid moulds, differ substantially from those of the conventional metallic materials. Particularly they must be known for guaranteeing the structural integrity and the thermal performance of the mould. Also the chemistry behaviour of the resin in contact with the polymer is important when tribological aspects are involved, especially during the ejection of the moulding. In this work, the behaviour of hybrid moulds with SL Vantico 5260 resin moulding cores was assessed. Several thermoplastics (iPP, ABS, PET and PA 6.6) were moulded, and their mechanical, thermal and chemical properties considered and related to the performance of the moulding process. Also, the friction properties of the SL resin in contact with the moulded thermoplastic in moulding conditions were observed and considered in the context of the performance of hybrid moulds.

Fabrication of Three-Dimensional Micro-Structures with Two-Photon Absorption by Femtosecond Laser

2006 ◽  
Vol 532-533 ◽  
pp. 568-571
Author(s):  
Ming Zhou ◽  
Hai Feng Yang ◽  
Li Peng Liu ◽  
Lan Cai
Keyword(s):  
Photonic Crystal ◽  
Femtosecond Laser ◽  
Detection System ◽  
Three Dimensional ◽  
Photon Absorption ◽  
Micro Fabrication ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Photo Polymerization ◽  
System A

The photo-polymerization induced by Two-Photon Absorption (TPA) is tightly confined in the focus because the efficiency of TPA is proportional to the square of intensity. Three-dimensional (3D) micro-fabrication can be achieved by controlling the movement of the focus. Based on this theory, a system for 3D-micro-fabrication with femtosecond laser is proposed. The system consists of a laser system, a microscope system, a real-time detection system and a 3D-movement system, etc. The precision of micro-machining reaches a level down to 700nm linewidth. The line width was inversely proportional to the fabrication speed, but proportional to laser power and NA. The experiment results were simulated, beam waist of 0.413μm and TPA cross section of 2×10-54cm4s was obtained. While we tried to optimize parameters, we also did some research about its applications. With TPA photo-polymerization by means of our experimental system, 3D photonic crystal of wood-pile structure twelve layers and photonic crystal fiber are manufactured. These results proved that the micro-fabrication system of TPA can not only obtain the resolution down to sub-micron level, but also realize real 3D micro-fabrication.

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