Thermal degradation behaviors and flame retardancy of epoxy resins with novel silicon-containing flame retardant

2012 ◽  
Vol 127 (3) ◽  
pp. 1842-1847 ◽  
Author(s):  
Ming Gao ◽  
Weihong Wu ◽  
Zhi-qiang Xu
Keyword(s):  
Thermal Degradation ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
Epoxy Resins ◽  
Degradation Behaviors

Thermal degradation behaviors and flame retardancy of PC/ABS with novel silicon-containing flame retardant

2007 ◽  
Vol 31 (6) ◽  
pp. 411-423 ◽  
Author(s):  
Hanfang Zhong ◽  
Ping Wei ◽  
Pingkai Jiang ◽  
Genlin Wang
Keyword(s):  
Thermal Degradation ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
Degradation Behaviors

Study on flame-retardancy and thermal degradation behaviors of intumescent flame-retardant polylactide systems

2011 ◽  
Vol 60 (10) ◽  
pp. 1541-1547 ◽  
Author(s):  
Shanyong Xuan ◽  
Xin Wang ◽  
Lei Song ◽  
Weiyi Xing ◽  
Hongdian Lu ◽  
...  
Keyword(s):  
Thermal Degradation ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
Intumescent Flame Retardant ◽  
Degradation Behaviors

Thermal Stabilities and the Thermal Degradation Kinetics Study of the Flame Retardant Epoxy Resins

2014 ◽  
Vol 1053 ◽  
pp. 263-267 ◽  
Author(s):  
Xiu Juan Tian
Keyword(s):  
Thermal Stability ◽  
Thermal Degradation ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Epoxy Resins ◽  
Degradation Kinetics ◽  
Thermal Degradation Kinetics ◽  
Thermal Stabilities ◽  
Degradation Kinetic ◽  
Modified Epoxy

Thermal stability and thermal degradation kinetics of epoxy resins with 2-(Diphenylphosphinyl)-1, 4-benzenediol were investegated by thermogravimetric analysis (TGA) at different heating rates of 5 K/min, 10 K/min, 20 K/min and 40 K/min. The thermal degradation kinetic mechanism and models of the modified epoxy resins were determined by Coast Redfern method.The results showed that epoxy resins modified with the flame retardant had more thermal stability than pure epoxy resin. The solid-state decomposition mechanism of epoxy resin and the modified epoxy resin corresponded to the controlled decelerating ځ˽̈́˰̵̳͂͆ͅ˼˰̴̱̾˰̸̵̈́˰̵̸̳̱̹̽̾̓̽˰̶̳̹̾̈́̿̾̓ͅ˰̶˸ځ˹˰̵̵͇͂˰̃˸́˽ځ˹2/3. The introduction of phosphorus-containing flame retardant reduced thermal degradation rate of epoxy resins in the primary stage, and promote the formation of carbon layer.

Application of Calculus Equation in Solving Thermal Decomposition Kinetics Parameters of Flame Retardant Wood

2014 ◽  
Vol 983 ◽  
pp. 190-193
Author(s):  
Cai Yun Sun ◽  
Yong Li Yang ◽  
Ming Gao
Keyword(s):  
Activation Energy ◽  
Thermal Decomposition ◽  
Thermal Degradation ◽  
Phosphoric Acid ◽  
Flame Retardant ◽  
Kinetic Parameters ◽  
Flame Retardancy ◽  
Decomposition Kinetics ◽  
Thermal Decomposition Kinetics ◽  
Kinetics Parameters

Wood has been treated with amino resins and amino resins modified with phosphoric acid to impart flame retardancy. The thermal degradation of samples has been studied by thermogravimetry (TG) in air. From the resulting data, kinetic parameters for different stages of thermal degradation are obtained following the method of Broido. For the decomposition of wood and flame retardant wood, the activation energy is found to decrease from 122 to 72 kJmol-1.

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